Patent US5071609A successfully refreshed from Google Patents.
US5071609A
Expired / Lapsed
US
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Process of manufacturing porous multi-expanded fluoropolymers
Assignee: Edwards Lifesciences Corp
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Filing: 1988-11-03
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Granted: 1991-12-10
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Expires: 2008-11-03
Abstract
Abstract Interpenetrated matrix of polytetrafluoroethylene and elastomer is disclosed. The matrix is formed into a composite material which is flexible, durable, highly porous with a tight microporous structure and improved retractability. The composite material is subjected to a multi-expansion process to produce shaped articles such as films, tubes, rods and filaments with excellent flexibility and elasticity. More particularly, the composite material can be utilized to produce vascular grafts with excellent biological compatibility.
Inventors
- 👤 Roger H. Tu
- 👤 Wilfred F. Mathewson
- 👤 Mark A. Roberts
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 08:03
CPC Classifications
C; C08; C08J; C08J9/00; B; B29; B29C; B29C55/00; B29C55/005; C08L; C08L27/00; C08L27/02; C08L27/12; C08L27/18; B29K; B29K2027/00; B29K2027/12; B29K2027/18; B29K2105/00; B29K2105/0088; B29K2105/04; C08J2327/00; C08J2327/02; C08J2327/12; C08J2327/18; C08L21/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/3154; Y10T428/31544
Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
113 words
A process of preparing a polytetrafluroethylene-elastomer microporous substrate comprising the steps of: forming said substrate from a blend of polytetrafluoroethylene and an elastomer; heating said substrate to a temperature, and for a period of time which will not cause said elastomer to become cured; expanding said heated substrate to a first expanded position; maintaining said substrate in said first expanded position; heating said substrate to a temperature for a sufficient period of time for curing said elastomer but that will not effect sintering of said polytetrafluoroethylene; raising the temperature of said substrate for a sufficient period of time to flash sinter said polytetrafluoroethylene while allowing the substrate to assume a second expanded position.
Claim 2
Dependent Claim
113 words
A process of preparing a polytetrafluroethylene-elastomer microporous substrate comprising the steps of: forming said substrate from a blend of polytetrafluoroethylene and an elastomer; heating said substrate to a temperature, and for a period of time which will not cause said elastomer to become cured; expanding said heated substrate to a first expanded position; maintaining said substrate in said first expanded position; heating said substrate to a temperature for a sufficient period of time for curing said elastomer but that will not effect sintering of said polytetrafluoroethylene; raising the temperature of said substrate for a sufficient period of time to flash sinter said polytetrafluoroethylene while allowing the substrate to assume a second expanded position.
Claim 3
Dependent Claim
33 words
The process of claim 1 wherein said substrate is allowed to assume said second expanded position by performing a second step of expanding said substrate between said step of curing and flash sintering.
Claim 4
Dependent Claim
27 words
The process of claim 2 further including a second step of maintaining said substrate in said second expanded position before said step of flash sintering is performed.
Claim 5
Dependent Claim
26 words
The process of claim 1 wherein said first step of heating is performed to uniformly heat said substrate to said temperature below said elastomer curing temperature.
Claim 6
Dependent Claim
28 words
The process of claim 1 further including a step of preparing said polytetrafluroethylene-elastomer blend, with said elastomer comprising from about ten to thirty weight percent of said blend.
Claim 7
Dependent Claim
28 words
The process of claim 3 further including a step of preparing said polytetrafluroethylene-elastomer blend, with said elastomer comprising from about ten to thirty weight percent of said blend.
Claim 8
Dependent Claim
74 words
A process of forming a vascular graft comprising the steps of: forming a tubular structure from a blend of polytetrafluoroethylene and at least one elastomer; heating said tubular structure to a temperature below said elastomer curing temperature; expanding said tubular structure to a first expanded state; maintaining said tubular structure in said first expanded state; curing said elastomer; and flash sintering said polytetrafluoroethylene while allowing said tubular structure to assume a second expanded position.
Claim 9
Dependent Claim
74 words
A process of forming a vascular graft comprising the steps of: forming a tubular structure from a blend of polytetrafluoroethylene and at least one elastomer; heating said tubular structure to a temperature below said elastomer curing temperature; expanding said tubular structure to a first expanded state; maintaining said tubular structure in said first expanded state; curing said elastomer; and flash sintering said polytetrafluoroethylene while allowing said tubular structure to assume a second expanded position.
Claim 10
Dependent Claim
32 words
The process of claim 7 wherein said tubular structure is allowed to assume a second expanded position by releasing said tubular structure from said first expanded position prior to said sintering step.
Claim 11
Dependent Claim
38 words
The process of claim 7 wherein said tubular structure is allowed to assume a second expanded position by maintaining said tubular structure completely or partially in said first expanded position before said step of flash sintering is performed.
Claim 12
Dependent Claim
28 words
The process of claims 8 or 9 wherein said step of heating is performed to uniformly heat said tubular structure to said temperature below said elastomer curing temperature.
Claim 13
Dependent Claim
28 words
The process of claims 10 further including a step of preparing said polytetrafluroethylene-elastomer blend, with said elastomer comprising from about ten to thirty weight percent of said blend.
Claim 14
Dependent Claim
28 words
The process of claims 11 further including a step of preparing said polytetrafluroethylene-elastomer blend, with said elastomer comprising from about ten to thirty weight percent of said blend.
Claim 15
Dependent Claim
30 words
The process of claims 12 wherein said step of expanding of said tubular structure is performed by expanding said tubular structure in the longitudinal or radially direction, or both directions.
Claim 16
Dependent Claim
45 words
The process of claim 13 wherein said expanding step is performed to expand said tubular structure at a rate of about ten to about one-hundred percent per second and to a ratio of about two-hundred to about six-hundred percent of said tubular structure original length.
Claim 17
Dependent Claim
45 words
The process of claim 13 wherein said expanding step is performed to expand said tubular structure at a rate of about ten to about fifty percent per second and to a ratio of about two-hundred to about three-hundred percent of said tubular structure original length.
Claim 18
Dependent Claim
20 words
The process of claim 15 wherein said polytetrafluroethylene-elastomer blend is formed with from about ten to about thirty percent elastomer.
Claim 19
Dependent Claim
23 words
The process of claim 7 further including a second step of expanding said tubular structure between said step of curing and flash sintering.
Claim 20
Dependent Claim
21 words
The process of claim 17 wherein said tubular structure is released from said second expanded position prior to said sintering step.
Claim 21
Dependent Claim
23 words
The process of claim 17 wherein said tubular structure is completely or partially maintained in said second expanded position during said sintering step.
Claim 22
Dependent Claim
30 words
The process of claims 18 or 19 further including a step of preparing said polytetrafluroethylene-elastomer blend, with said elastomer comprising from about ten to thirty weight percent of said blend.
Claim 23
Dependent Claim
30 words
The process of claim 20 wherein said step of expanding of said tubular structure is performed by expanding said tubular structure in the longitudinal or radially direction, or both directions.
Claim 24
Dependent Claim
45 words
The process of claim 21 wherein said expanding step is performed to expand said tubular structure at a rate of about ten to about one-hundred percent per second and to a ratio of about two-hundred to about six-hundred percent of said tubular structure original length.
Claim 25
Dependent Claim
45 words
The process of claim 22 wherein said expanding step is performed to expand said tubular structure at a rate of about ten to about fifty percent per second and to a ratio of about two-hundred to about three-hundred percent of said tubular structure original length.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1994-12-09 | 1995-06-10 | 1995-12-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1998-12-09 | 1999-06-10 | 1999-12-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2002-12-09 | 2003-06-10 | 2003-12-10 | $7700.00 | Window Closed / Lapsed |