US5849206A
Expired / Lapsed
US
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Method of producing a biocompatible prosthesis
Assignee: Biotronik SE and Co KG
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Filing: 1997-02-04
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Granted: 1998-12-15
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Expires: 2017-02-04
Abstract
Abstract A method of producing a biocompatible prosthesis based on a substrate made essentially of metal or ceramic. The substrate is placed into a reactor chamber of a cathodic vapor deposition arrangement and the chamber is evacuated to a predetermined pressure. A predetermined, negative bias voltage is then applied to the substrate and the substrate is surface treated by adding an etching gas to the reactor chamber, at a predetermined, first flow rate and coupling in a high frequency power with a first, predetermined power density for ionic etching for a first, predetermined period of time. The surface treated substrate is separated from the negative bias voltage and a semiconductor cover layer is chemical vapor-phase deposited on the substrate by adding to the reactor chamber a multi-component mixture of process gases containing a semiconductor element in bound form at a second, predetermined flow rate and coupling-in of HF power with a predetermined, second power density, for a second, predetermined time period.
Inventors
- 👤 Michael Amon
- 👤 Armin Bolz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 11:07
CPC Classifications
A; A61; A61F; A61F2/00; A61F2/82; A61L; A61L27/00; A61L27/28; A61L27/30; A61L27/306; A61L31/00; A61L31/08; A61L31/082; A61L31/088; A61L33/00; A61L33/02; A61L33/027; C; C23; C23C; C23C16/00; C23C16/02; C23C16/0227; C23C16/0245; C23C16/0272; C23C16/22; C23C16/30; C23C16/32; C23C16/325; A61F2/0077; A61F2240/00; A61F2240/001; A61F2310/00; A61F2310/00389; A61F2310/00592; A61F2310/0073; A61F2310/00742
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
157 words
A method of producing a biocompatible prosthesis based on a prefabricated substrate comprised essentially of metal or ceramic, said method comprising: placing the substrate into a reactor chamber of a cathodic vapor deposition arrangement and evacuating the chamber to a pressure; surface treating the substrate by applying a negative bias voltage to the substrate, and adding an etching gas, at a first flow rate and coupling in a high frequency (HF) power, with a first power density, into the reactor chamber for ionic etching a surface of the substrate for a first period of time; separating the surface-treated substrate from the negative bias voltage; and chemical vapor-phase depositing a semiconductor cover layer on the surface of the substrate by adding a multi-component mixture of process gases containing a semiconductor element in bound form at a second flow rate and coupling-in of HF power, with a second power density, into the reactor chamber for a second time period.
Claim 2
Independent Claim
157 words
A method of producing a biocompatible prosthesis based on a prefabricated substrate comprised essentially of metal or ceramic, said method comprising: placing the substrate into a reactor chamber of a cathodic vapor deposition arrangement and evacuating the chamber to a pressure; surface treating the substrate by applying a negative bias voltage to the substrate, and adding an etching gas, at a first flow rate and coupling in a high frequency (HF) power, with a first power density, into the reactor chamber for ionic etching a surface of the substrate for a first period of time; separating the surface-treated substrate from the negative bias voltage; and chemical vapor-phase depositing a semiconductor cover layer on the surface of the substrate by adding a multi-component mixture of process gases containing a semiconductor element in bound form at a second flow rate and coupling-in of HF power, with a second power density, into the reactor chamber for a second time period.
Claim 3
Dependent Claim
86 words
The method according to claim 1, wherein following the surface treating step, said method further comprises: depositing a thin bonding agent layer, which includes the semiconductor element, onto the surface treated substrate by steps including: applying a second negative bias voltage to the surface-treated substrate; supplying a process gas that contains the semiconductor material in bound form at a third flow rate into the reactor chamber; and coupling into the reactor chamber an HF power with a third power density for a third period of time.
Claim 4
Dependent Claim
18 words
The method according to claim 2, wherein the process gas of said supplying step has a single component.
Claim 5
Dependent Claim
20 words
The method according to claim 3, wherein the single component process gas of said supplying step comprises SiH 4 .
Claim 6
Dependent Claim
15 words
The method according to claim 2, wherein the bonding agent layer essentially comprises silicon (Si).
Claim 7
Dependent Claim
23 words
The method according to claim 2, wherein said supplying step includes supplying process gas comprising monosilane in hydrogen (SiH 4 :H 2 ).
Claim 8
Dependent Claim
36 words
The method according to claim 2, including separating the substrate from the negative bias voltage without interruption of the coupling-in of the HF power in said coupling step to thus maintain plasma in the reactor chamber.
Claim 9
Dependent Claim
29 words
The method according to claim 2, wherein said step of depositing a thin bonding agent layer includes depositing the bonding agent layer to a thickness of a few nm.
Claim 10
Dependent Claim
32 words
The method according to claim 8, wherein said step of depositing a thin bonding agent layer includes depositing the bonding agent layer to a thickness of a about 3 to 5 nm.
Claim 11
Dependent Claim
58 words
The method according to claim 2, including forming the bonding agent layer and the semiconductor cover layer so as to blend at an increasing distance from the surface of the substrate and without a distinctive boundary layer by continuously changing a composition of the process gas over a period of time, with the semiconductor element component being removed.
Claim 12
Dependent Claim
22 words
The method according to claim 1, wherein the semiconductor element is silicon (Si), and the semiconductor cover layer includes silicon carbide (SiC).
Claim 13
Dependent Claim
16 words
The method as according to claim 1, wherein the semiconductor cover layer comprises an amorphous layer.
Claim 14
Dependent Claim
25 words
The method according to claim 1, wherein the multi-component mixture of process gases comprises at least monosilane (SiH 4 ) and methane (CH 4 ).
Claim 15
Dependent Claim
16 words
The method according to claim 1, wherein the etching gas is a single component etching gas.
Claim 16
Dependent Claim
21 words
The method according to claim 1, the etching gas in said step of adding an etching gas comprises an inert gas.
Claim 17
Dependent Claim
25 words
The method according to claim 15, wherein the inert gas comprises at least one of argon (Ar), Nitrogen (N) and carbon tetrachloride (CCl 4 ).
Claim 18
Dependent Claim
23 words
The method according to claim 1, wherein the substrate comprises one of high-grade steel, a titanium alloy, a tantalum alloy and platinum/iridium alloy.
Claim 19
Dependent Claim
21 words
The method according to claim 1, further comprising keeping the temperature of the prefabricated prosthesis substantially constant during the entire method.
Claim 20
Dependent Claim
14 words
The method according to claim 18, wherein the substantially constant temperature is 250° C.
Claim 21
Dependent Claim
27 words
The method according to claim 18, wherein said heating step includes substantially inertia-free substrate heating during a transition to and execution of said chemical vapor-phase depositing step.
Claim 22
Dependent Claim
23 words
The method according to claim 1, wherein said chemical vapor-phase depositing step includes depositing the semiconductor cover layer to a few hundred nm.
Claim 23
Dependent Claim
22 words
The method according to claim 21, wherein said depositing step includes depositing the semiconductor layer to a thickness of about 400 nm.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 2001-12-14 | 2002-06-15 | 2002-12-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2005-12-14 | 2006-06-15 | 2006-12-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2009-12-14 | 2010-06-15 | 2010-12-15 | $7700.00 | Window Closed / Lapsed |