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US5445992A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for forming a silicon carbide film

Assignee: Canon Inc
•
Filing: 1994-05-05
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Granted: 1995-08-29
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Expires: 2014-05-05
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Abstract

Abstract A semiconductor film having a very high light response of photoconductivity and good electrical characteristics such a wide band gap, for example, a non-monocrystalline silicon carbide film, is formed by decomposition reaction of a silicon-containing raw material gas and a hydrocarbon as a carbon raw material under light irradiation or high frequency, where the carbon raw material gas comprises at least one of tertiary and quaternary carbon atom-containing hydrocarbons of specific chemical formulae, and a semiconductor device using the thus formed semiconductor film is also provided.

Inventors

  • 👤 Hiroyuki Tokunaga
  • 👤 Tadashi Atoji

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:31
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/22; C23C16/30; C23C16/32; C23C16/325; H; H10; H10F; H10F71/00; H10F71/10; H10F71/103; H10F71/1035; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02P; Y02P70/00; Y02P70/50; Y10; Y10S; Y10S438/00; Y10S438/931

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 87 words
A chemical vapor deposition process for forming a semiconductor film containing silicon carbide, which comprises subjecting a silicon-containing raw material gas and a hydrocarbon as a carbon raw material to a decomposition reaction, the carbon raw material comprising at least one member selected from the group consisting of hydrocarbons comprising tertiary or quaternary carbon atom represented by the following general formulae (I) and (II): ##STR5## wherein R 1 to R 4 represent hydrocarbon groups selected from the group consisting of alkyl groups, aryl groups and aromatic groups.
Claim 2
Dependent Claim 87 words
A chemical vapor deposition process for forming a semiconductor film containing silicon carbide, which comprises subjecting a silicon-containing raw material gas and a hydrocarbon as a carbon raw material to a decomposition reaction, the carbon raw material comprising at least one member selected from the group consisting of hydrocarbons comprising tertiary or quaternary carbon atom represented by the following general formulae (I) and (II): ##STR5## wherein R 1 to R 4 represent hydrocarbon groups selected from the group consisting of alkyl groups, aryl groups and aromatic groups.
Claim 3
Dependent Claim 32 words
A process according to claim 1, wherein the decomposition reaction is carried out under at least one form of energy selected from the group consisting of light irradiation, high frequency and heat.
Claim 4
Dependent Claim 25 words
A process according to claim 1, wherein the selected hydrocarbon is a mixture of at least two of the tertiary and quaternary carbon atom-containing hydrocarbons.
Claim 5
Dependent Claim 16 words
A process according to claim 1, wherein the tertiary and quaternary carbon atom-containing hydrocarbons are isobutanes.
Claim 6
Dependent Claim 17 words
A process according to claim 1, wherein the tertiary and quaternary carbon atom-containing hydrocarbons are 2, 2-dimethylpropane.
Claim 7
Dependent Claim 16 words
A process according to claim 1, wherein the tertiary and quaternary carbon atom-containing hydrocarbons are isopentanes.
Claim 8
Dependent Claim 26 words
A process according to claim 1, wherein the tertiary and quaternary carbon atom-containing hydrocarbons take at least 90% by mole of the carbon raw material gas.
Claim 9
Dependent Claim 22 words
A process according to claim 1, wherein the semiconductor film containing the silicon atoms and the carbon atoms comprises non-monocrystalline silicon carbide.
Claim 10
Dependent Claim 15 words
A process according to claim 8, wherein the non-monocrystalline silicon carbide comprises amorphous silicon carbide.
Claim 11
Dependent Claim 21 words
A process according to claim 8, wherein the non-monocrystalline silicon carbide has an optical energy gap of at least 2.0 eV.
Claim 12
Dependent Claim 20 words
A process according to claim 1, wherein a hydrogen gas or an inert gas is used as a dilution gas.

References Cited (Backward Citations)

JPS57103311A Cited
JPS59172275A Cited
US4568626A Cited
US4546008A Cited
JPS62113482A Cited
JPS63136514A Cited
JPH023912A Cited
US5151296A Cited
US5011706A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-08-28 1999-02-27 1999-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-08-28 2003-02-27 2003-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-08-28 2007-02-27 2007-08-29 $7700.00 Window Closed / Lapsed

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