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US5284492A Expired / Lapsed US ⏱️ 0.0 years remaining

Enhanced lubricity fuel oil emulsions

Assignee: Nalco Fuel Tech
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Filing: 1992-10-08
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Granted: 1994-02-08
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Expires: 2012-10-08
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Abstract

Abstract An improved lubricity water and fuel oil emulsion is presented. The emulsion is used as fuel for an electric power generating turbine, and includes a lubricity additive selected from the group consisting of dimer acids, trimer acids, phosphate esters, sulfurized castor oil, and mixtures thereof. Also included is a method for improving the combustion efficiency of a turbine, using the inventive additives.

Inventors

  • 👤 Leonard Dubin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 13:16
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/32; C10L1/328

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 38 words
An improved lubricity water and fuel oil emulsion for use as fuel for an electric power generating turbine, comprising a lubricity additive selected from the group consisting of dimer acids, trimer acids, sulfurized castor oil, and mixtures thereof.
Claim 2
Dependent Claim 38 words
An improved lubricity water and fuel oil emulsion for use as fuel for an electric power generating turbine, comprising a lubricity additive selected from the group consisting of dimer acids, trimer acids, sulfurized castor oil, and mixtures thereof.
Claim 3
Dependent Claim 20 words
The emulsion of claim 1, wherein said lubricity additive is present at a level of at least about 100 ppm.
Claim 4
Dependent Claim 17 words
The emulsion of claim 2, wherein said lubricity additive comprises dimer acids, trimer acids, or blends thereof.
Claim 5
Dependent Claim 18 words
The emulsion of claim 1, wherein said lubricity additive further comprises a corrosion inhibitor comprising a filming amine.
Claim 6
Dependent Claim 49 words
The emulsion of claim 1, which further comprises an emulsification system comprising: a) about 25% to about 85% of an amide; b) about 5% to about 25% of a phenolic surfactant; and c) about 0% to about 40% of a difunctional block polymer terminating in a primary hydroxyl group.
Claim 7
Dependent Claim 22 words
The emulsion of claim 5, wherein said amide comprises an alkanolamide formed by condensation of a hydroxyalkyl amine with an organic acid.
Claim 8
Dependent Claim 13 words
The emulsion of claim 5, wherein said phenolic surfactant comprises an ethoxylated alkylphenol.
Claim 9
Dependent Claim 13 words
The emulsion of claim 7, wherein said ethoxylated alkylphenol comprises ethylene oxide nonylphenyl.
Claim 10
Dependent Claim 16 words
The emulsion of claim 5, wherein said difunctional block polymer comprises propylene oxide/ethylene oxide block polymer.
Claim 11
Dependent Claim 22 words
The emulsion of claim 5, wherein said emulsification system is present in an amount of about 0.05% to about 5.0% by weight.
Claim 12
Dependent Claim 19 words
The emulsion of claim 1, wherein said fuel comprises #2 oil, kerosene, jet fuels, diesel fuels and mixtures thereof.
Claim 13
Dependent Claim 12 words
The emulsion of claim 1, which comprises up to about 90% water.
Claim 14
Independent Claim 53 words
A method for improving the combustion efficiency of an electric power generating turbine, comprising forming an emulsion of water and fuel oil, which comprises a lubricity additive selected from the group consisting of dimer acids, trimer acids, sulfurized castor oil and mixtures thereof; and combusting said emulsion in an electric power generating turbine.
Claim 15
Independent Claim 53 words
A method for improving the combustion efficiency of an electric power generating turbine, comprising forming an emulsion of water and fuel oil, which comprises a lubricity additive selected from the group consisting of dimer acids, trimer acids, sulfurized castor oil and mixtures thereof; and combusting said emulsion in an electric power generating turbine.
Claim 16
Dependent Claim 20 words
The method of claim 13, wherein said lubricity additive is present at a level of at least about 100 ppm.
Claim 17
Dependent Claim 17 words
The method of claim 13, wherein said lubricity additive comprises dimer acids, trimer acids, or blends thereof.
Claim 18
Dependent Claim 18 words
The method of claim 13, wherein said lubricity additive further comprises a corrosion inhibitor comprising a filming amine.
Claim 19
Dependent Claim 49 words
The method of claim 13, which further comprises an emulsification system comprising: a) about 25% to about 85% of an amide; b) about 5% to about 25% of a phenolic surfactant; and c) about 0% to about 40% of a difunctional block polymer terminating in a primary hydroxyl group.
Claim 20
Dependent Claim 22 words
The method of claim 17, wherein said amide comprises an alkanolamide formed by condensation of a hydroxyalkyl amine with an organic acid.
Claim 21
Dependent Claim 13 words
The method of claim 17, wherein said phenolic surfactant comprises an ethoxylated alkylphenol.
Claim 22
Dependent Claim 13 words
The method of claim 19, wherein said ethoxylated alkylphenol comprises ethylene oxide nonylphenyl.
Claim 23
Dependent Claim 16 words
The method of claim 17, wherein said difunctional block polymer comprises propylene oxide/ethylene oxide block polymer.
Claim 24
Dependent Claim 22 words
The method of claim 17, wherein said emulsification system is present in an amount of about 0.05% to about 5.0% by weight.
Claim 25
Dependent Claim 20 words
The method of claim 13, wherein said fuel oil comprises #2 oil, kerosene, jet fuels, diesel fuels and mixtures thereof.
Claim 26
Dependent Claim 13 words
The method of claim 13, which comprises up to about 90% water-in-fuel oil.
Claim 27
Dependent Claim 14 words
The method of claim 13, wherein said emulsion is combusted simultaneously with natural gas.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-02-07 1997-08-09 1998-02-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-02-07 2001-08-09 2002-02-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-02-07 2005-08-09 2006-02-08 $7700.00 Window Closed / Lapsed

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