Patent US4912167A successfully refreshed from Google Patents.
US4912167A
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Polyester compositions for blow molding
Assignee: EIDP Inc
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Filing: 1987-12-14
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Granted: 1990-03-27
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Expires: 2007-12-14
Abstract
Abstract A blow moldable composition of a polyester, an epoxide polymer and a source of catalytic cations.
Inventors
- 👤 Edward J. Deyrup
- 👤 Edmund A. Flexman, Jr.
- 👤 King L. Howe
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 13:03
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/098; C08L; C08L67/00; C08L67/02
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
216 words
A melt-blend of a mixture consisting essentially of: (a) 70-90 parts by weight of a semicrystalline polyester; (b) 10-30 parts by weight of an epoxide-group containing copolymer containing recurring units of monomer of the formula (1) CH 2 ═C(R)COOCH 2 CHCH 2 O wherein R═H or lower alkyl of 1-6 carbon atoms and recurring units of one or more monomers selected from the group consisting of (2) CH 2 ═CHR where R═H, lower alkyl, or phenyl, (3) CH 2 ═C(R 1 )COOR 2 where R 1 ═H or lower alkyl and R 2 ═alkyl of 1-8 carbon atoms, (4) RCOOCH═CH 2 where R═lower alkyl, and (5) CO; and (c) 0.01 to 3.0 parts by weight of a source of catalytic cartons selected from the group consisting of metal salts of hydrocarbon mono-, di-, or poly-carboxylic acids and metal salts of organic polymers containing carboxyl groups, said cations being selected from the group consisting of Al 30 ++, Cd ++ , Co ++ , Cu ++ , Fe ++ , In +++ , Mn ++ , Nd +++ , Sb +++ , Sn ++ , and Zn ++ and provided that the source of catalytic cations imparts into the melt blend 0.05 to 0.5 millimoles of catalytic cation per 100 grams of components (a) and (b) combined.
Claim 2
Dependent Claim
216 words
A melt-blend of a mixture consisting essentially of: (a) 70-90 parts by weight of a semicrystalline polyester; (b) 10-30 parts by weight of an epoxide-group containing copolymer containing recurring units of monomer of the formula (1) CH 2 ═C(R)COOCH 2 CHCH 2 O wherein R═H or lower alkyl of 1-6 carbon atoms and recurring units of one or more monomers selected from the group consisting of (2) CH 2 ═CHR where R═H, lower alkyl, or phenyl, (3) CH 2 ═C(R 1 )COOR 2 where R 1 ═H or lower alkyl and R 2 ═alkyl of 1-8 carbon atoms, (4) RCOOCH═CH 2 where R═lower alkyl, and (5) CO; and (c) 0.01 to 3.0 parts by weight of a source of catalytic cartons selected from the group consisting of metal salts of hydrocarbon mono-, di-, or poly-carboxylic acids and metal salts of organic polymers containing carboxyl groups, said cations being selected from the group consisting of Al 30 ++, Cd ++ , Co ++ , Cu ++ , Fe ++ , In +++ , Mn ++ , Nd +++ , Sb +++ , Sn ++ , and Zn ++ and provided that the source of catalytic cations imparts into the melt blend 0.05 to 0.5 millimoles of catalytic cation per 100 grams of components (a) and (b) combined.
Claim 3
Dependent Claim
14 words
The composition of claim 1 wherein the polyester is poly(ethylene terephthalate) or poly(butylene terephthalate).
Claim 4
Dependent Claim
25 words
The composition of claim 1 wherein the source of the catalytic cations in component (c) is the zinc salt of a carboxyl containing organic polymer.
Claim 5
Dependent Claim
36 words
A composition of claim 1 where component (a) is poly(butylene terephthalate, component (b) is a terpolymer of ethylene/butyl acrylate/glycidyl methacrylate and component (c) is the zinc salt of a copolymer of ethylene and copolymerizable unsaturated acids.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1993-03-26 | 1993-09-25 | 1994-03-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-03-26 | 1997-09-25 | 1998-03-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-03-26 | 2001-09-25 | 2002-03-27 | $7700.00 | Window Closed / Lapsed |