US4284540A
Expired / Lapsed
US
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Polyethylene terephthalate molding compositions
Assignee: Toray Industries Inc
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Filing: 1980-04-16
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Granted: 1981-08-18
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Expires: 2000-04-16
Abstract
Abstract Impact-modified and moldability-improved polyethylene terephthalate molding compositions are provided which comprise polyethylene terephthalate resins, a copolymer of α-olefins and glycidyl esters of α,β-ethylenically-unsaturated carboxylic acids and barium salt of fatty acids. Glass fiber reinforcement of the polyester compositions is preferable because of further enhancement of the moldability of the polyester composition thereof. In addition, resistance to moist heat is also increased.
Inventors
- 👤 Hiroshi Iida
- 👤 Kiichi Kometani
- 👤 Masana Yanagi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 08:02
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/098; C08L; C08L63/00; C08L67/00; C08L67/02
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
104 words
Polyethylene terephthalate molding compositions which comprise (a) polyethylene terephthalate having an intrinsic viscosity of at least 0.4 as measured at 1% concentration in o-chlorophenol at 25° C., (b) from 0.1 to 40 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of a copolymer of an α-olefin, and a glycidyl ester of α,β-unsaturated-aliphatic carboxylic acid having the general formula ##STR4## wherein R is hydrogen or a lower alkyl radical, and (c) from 0.1 to 5 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of the barium salt of a fatty acid having 8 to 33 carbon atoms.
Claim 2
Dependent Claim
104 words
Polyethylene terephthalate molding compositions which comprise (a) polyethylene terephthalate having an intrinsic viscosity of at least 0.4 as measured at 1% concentration in o-chlorophenol at 25° C., (b) from 0.1 to 40 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of a copolymer of an α-olefin, and a glycidyl ester of α,β-unsaturated-aliphatic carboxylic acid having the general formula ##STR4## wherein R is hydrogen or a lower alkyl radical, and (c) from 0.1 to 5 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of the barium salt of a fatty acid having 8 to 33 carbon atoms.
Claim 3
Dependent Claim
24 words
Polyethylene terephthalate molding compositions as claimed in claim 1, wherein the amount of the copolymer (b) is from 0.5 to 30 parts by weight.
Claim 4
Dependent Claim
50 words
Polyethylene terephthalate molding compositions as claimed in claim 1, wherein the copolymer (b) comprises at least one α-olefin, selected from the group consisting of ethylene and propylene, and at least one glycidyl ester of α,β-unsaturated-aliphatic carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid and ethacrylic acid.
Claim 5
Dependent Claim
18 words
Polyethylene terephthalate molding compositions as claimed in claim 3, wherein said copolymer (b) comprises ethylene and glycidyl methacrylate.
Claim 6
Dependent Claim
29 words
Polyethylene terephthalate molding compositions as claimed in claim 1, wherein said copolymer contains the unit of α,β-ethylenically-unsaturated carboxylic acid in an amount ranging from 1 to 50% by weight.
Claim 7
Dependent Claim
192 words
Polyethylene terephthalate molding compositions which comprise (a) polyethylene terephthalate having an intrinsic viscosity of at least 0.4 as measured at 1% concentration in o-chlorophenol at 25° C., (b) from 0.1 to 40 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of copolymers of α-olefins and glycidyl esters of α,β-unsaturated-aliphatic carboxylic acids, (c) from 0.1 to 5 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of the barium salt of fatty acids having 8 to 33 carbon atoms, (d) up to 100 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of a reinforcement selected from the group consisting of glass fiber, asbestos, mica and talc, and (e) from 0 to 10 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of a compound containing ester linkages, of the general formulas ##STR5## wherein R 1 is an alcoholic residue having 1 to 20 carbon atoms, and n is from 1 to 4, ##STR6## wherein R 2 is hydrogen or carboxylic residue, and l, m, and n are from 2 to 10, 1 to 10 and 1 to 30, respectively.
Claim 8
Dependent Claim
192 words
Polyethylene terephthalate molding compositions which comprise (a) polyethylene terephthalate having an intrinsic viscosity of at least 0.4 as measured at 1% concentration in o-chlorophenol at 25° C., (b) from 0.1 to 40 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of copolymers of α-olefins and glycidyl esters of α,β-unsaturated-aliphatic carboxylic acids, (c) from 0.1 to 5 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of the barium salt of fatty acids having 8 to 33 carbon atoms, (d) up to 100 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of a reinforcement selected from the group consisting of glass fiber, asbestos, mica and talc, and (e) from 0 to 10 parts by weight, based on 100 parts by weight of polyethylene terephthalate, of a compound containing ester linkages, of the general formulas ##STR5## wherein R 1 is an alcoholic residue having 1 to 20 carbon atoms, and n is from 1 to 4, ##STR6## wherein R 2 is hydrogen or carboxylic residue, and l, m, and n are from 2 to 10, 1 to 10 and 1 to 30, respectively.
Claim 9
Dependent Claim
25 words
Polyethylene terephthalate molding compositions as claimed in claim 6 wherein the amount of the copolymer (b) is from about 0.5 to 30 parts by weight.
Claim 10
Dependent Claim
49 words
Polyethylene terephthalate molding compositions as claimed in claim 6 wherein the copolymer (b) comprises at least one α-olefin, selected from the group consisting of ethylene and propylene, and a glycidyl ester of an α,β-unsaturated-aliphatic carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid or ethacrylic acid.
Claim 11
Dependent Claim
18 words
Polyethylene terephthalate molding compositions as claimed in claim 8, wherein said copolymer (b) comprises ethylene and glycidyl methacrylate.
Claim 12
Dependent Claim
30 words
Polyethylene terephthalate molding compositions as claimed in claim 6, wherein said copolymer (b) contains a unit of α,β-unsaturated-aliphatic carboxylic acid in an amount ranging from 1 to 50% by weight.
Claim 13
Dependent Claim
24 words
Polyethylene terephthalate molding compositions as claimed in claim 6, wherein the reinforcement (d) is glass fibers having an average standard diameter greater than 5.
Claim 14
Dependent Claim
38 words
Polyethylene terephthalate molding compositions as claimed in claim 6, wherein the compound containing the ester linkage represented by general formula II is selected from the group consisting of triethylene glycol dibenzoate, neopentyl glycol dibenzoate and polyethylene glycol dibenzoate.
Claim 15
Dependent Claim
32 words
Polyethylene terephthalate molding compositions as claimed in claim 6, wherein the compound containing the ester linkage represented by general formula III is ethylene terephthalate oligomer where n is from 1 to 30.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-08-17 | 1985-02-16 | 1985-08-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-08-17 | 1989-02-16 | 1989-08-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-08-17 | 1993-02-16 | 1993-08-18 | $7700.00 | Window Closed / Lapsed |