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US4912167A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester compositions for blow molding

Assignee: EIDP Inc
•
Filing: 1987-12-14
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Granted: 1990-03-27
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Expires: 2007-12-14
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Abstract

Abstract A blow moldable composition of a polyester, an epoxide polymer and a source of catalytic cations.

Inventors

  • 👤 Edward J. Deyrup
  • 👤 Edmund A. Flexman, Jr.
  • 👤 King L. Howe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 11:05
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/098; C08L; C08L67/00; C08L67/02

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 216 words
A melt-blend of a mixture consisting essentially of: (a) 70-90 parts by weight of a semicrystalline polyester; (b) 10-30 parts by weight of an epoxide-group containing copolymer containing recurring units of monomer of the formula (1) CH 2 ═C(R)COOCH 2 CHCH 2 O wherein R═H or lower alkyl of 1-6 carbon atoms and recurring units of one or more monomers selected from the group consisting of (2) CH 2 ═CHR where R═H, lower alkyl, or phenyl, (3) CH 2 ═C(R 1 )COOR 2 where R 1 ═H or lower alkyl and R 2 ═alkyl of 1-8 carbon atoms, (4) RCOOCH═CH 2 where R═lower alkyl, and (5) CO; and (c) 0.01 to 3.0 parts by weight of a source of catalytic cartons selected from the group consisting of metal salts of hydrocarbon mono-, di-, or poly-carboxylic acids and metal salts of organic polymers containing carboxyl groups, said cations being selected from the group consisting of Al 30 ++, Cd ++ , Co ++ , Cu ++ , Fe ++ , In +++ , Mn ++ , Nd +++ , Sb +++ , Sn ++ , and Zn ++ and provided that the source of catalytic cations imparts into the melt blend 0.05 to 0.5 millimoles of catalytic cation per 100 grams of components (a) and (b) combined.
Claim 2
Dependent Claim 216 words
A melt-blend of a mixture consisting essentially of: (a) 70-90 parts by weight of a semicrystalline polyester; (b) 10-30 parts by weight of an epoxide-group containing copolymer containing recurring units of monomer of the formula (1) CH 2 ═C(R)COOCH 2 CHCH 2 O wherein R═H or lower alkyl of 1-6 carbon atoms and recurring units of one or more monomers selected from the group consisting of (2) CH 2 ═CHR where R═H, lower alkyl, or phenyl, (3) CH 2 ═C(R 1 )COOR 2 where R 1 ═H or lower alkyl and R 2 ═alkyl of 1-8 carbon atoms, (4) RCOOCH═CH 2 where R═lower alkyl, and (5) CO; and (c) 0.01 to 3.0 parts by weight of a source of catalytic cartons selected from the group consisting of metal salts of hydrocarbon mono-, di-, or poly-carboxylic acids and metal salts of organic polymers containing carboxyl groups, said cations being selected from the group consisting of Al 30 ++, Cd ++ , Co ++ , Cu ++ , Fe ++ , In +++ , Mn ++ , Nd +++ , Sb +++ , Sn ++ , and Zn ++ and provided that the source of catalytic cations imparts into the melt blend 0.05 to 0.5 millimoles of catalytic cation per 100 grams of components (a) and (b) combined.
Claim 3
Dependent Claim 14 words
The composition of claim 1 wherein the polyester is poly(ethylene terephthalate) or poly(butylene terephthalate).
Claim 4
Dependent Claim 25 words
The composition of claim 1 wherein the source of the catalytic cations in component (c) is the zinc salt of a carboxyl containing organic polymer.
Claim 5
Dependent Claim 36 words
A composition of claim 1 where component (a) is poly(butylene terephthalate, component (b) is a terpolymer of ethylene/butyl acrylate/glycidyl methacrylate and component (c) is the zinc salt of a copolymer of ethylene and copolymerizable unsaturated acids.

References Cited (Backward Citations)

US4034013A Cited
US4246378A Cited
US4284540A Cited
JPS59184251A Cited
US4659757A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-03-26 1993-09-25 1994-03-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-03-26 1997-09-25 1998-03-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-03-26 2001-09-25 2002-03-27 $7700.00 Window Closed / Lapsed

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