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US4803035A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for making composite films

Assignee: ExxonMobil Chemical Patents Inc
•
Filing: 1985-12-16
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Granted: 1989-02-07
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Expires: 2005-12-16
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Abstract

Abstract A process for preparing composite films comprising at least one layer of a first plastic polymer and a substrate of a second polymer/first plastic polymer composition by intimately mixing about 15 to about 90 wt. % of first plastic polymer and about 10 to 85 wt. % of the second polymer, extruding the mixture through a film die while cooling at least one surface of the die outlet at least about 10° C. below the melting point of the plastic polymer and cooling the film. In a preferred embodiment the first plastic polymer has a semi-crystalline or crystalline melting point which is at least 10° C. above the softening or melting point of the second polymer. A sandwich type laminate comprising two outer skins of first plastic polymer enclosing a core comprising a blend of first plastic polymer and second polymer can be prepared by cooling both die outlet surfaces. Where a blown film die is utilized the inner and outer die layers must be cooled to accomplish this end. In a sheet die both the upper and lower die layers are cooled.

Inventors

  • 👤 Edward N. Kresge
  • 👤 Donald R. Hazelton

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 11:58
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B29; B29C; B29C48/00; B29C48/022; B29C48/03; B29C48/04; B29C48/07; B29C48/08; B29C48/25; B29C48/78; B29C48/86; B29C48/87; B29C48/88; B29C48/919; B32B27/32; B32B7/00; B32B7/04; B32B7/12; C; C08; C08J; C08J5/00; C08J5/18; C08L; C08L23/00; C08L23/02; B32B2270/00; B32B2439/00; B32B2439/80

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 150 words
A process for preparing a composite film comprising at least one layer of a first plastic polymer and a substrate of a second polymer/first plastic polymer composition wherein the plastic polymer has a semicrystalline or crystalline melting point which is at least 10° C. higher than the second polymer softening or melting point, said first plastic polymer comprising about 15 to about 90 weight percent of the second polymer/first plastic polymer composition said second polymer and plastic polymer being insoluble in one another, which comprises: (a) intimately mixing the second polymer and first plastic polymer; (b) extruding the mixture through a film die having a die outlet comprising a first die surface and a second die surface; (c) cooling at least one surface of the die outlet to a temperature at least about 10° C. below the melting point of the plastic polymer; and (d) cooling the film so formed.
Claim 2
Dependent Claim 150 words
A process for preparing a composite film comprising at least one layer of a first plastic polymer and a substrate of a second polymer/first plastic polymer composition wherein the plastic polymer has a semicrystalline or crystalline melting point which is at least 10° C. higher than the second polymer softening or melting point, said first plastic polymer comprising about 15 to about 90 weight percent of the second polymer/first plastic polymer composition said second polymer and plastic polymer being insoluble in one another, which comprises: (a) intimately mixing the second polymer and first plastic polymer; (b) extruding the mixture through a film die having a die outlet comprising a first die surface and a second die surface; (c) cooling at least one surface of the die outlet to a temperature at least about 10° C. below the melting point of the plastic polymer; and (d) cooling the film so formed.
Claim 3
Dependent Claim 26 words
The process according to claim 1 wherein the first plastic polymer comprises about 15 to about 60 weight percent of the second polymer/first plastic polymer mixture.
Claim 4
Dependent Claim 26 words
The process according to claim 2 wherein the first plastic polymer comprises about 15 to about 35 weight percent of the second polymer/first plastic polymer composition.
Claim 5
Dependent Claim 22 words
The process according to claim 1 wherein the second polymer is an elastomeric polymer having a Tg of less than 0° C.
Claim 6
Dependent Claim 21 words
The process according to claim 4 wherein the elastomer is EPR, EPDM, NR, SBR, PIB, or halobutyl rubber, or mixtures thereof.
Claim 7
Dependent Claim 27 words
The process according to claim 4 wherein the plastic polymer is HDPE, LDPE, LLDPE, polypropylene, polybutene-1, a crystalline copolymer of ethylene and an alphaolefin or mixtures thereof.
Claim 8
Dependent Claim 26 words
The process according to claim 4 wherein the elastomer is EPR or EPDM and the plastic polymer is a crystalline ethylenepropylene copolymer, HDPE or mixtures thereof.
Claim 9
Dependent Claim 18 words
The process according to claim 4 wherein the plastic polymer is sulfonated EPDM ionomer or poly(ethylene glycol terphalate).
Claim 10
Dependent Claim 22 words
The process according to claim 4 wherein the elastomer is combined with tackifier resins thereby forming an elastomeric pressure sensitive adhesive composition.
Claim 11
Dependent Claim 33 words
The process according to claim 9 wherein the die is a blown film die having an annular outlet bounded by an inner and outer die lip, only said inner die lip being cooled.
Claim 12
Dependent Claim 32 words
The process according to claim 4 wherein the elastomer is an ethylene propylene copolymer and the plastic polymer is a blend of an HDPE and a crystalline copolymer of ethylene and propylene.
Claim 13
Dependent Claim 47 words
The process according to claim 11 wherein the elastomer/plastic composition comprises about 40 weight percent elastomer based on the elastomer/plastic composition, the HDPE comprises about 16 weight percent of the elastomer/plastic composition and the crystalline ethylene propylene copolymer comprises about 44 weight percent of the elastomer/plastic composition.
Claim 14
Dependent Claim 16 words
The process according to claim 1 wherein both the first and second die surface are cooled.

References Cited (Backward Citations)

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US4053548A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-02-07 1992-08-08 1993-02-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-02-07 1996-08-08 1997-02-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-02-07 2000-08-08 2001-02-07 $7700.00 Window Closed / Lapsed

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