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US4053548A Expired / Lapsed US ⏱️ 0.0 years remaining

Fabrication process for multiphased plastics

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1971-11-17
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Granted: 1977-10-11
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Expires: 1991-11-17
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Abstract

Abstract A process for fabricating a plastic, which plastic is either a thermoplastic ionomer or a multiphase graft or block copolymer of the ABA, ##STR1## or (AB) n wherein n is greater than 1 and wherein the polymer blocks (A and B) are thermoplastic, incompatible with one another, and have different softening points, both softening points being substantially above room temperature when using the latter class of polymers. The material is first heated to a temperature above both softening points and formed into any desired shape, then cooled and re-formed into a new desired shape at a temperature between that of the softening points of the two blocks and finally cooled to a temperature below both softening points thereby retaining the shape last achieved. When using thermoplastic ionomers the process is similar. The material is heated above the softening point of the thermoplastic backbone and plasticizers are employed to disrupt the ionic domains. The process may be readily employed to prepare containers, bottles, or rigid foams and the like which may be shipped as compact materials and re-formed for actual use by simply reheating, etc.

Inventors

  • 👤 Robert D. Lundberg
  • 👤 Henry S. Makowski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 14:55
CPC Classifications
C; C08; C08L; C08L53/00; B; B29; B29C; B29C61/00; B29C61/003; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C08J; C08J3/00; C08J3/18; C08J5/00; B29K; B29K2096/00; B29K2096/005; B29K2096/02; B29K2096/04

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 165 words
A process for fabricating an article from a thermoplastic composition, said thermoplastic composition being a multiphase copolymer of the A-B-A, ##STR6## or (AB) n type, wherein n is greater than 1 and wherein polymer blocks, A and B, are thermoplastic resins, each comprising at least 10 monomer units and having softening points of at least 35° C., with B being the lower softening block and being present in at least about 50% to about 97% by weight % of the total polymer, and the A block having a softening point at least 10° C. higher than said B block which comprises: a. forming said thermoplastic composition in a first desired shape at a temperature above both softening points; b. reforming to a second desired shape the formed thermoplastic of step (a) at a temperature between that of the softening point of the A and B blocks; and c. cooling the reformed thermoplastic to a temperature below both softening points while retaining said new desired shape.
Claim 2
Dependent Claim 165 words
A process for fabricating an article from a thermoplastic composition, said thermoplastic composition being a multiphase copolymer of the A-B-A, ##STR6## or (AB) n type, wherein n is greater than 1 and wherein polymer blocks, A and B, are thermoplastic resins, each comprising at least 10 monomer units and having softening points of at least 35° C., with B being the lower softening block and being present in at least about 50% to about 97% by weight % of the total polymer, and the A block having a softening point at least 10° C. higher than said B block which comprises: a. forming said thermoplastic composition in a first desired shape at a temperature above both softening points; b. reforming to a second desired shape the formed thermoplastic of step (a) at a temperature between that of the softening point of the A and B blocks; and c. cooling the reformed thermoplastic to a temperature below both softening points while retaining said new desired shape.
Claim 3
Dependent Claim 34 words
The process of claim 1 wherein prior to step (b) the formed thermoplastic is cooled to a temperature below that of both softening points and thereafter heated to the temperature required by step (b).
Claim 4
Dependent Claim 13 words
The process of claim 1 wherein the thermoplastic is a poly-t-butylstyrene-polystyrene block copolymer.
Claim 5
Dependent Claim 14 words
The process of claim 3 wherein the block polymer is of the ABA type.
Claim 6
Dependent Claim 15 words
The process of claim 1 wherein each polymer block contains at least 50 monomer units.
Claim 7
Dependent Claim 27 words
The process of claim 1 wherein step (a) is performed at a temperature at least 10° C. above that of the softening point of the A block.
Claim 8
Dependent Claim 39 words
The process of claim 1 which comprises the additional step of reheating the cooled thermoplastic of step (c) to a temperature between that of the softening points of the A and B blocks, thereby reachieving said first desired shape.

References Cited (Backward Citations)

US3655829A Cited
US3386877A Cited
US3544671A Cited
US3526683A Cited
US3548048A Cited
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US3673295A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-10-10 1981-04-11 1981-10-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-10-10 1985-04-11 1985-10-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-10-10 1989-04-11 1989-10-11 $7700.00 Window Closed / Lapsed

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