Patent US4643734A successfully refreshed from Google Patents.
US4643734A
Expired / Lapsed
US
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Lactide/caprolactone polymer, method of making the same, composites thereof, and prostheses produced therefrom
Assignee: Hexcel Corp
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Filing: 1983-05-05
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Granted: 1987-02-17
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Expires: 2003-05-05
Abstract
Abstract A bio-absorbable copolymer of lactide and epsilon caprolactone comprising a major amount of epsilon caprolactone and a minor amount of lactide; a method of making the same; a composition of said polymer and at least one substrate of a plurality of carbon fibers; surgical articles of said composition; and a method of repairing ligaments and tendons are disclosed.
Inventors
- 👤 Steve Lin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 18:09
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/06; C08G63/08; A; A61; A61F; A61F2/00; A61F2/02; A61F2/08; A61L; A61L27/00; A61L27/14; A61L27/18; A61L27/40; A61L27/44; A61L27/443
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
57 words
A bio-absorbable copolymer consisting essentially of lactide and epsilon caprolactone, wherein said epsilon caprolactone is present in amounts of 60-95% by weight and said lactide is present in amounts of 5-40% by weight, and wherein said copolymer is tough, elastic, has good tensile strength and elongation to failure in excess of 2000%, and is non-brittle and non-rigid.
Claim 2
Dependent Claim
57 words
A bio-absorbable copolymer consisting essentially of lactide and epsilon caprolactone, wherein said epsilon caprolactone is present in amounts of 60-95% by weight and said lactide is present in amounts of 5-40% by weight, and wherein said copolymer is tough, elastic, has good tensile strength and elongation to failure in excess of 2000%, and is non-brittle and non-rigid.
Claim 3
Dependent Claim
16 words
The bio-absorbable copolymer according to claim 1 wherein said lactide is optically active or optically inactive.
Claim 4
Dependent Claim
22 words
The bio-absorbable copolymer according to claim 2, wherein the optically active lactide is L-(-)-lactide having a melting point of about 95°-98° C.
Claim 5
Dependent Claim
22 words
The bio-absorbable copolymer according to claim 2, wherein the optically inactive lactide is D,L-lactide having a melting point of about 115°-129° C.
Claim 6
Dependent Claim
25 words
The bio-absorbable copolymer according to claim 1, wherein said polymer comprises about 75% by weight of epsilon caprolactone and about 25% by weight of lactide.
Claim 7
Dependent Claim
100 words
A bio-compatible composition suitable for fabricating a surgical article for the repair or replacement of a part of the body of a human or animal comprising a composite of a bio-absorbable copolymer of lactide and epsilon caprolactone, wherein epsilon caprolactone is present in amounts of 60-95% by weight and said lactide is present in amounts of 5-40% by weight, and wherein said copolymer is tough, elastic, has good tensile strength and elongation to failure in excess of 2000% and is non-brittle and non-rigid, and at least one substrate of a plurality of carbon fibers, said fibers having a longitudinal axis.
Claim 8
Dependent Claim
100 words
A bio-compatible composition suitable for fabricating a surgical article for the repair or replacement of a part of the body of a human or animal comprising a composite of a bio-absorbable copolymer of lactide and epsilon caprolactone, wherein epsilon caprolactone is present in amounts of 60-95% by weight and said lactide is present in amounts of 5-40% by weight, and wherein said copolymer is tough, elastic, has good tensile strength and elongation to failure in excess of 2000% and is non-brittle and non-rigid, and at least one substrate of a plurality of carbon fibers, said fibers having a longitudinal axis.
Claim 9
Dependent Claim
29 words
The composition according to claim 6, wherein said copolymer of lactide and epsilon caprolactone comprises about 75% by weight of epsilon caprolactone and about 25% by weight of lactide.
Claim 10
Dependent Claim
27 words
The composition according to claim 6, wherein the longitudinal axes of the carbon fibers in each at least one substrate are oriented in substantially the same direction.
Claim 11
Dependent Claim
26 words
The composition according to claim 6, wherein each of said carbon fibers has a diameter in the range of from about 5 to about 15 microns.
Claim 12
Dependent Claim
19 words
The composition according to claim 9, wherein each of said carbon fibers has a diameter of about 10 microns.
Claim 13
Dependent Claim
21 words
The composition according to claim 6, wherein said composite contains from about 30 to about 95%, by weight, of carbon fibers.
Claim 14
Dependent Claim
17 words
The composition according to claim 11, wherein said composite contains about 90% by weight, of carbon fibers.
Claim 15
Dependent Claim
28 words
The composition according to claim 6, wherein said composite comprises said at least one substrate of carbon fibers coated with said bio-absorbable copolymer of lactide and epsilon caprolactone.
Claim 16
Dependent Claim
28 words
The composition according to claim 6, wherein said composite comprises said bio-absorbable copolymer of lactide and epsilon caprolactone filled with said at least one substrate of carbon fibers.
Claim 17
Dependent Claim
17 words
The composition according to claim 6, wherein said substrate comprises a substantially uniplanar layer of carbon fibers.
Claim 18
Dependent Claim
102 words
A bio-compatible surgical article, having a longitudinal axis, for the repair or replacement of a tendon or ligament comprising at least one substrate of a plurality of carbon fibers coated with a bio-absorbable copolymer of lactide and epsilon caprolactone, wherein said epsilon caprolactone is present in amounts of 60-95% by weight and said lactide is present in amounts of 5-40% by weight, and wherein said copolymer is tough, elastic, has good tensile strength and elongation to failure in excess of 2000% and is non-brittle and non-rigid, and said carbon fibers are oriented substantially parallel to each other and to said longitudinal axis.
Claim 19
Dependent Claim
102 words
A bio-compatible surgical article, having a longitudinal axis, for the repair or replacement of a tendon or ligament comprising at least one substrate of a plurality of carbon fibers coated with a bio-absorbable copolymer of lactide and epsilon caprolactone, wherein said epsilon caprolactone is present in amounts of 60-95% by weight and said lactide is present in amounts of 5-40% by weight, and wherein said copolymer is tough, elastic, has good tensile strength and elongation to failure in excess of 2000% and is non-brittle and non-rigid, and said carbon fibers are oriented substantially parallel to each other and to said longitudinal axis.
Claim 20
Dependent Claim
30 words
The surgical article according to claim 16 wherein said copolymer of lactide and epsilon caprolactone comprises about 75% by weight of epsilon caprolactone and about 25% by weight of lactide.
Claim 21
Dependent Claim
27 words
The surgical article according to claim 16, wherein each of said carbon fibers has a diameter in the range of from about 5 to about 15 microns.
Claim 22
Dependent Claim
20 words
The surgical article according to claim 18, wherein each of said carbon fibers has a diameter of about 10 microns.
Claim 23
Dependent Claim
23 words
The surgical article according to claim 16, wherein said article comprises from about 30 to about 95% by weight, of said carbon fibers.
Claim 24
Dependent Claim
19 words
The surgical article according to claim 20, wherein said article comprises about 90% by weight of said carbon fibers.
Claim 25
Independent Claim
141 words
A method for repairing a damaged ligament comprising overlaying the damaged part of said ligament with a bio-compatible surgical article, having a longitudinal axis, comprising at least one substrate of a plurality of carbon fibers, having a longitudinal axis, coated with a bio-absorbable copolymer of lactide and epsilon caprolactone, and said epsilon caprolactone is present in amounts of 60-95% by weight and said lactide is present in amounts of 5-40% by weight, and wherein said copolymer is tough, elastic, has good tensile strength and elongation to failure in excess of 2000% and is non-brittle and non-rigid such that a longitudinal axes of the carbon fibers are substantially parallel to the longitudinal axes of the fibrous tissue of said ligament and securing said surgical article to said ligament or tissue connective therewith at sites on opposite sides of said damaged portions thereof.
Claim 26
Independent Claim
141 words
A method for repairing a damaged ligament comprising overlaying the damaged part of said ligament with a bio-compatible surgical article, having a longitudinal axis, comprising at least one substrate of a plurality of carbon fibers, having a longitudinal axis, coated with a bio-absorbable copolymer of lactide and epsilon caprolactone, and said epsilon caprolactone is present in amounts of 60-95% by weight and said lactide is present in amounts of 5-40% by weight, and wherein said copolymer is tough, elastic, has good tensile strength and elongation to failure in excess of 2000% and is non-brittle and non-rigid such that a longitudinal axes of the carbon fibers are substantially parallel to the longitudinal axes of the fibrous tissue of said ligament and securing said surgical article to said ligament or tissue connective therewith at sites on opposite sides of said damaged portions thereof.
Claim 27
Independent Claim
141 words
A method for repairing a damaged tendon comprising overlaying the damaged part of said tendon with a bio-compatible surgical article, having a longitudinal axis, comprising at least one substrate of a plurality of carbon fibers, having a longitudinal axis, coated with a bioabsorbable copolymer of lactide and epsilon caprolactone, and said epsilon caprolactone is present in amounts of 60-95% by weight and said lactide is present in amounts of 5-40% by weight, and wherein said copolymer is tought, elastic, has good tensile strength and elongation to failure in excess of 2000% and is non-brittle and non-rigid such that a longitudinal axes of the carbon fibers are substantially parallel to the longitudinal axes of the fibrous tissue of said tendon and securing said surgical article to said tendon or tissue connective therewith at sites on opposite sides of said damaged portions thereof.
Claim 28
Independent Claim
141 words
A method for repairing a damaged tendon comprising overlaying the damaged part of said tendon with a bio-compatible surgical article, having a longitudinal axis, comprising at least one substrate of a plurality of carbon fibers, having a longitudinal axis, coated with a bioabsorbable copolymer of lactide and epsilon caprolactone, and said epsilon caprolactone is present in amounts of 60-95% by weight and said lactide is present in amounts of 5-40% by weight, and wherein said copolymer is tought, elastic, has good tensile strength and elongation to failure in excess of 2000% and is non-brittle and non-rigid such that a longitudinal axes of the carbon fibers are substantially parallel to the longitudinal axes of the fibrous tissue of said tendon and securing said surgical article to said tendon or tissue connective therewith at sites on opposite sides of said damaged portions thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-02-16 | 1990-08-18 | 1991-02-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-02-16 | 1994-08-18 | 1995-02-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-02-16 | 1998-08-18 | 1999-02-17 | $7700.00 | Window Closed / Lapsed |