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Slippery biaxially stretched polyester films

Assignee: Teijin Ltd
•
Filing: 1982-01-11
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Granted: 1984-03-27
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Expires: 2002-01-11
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Abstract

Abstract A process for producing a slippery biaxially stretched polyester film, which comprises coating one or both surfaces, preferably one surface, of a running polyester film, before the completion of its crystalline orientation, with an aqueous solution or dispersion containing (A) a metal salt having the composition of the following formula ##STR1## wherein Me represents a metal ion having a valence of 2 to 6, R is H or CH 3 , X is one equivalent of an anion, y is 1-6, z is 0-2, w is 0-8, and p is a number equal to the quotient obtained by dividing the total of y+2z+w by the atomic valence of Me, provided that when y is 2 or more, two or more R groups may be identical or different, when w is 2 or more, two or more X ions may be identical or different, and the group ##STR2## in the case of R=CH 3 is contained in a number of not more than 2 for each Me, and (B) a film-forming polymeric compound, a monomer thereof, or a mixture of these; and thereafter heating the coating, before completion of the crystalline orientation of the film, to convert it on the film surface into numerous minute protrusions substantially having form retention; and a slippery biaxially stretched polyester film having a substantially continuous coating with numerous protrusions substantially having form retention, said coating being formed substantially all over on at least one surface of the film and at least comprising a metal salt having the composition of formula (I) above and a film-forming polymeric compound.

Inventors

  • 👤 Tamaki Kanai
  • 👤 Hirofumi Yoshikawa
  • 👤 Takashi Yamagishi
  • 👤 Kenji Suzuki
  • 👤 Yoshikatsu Ohta

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 10:36
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; B; B05; B05D; B05D5/00; B05D5/08; B05D7/00; B05D7/02; B05D7/04; C09; C09D; C09D4/00; G; G03; G03C; G03C1/00; G03C1/76; G03C1/795; G03C1/7954; G11; G11B; G11B5/00; G11B5/62; G11B5/68; G11B5/70; G11B5/7013; C08J2367/00; C08J2367/02; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/24; Y10T428/24355; Y10T428/24372; Y10T428/24413; Y10T428/24479; Y10T428/24612; Y10T428/25; Y10T428/256; Y10T428/31504; Y10T428/31786

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 227 words
A slippery biaxially stretched polyester film having a substantially continuous coating with numerous protrusions substantially having form retention, said coating being formed substantially all over on at least one surface of the film and at least comprising a film-forming polymeric compound and a metal salt having the composition of formula (I) ##STR9## wherein Me represents a metal ion having a valence of 2 to 6, R is a hydrogen atom or a methyl group, X is one equivalent of an anion, y is a number of from 1 to 6, z is a number of from 0 to 2, w is a number of from 0 to 8, and p is a number equal to the quotient obtained by dividing the total of y+2z+w by the atomic valence of Me, provided that when y is a number of 2 or more, two or more R groups may be identical or different, when w is a number of 2 or more, two or more X ions may be identical or different, and the group ##STR10## in the case of R=methyl is contained in a number of not more than 2 for each Me, and said coating consisting of a substantially continuous base coating layer in contact with the surface of the polyester base film and numerous minute protrusions integral with the base coating layer and extending outwardly therefrom.
Claim 2
Dependent Claim 227 words
A slippery biaxially stretched polyester film having a substantially continuous coating with numerous protrusions substantially having form retention, said coating being formed substantially all over on at least one surface of the film and at least comprising a film-forming polymeric compound and a metal salt having the composition of formula (I) ##STR9## wherein Me represents a metal ion having a valence of 2 to 6, R is a hydrogen atom or a methyl group, X is one equivalent of an anion, y is a number of from 1 to 6, z is a number of from 0 to 2, w is a number of from 0 to 8, and p is a number equal to the quotient obtained by dividing the total of y+2z+w by the atomic valence of Me, provided that when y is a number of 2 or more, two or more R groups may be identical or different, when w is a number of 2 or more, two or more X ions may be identical or different, and the group ##STR10## in the case of R=methyl is contained in a number of not more than 2 for each Me, and said coating consisting of a substantially continuous base coating layer in contact with the surface of the polyester base film and numerous minute protrusions integral with the base coating layer and extending outwardly therefrom.
Claim 3
Dependent Claim 23 words
The polyester film of claim 1 which has a dual surface structure having the continuous coating only on one surface of the film.
Claim 4
Dependent Claim 87 words
The polyester film of claim 1 or 2 wherein the numerous minute protrusions substantially having form retention have a percent form retention (F, %), defined by the following equation, of 100 to about 75%, ##EQU5## wherein (μ k ) A is the coefficient of dynamic friction measured by the method described in the specification by means of a reciprocating friction tester in the 20th sliding cycle, and (μ k ) B is the coefficient of dynamic friction measured in the same way in the first sliding cycle.
Claim 5
Dependent Claim 28 words
The polyester film of claim 1 wherein the continuous coating further includes a water-insoluble solid substance having an average particle diameter of about 0.005 to about 1.0 micron.
Claim 6
Dependent Claim 28 words
The polyester film of claim 1 wherein the continuous coating is formed at a rate of about 2.5 to about 200 mg per m 2 of the film.
Claim 7
Dependent Claim 45 words
The polyester film of claim 1 wherein the polyester base film is composed of an aromatic homo- or co-polyester composed of an aromatic dibasic acid as a main acid component and an aliphatic diol having 2 to 6 carbon atoms as a main glycol component.

References Cited (Backward Citations)

JPS5232970A Cited
US4348446A Cited
JPS5610455A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-03-27 1987-09-26 1988-03-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-03-27 1991-09-26 1992-03-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-03-27 1995-09-26 1996-03-27 $7700.00 Window Closed / Lapsed

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