US4348446A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyester film having improved slipperiness
Assignee: Teijin Ltd
•
Filing: 1980-09-04
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Granted: 1982-09-07
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Expires: 2000-09-04
Abstract
Abstract A biaxially oriented polyester film containing fine particles of insoluble inert substance, has a kinetic coefficient of friction of not more than 0.3, and has microscopic protrusions integrated thereto, said protrusion having an peak-to-valley height of not more than 1 micron mostly range of 0.2 to 0.5 micron. The film having improved slipperiness is useful as the base film of magnetic recording tape for a video tape recorder or a computer data storage.
Inventors
- 👤 Yukio Mitsuishi
- 👤 Shigeru Shiozaki
- 👤 Takao Chujo
- 👤 Takeyuki Yokoyama
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 00:29
CPC Classifications
C; C08; C08K; C08K7/00; C08K3/00; C08K3/01; C08K3/013; Y; Y10; Y10S; Y10S428/00; Y10S428/90; Y10T; Y10T428/00; Y10T428/24; Y10T428/24355; Y10T428/24372; Y10T428/24413; Y10T428/24421; Y10T428/2443; Y10T428/25; Y10T428/251; Y10T428/256; Y10T428/258; Y10T428/259; Y10T428/31; Y10T428/31504; Y10T428/31786; Y10T428/31797
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
318 words
A magnetic recording tape comprising a substrate with a magnetic coating thereon, said magnetic recording tape having good transportability and high abrasion resistance and being free of a back lubricant layer, said substrate consisting of a biaxially oriented polyester film having a kinetic friction coefficient at a tape speed of 25 cm/sec in the range from 0.05 to 0.25, and having at least one rough surface with protrusions integrated thereto, said protrusions having a maximum size of 1 micron in height and having an average peak-to-valley height of not more than about 0.55 micron and being originated from an insoluble inert substance having a representative particle diameter of not more than 0.55 micron incorporated into said polyester in an amount ranging from 0.08 to 2% by weight, wherein the height denoted by h (micron) in the range 1.0≧h>0.75, is not more than 14/mm 2 , 0.75≧h>0.5, is from 5 to 150/mm 2 , and 0.5≧h, is not less than 40/mm 2 , and wherein the insoluble inert substance consists essentially of not more than 8% by weight of a fraction having particle diameters, expressed as d in microns, 2.5≧d>1.5 and from 40 to 80% by weight of a fraction of 0.5≧d, said film having an abrasion resistance grade of at least 2 when transported at a speed of 25 cm/sec at 25° C. and 60% relative humidity with said rough surface in contact with an SUS 27 stationary rod wrapped with tissue paper having a surface roughness of 0.35, an outer diameter of 20 mm φ with a wrapping arc angle of θ=(152/180) π radius (152°), said abrasion resistance grade being defined as follows: Grade 1: free from white powder; Grade 2: a small amount of white powder; Grade 3: white powder speckled all over the tissue paper; Grade 4: white powder more than Grade 3; Grade 5: white powder covering the whole surface of the tissue paper.
Claim 2
Dependent Claim
318 words
A magnetic recording tape comprising a substrate with a magnetic coating thereon, said magnetic recording tape having good transportability and high abrasion resistance and being free of a back lubricant layer, said substrate consisting of a biaxially oriented polyester film having a kinetic friction coefficient at a tape speed of 25 cm/sec in the range from 0.05 to 0.25, and having at least one rough surface with protrusions integrated thereto, said protrusions having a maximum size of 1 micron in height and having an average peak-to-valley height of not more than about 0.55 micron and being originated from an insoluble inert substance having a representative particle diameter of not more than 0.55 micron incorporated into said polyester in an amount ranging from 0.08 to 2% by weight, wherein the height denoted by h (micron) in the range 1.0≧h>0.75, is not more than 14/mm 2 , 0.75≧h>0.5, is from 5 to 150/mm 2 , and 0.5≧h, is not less than 40/mm 2 , and wherein the insoluble inert substance consists essentially of not more than 8% by weight of a fraction having particle diameters, expressed as d in microns, 2.5≧d>1.5 and from 40 to 80% by weight of a fraction of 0.5≧d, said film having an abrasion resistance grade of at least 2 when transported at a speed of 25 cm/sec at 25° C. and 60% relative humidity with said rough surface in contact with an SUS 27 stationary rod wrapped with tissue paper having a surface roughness of 0.35, an outer diameter of 20 mm φ with a wrapping arc angle of θ=(152/180) π radius (152°), said abrasion resistance grade being defined as follows: Grade 1: free from white powder; Grade 2: a small amount of white powder; Grade 3: white powder speckled all over the tissue paper; Grade 4: white powder more than Grade 3; Grade 5: white powder covering the whole surface of the tissue paper.
Claim 3
Dependent Claim
27 words
A polyester film of claim 1, wherein the inert substance added to the polyester comprises 20 to 50% by weight particles having particle diameters [d(micron)] of 1.5≧d>0.5.
Claim 4
Dependent Claim
32 words
A polyester film of claim 2 wherein the height denoted by h in the range of 1.0≧h>0.75 is 8 or less, 0.75≧h>0.5 is 60 or less and 0.5≧h>0.25 is 100 to 400.
Claim 5
Dependent Claim
45 words
A polyester film of claim 3 wherein the insoluble inert substance consists essentially of 0-4% by weight of a fraction having particle diameters, expressed as d in microns, 2.5≧d≧1.5, 20-40% by weight of a fraction 1.5≧d≧0.5 and from 50-80% by weight of a fraction 0.5≧d.
Claim 6
Dependent Claim
23 words
A polyester film of claim 4 wherein the insoluble inert substance is incorporated into the polyester in an amount of 0.10-5% by weight.
Claim 7
Dependent Claim
26 words
A polyester film of claim 5 wherein the fraction 2.5≧d≧1.5 includes 0-3% of a fraction 2.5≧d>2.0 and the fraction 1.5≧d≧0.5 includes 4-20% of a fraction 1.5≧d>1.0.
Claim 8
Dependent Claim
33 words
A polyester film of claim 6, wherein the representative particles diameter, which defines the diameter corresponding to the 50% by weight of the particle size-amount cumulative distribution curve, is 0.43 micron or less.
Claim 9
Dependent Claim
18 words
A polyester film of claim 6 wherein the thickness of said film is about 3 to 100 microns.
Claim 10
Dependent Claim
11 words
A film of claim 1, wherein the polyester is polyethylene terephthalate.
Claim 11
Dependent Claim
14 words
A film of claim 1, wherein said protrusions originate from said insoluble inert substance.
Claim 12
Dependent Claim
38 words
A film of claim 1, wherein the surface protrusions having heights denoted by h (micron) of the range 1.0≧h>0.75 is 0 to 10 mm 2 , 0.74≧h>0.5 is 10 to 100/mm 2 and 0.5≧h>0.25 is >80/mm 2 .
Claim 13
Dependent Claim
63 words
A polyester film of claim 1, wherein the insoluble inert substance is selected from the group consisting of MgO, ZnO, MgCO 3 , CaCO 3 , CaSO 4 , BaSO 4 , Al 2 O 3 , SiO 2 , TiO 2 and Ca and Mn salts of terephthalic acid, kaolin, china clay, diatomaceous earth, aluminosilicates, their hydrates, carbon black and calcium phosphate.
Claim 14
Dependent Claim
32 words
A polyester film of claim 1, wherein said residue is selected from the group consisting of alkali metal compounds, alkaline earth metal compounds, antimony trioxide, germanium compounds, titanium compounds and phosphorous compounds.
Claim 15
Dependent Claim
33 words
A polyester film of claim 1, wherein the representative particle diameter, which defines the diameter corresponding to the 50% by weight of the particle size-amount cumulative distribution curve, is 0.55 micron or less.
Claim 16
Dependent Claim
30 words
A polyester film of claim 1 wherein said film carries a magnetic recording layer on one side thereof but is free from a lubricating layer on the other side thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-09-06 | 1986-03-08 | 1986-09-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-09-06 | 1990-03-08 | 1990-09-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-09-06 | 1994-03-08 | 1994-09-07 | $7700.00 | Window Closed / Lapsed |