Patent US5696178A successfully refreshed from Google Patents.
US5696178A
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Absorbable polyalkylene diglycolates
Assignee: Ethicon Inc
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Filing: 1996-07-22
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Granted: 1997-12-09
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Expires: 2016-07-22
Abstract
Abstract Absorbable polymers and blends of acrylated poly(alkylene diglycolate)s and aliphatic polyesters based on lactone monomers such as lactide, glycolide, e-caprolactone, p-dioxanone, and trimethylene carbonate are described. The polymers and blends exhibit a broad range of properties, useful in a variety of medical devices.
Inventors
- 👤 Kevin Cooper
- 👤 Angelo Scopelianos
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 14:33
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/06; C08L67/07; A; A61; A61L; A61L15/00; A61L15/16; A61L15/22; A61L15/225; A61L15/26; A61L24/00; A61L24/04; A61L24/043; A61L24/046; A61L26/00; A61L26/0009; A61L26/0019; A61L26/0052; A61L27/00; A61L27/14; A61L27/18; A61L27/26; A61L31/00; A61L31/04; A61L31/041; A61L31/06; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/672; C08G63/91; C08G63/914; C08L67/02; C08L67/025; C08L67/04
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
169 words
An absorbable, block segmented statistically random, or graft copolymer comprising the reaction product of: a) an absorbable, biocompatible poly(alkylene diglycolate) comprising the reaction product of: 1. an acid or ester of diglycolic acid; and, 2. an alcohol selected from the group consisting of glycerol, pentaerythitol, trimethylolpropane, hydroxyl terminated poly(ethylene glycol)s, ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butylene glycol, dipropylene glycol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, and 1,8-octanediol, wherein the poly(alkylene diglycolate) comprises about 10 mole percent to about 90 mole percent of repeating units with tri-, tetra-alcohols, and hydroxyl terminated poly(ethylene glycol)s, and wherein the balance of the poly(alkylene diglycolate) comprises repeating units with diol alcohols, and, b) a polyester formed from lactone monomers selected from the group consisting of p-dioxanone, e-caprolactone, delta-valerolactone, beta-butyrolactone, epsilon-decalactone, 2,5-diketomorpholine, pivalolactone, alpha, alpha-diethylpropiolactone, ethylene oxalate, 3-methyl-1,4-dioxane-2,5-dione, 3,3-diethyl-1,4-dioxan-2,5-dione, gamma-butyrolactone, 1,4-dioxepan-2-one, 1,5-dioxepan-2-one, 1,4-dioxan-2-one, 6,8-dioxabicycloctane-7-one, and combinations of two and more thereof, wherein the copolymer is comprised of about 10 weight percent to about 90 weight percent of poly(alkylene diglycolate), and wherein the poly(alkylene diglycolate) additionally comprised pendant acrylate groups.
Claim 2
Dependent Claim
169 words
An absorbable, block segmented statistically random, or graft copolymer comprising the reaction product of: a) an absorbable, biocompatible poly(alkylene diglycolate) comprising the reaction product of: 1. an acid or ester of diglycolic acid; and, 2. an alcohol selected from the group consisting of glycerol, pentaerythitol, trimethylolpropane, hydroxyl terminated poly(ethylene glycol)s, ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butylene glycol, dipropylene glycol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, and 1,8-octanediol, wherein the poly(alkylene diglycolate) comprises about 10 mole percent to about 90 mole percent of repeating units with tri-, tetra-alcohols, and hydroxyl terminated poly(ethylene glycol)s, and wherein the balance of the poly(alkylene diglycolate) comprises repeating units with diol alcohols, and, b) a polyester formed from lactone monomers selected from the group consisting of p-dioxanone, e-caprolactone, delta-valerolactone, beta-butyrolactone, epsilon-decalactone, 2,5-diketomorpholine, pivalolactone, alpha, alpha-diethylpropiolactone, ethylene oxalate, 3-methyl-1,4-dioxane-2,5-dione, 3,3-diethyl-1,4-dioxan-2,5-dione, gamma-butyrolactone, 1,4-dioxepan-2-one, 1,5-dioxepan-2-one, 1,4-dioxan-2-one, 6,8-dioxabicycloctane-7-one, and combinations of two and more thereof, wherein the copolymer is comprised of about 10 weight percent to about 90 weight percent of poly(alkylene diglycolate), and wherein the poly(alkylene diglycolate) additionally comprised pendant acrylate groups.
Claim 3
Dependent Claim
38 words
The copolymer of claim 1 wherein the polyester is formed from lactone monomers selected from the group consisting of glycolide and lactide, wherein the copolymer comprises about 55 weight percent to about 95 weight percent of poly(alkylene diglycolate).
Claim 4
Dependent Claim
21 words
The graft copolymer of claim 2 wherein the pendant acrylate groups are formed from an unsaturated acid halide comprising acryloyl chloride.
Claim 5
Dependent Claim
21 words
The graft copolymer of claim 1 wherein the pendant acrylate groups are formed from an unsaturated acid halide comprising acryloyl chloride.
Claim 6
Dependent Claim
67 words
The copolymer of claim 1 wherein the copolymer is cured via free radical photopolymerization, utilizing irradiation selected from the group consisting of visible and long wavelength ultraviolet radiation at a wavelength of about 150 to about 750 nm and laser light at about 514 nm, and free radical, photosensitive initiators selected from the group consisting of ethyl eosin, 2-methoxy-2-phenyl acetophenone, 2,2-dimethoxy-2-phenyl acetophenone, other acetophenone derivatives, and camphorquinone.
Claim 7
Dependent Claim
161 words
An absorbable polymer blend, comprising: a) an absorbable, biocompatible poly(alkylene diglycolate) of comprising the reaction product of: 1. an acid or ester of diglycolic acid; and, 2. an alcohol selected from the group consisting of glycerol, pentaerythitol, trimethylolpropane, hydroxyl terminated poly(ethylene glycol)s, ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butylene glycol, dipropylene glycol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, and 1,8-octanediol, wherein the poly(alkylene diglycolate) comprises about 10 mole percent to about 90 mole percent of repeating units with tri-, tetra-alcohols, and hydroxyl terminated poly(ethylene glycol)s, and wherein the balance of the poly(alkylene diglycolate) comprises repeating units with diol alcohols, and, b) a polyester formed from lactone monomers selected from the group consisting of p-dioxanone, e-caprolactone, delta-valerolactone, beta-butyrolactone, epsilon-decalactone, 2,5-diketomorpholine, pivalolactone, alpha, alpha-diethylpropiolactone, ethylene oxalate, 3-methyl-1,4-dioxane-2,5-dione, 3,3-diethyl-1,4-dioxan-2,5-dione, gamma-butyrolactone, 1,4-dioxepan-2-one, 1,5-dioxepan-2-one, 1,4-dioxan-2-one, 6,8-dioxabicycloctane-7-one, and combinations of two and more thereof, wherein the blend is comprised of about 10 weight percent to about 90 weight percent of poly(alkylene diglycolate), and wherein the poly(alkylene diglycolate) additionally comprises pendant acrylate groups.
Claim 8
Dependent Claim
161 words
An absorbable polymer blend, comprising: a) an absorbable, biocompatible poly(alkylene diglycolate) of comprising the reaction product of: 1. an acid or ester of diglycolic acid; and, 2. an alcohol selected from the group consisting of glycerol, pentaerythitol, trimethylolpropane, hydroxyl terminated poly(ethylene glycol)s, ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butylene glycol, dipropylene glycol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, and 1,8-octanediol, wherein the poly(alkylene diglycolate) comprises about 10 mole percent to about 90 mole percent of repeating units with tri-, tetra-alcohols, and hydroxyl terminated poly(ethylene glycol)s, and wherein the balance of the poly(alkylene diglycolate) comprises repeating units with diol alcohols, and, b) a polyester formed from lactone monomers selected from the group consisting of p-dioxanone, e-caprolactone, delta-valerolactone, beta-butyrolactone, epsilon-decalactone, 2,5-diketomorpholine, pivalolactone, alpha, alpha-diethylpropiolactone, ethylene oxalate, 3-methyl-1,4-dioxane-2,5-dione, 3,3-diethyl-1,4-dioxan-2,5-dione, gamma-butyrolactone, 1,4-dioxepan-2-one, 1,5-dioxepan-2-one, 1,4-dioxan-2-one, 6,8-dioxabicycloctane-7-one, and combinations of two and more thereof, wherein the blend is comprised of about 10 weight percent to about 90 weight percent of poly(alkylene diglycolate), and wherein the poly(alkylene diglycolate) additionally comprises pendant acrylate groups.
Claim 9
Dependent Claim
38 words
The blend of claim 6 wherein the polyester is formed from lactone monomers selected from the group consisting of glycolide and lactide, wherein the blend comprises about 55 weight percent to about 95 weight percent of poly(alkylene diglycolate).
Claim 10
Dependent Claim
20 words
The blend of claim 7 wherein the pendant acrylate groups are formed from an unsaturated acid halide comprising acryloyl chloride.
Claim 11
Dependent Claim
20 words
The blend of claim 6 wherein the pendant acrylate groups are formed from an unsaturated acid halide comprising acryloyl chloride.
Claim 12
Dependent Claim
67 words
The blend of claim 6 wherein the blend is cured via free radical photopolymerization, utilizing irradiation selected from the group consisting of visible and long wavelength ultraviolet radiation at a wavelength of about 150 to about 750 nm and laser light at about 514 nm, and free radical, photosensitive initiators selected from the group consisting of ethyl eosin, 2-methoxy-2-phenyl acetophenone, 2,2-dimethoxy-2-phenyl acetophenone, other acetophenone derivatives, and camphorquinone.
Claim 13
Dependent Claim
177 words
An absorbable device for use in medical applications, the medical device comprising a block, segmented, statistically random, or graft copolymer comprising the reaction product of: a) an absorbable, biocompatible poly(alkylene diglycolate) of comprising the reaction product of: 1. an acid or ester of diglycolic acid; and, 2. an alcohol selected group consisting of glycerol, pentaerythitol, trimethylolpropane, hydroxyl terminated poly(ethylene glycol)s, ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butylene glycol, dipropylene glycol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, and 1,8-octanediol, wherein the poly(alkylene diglycolate) comprises about 10 mole percent to about 90 mole percent of repeating units with tri-, tetra-alcohols, and hydroxyl terminated poly(ethylene glycol)s, and wherein the balance of the poly(alkylene diglycolate) comprises repeating units with diol alcohols, and, b) a polyester formed from lactone monomers selected from the group consisting of p-dioxanone, e-caprolactone, delta-valerolactone, beta-butyrolactone, epsilon-decalactone, 2,5-diketomorpholine, pivalolactone, alpha, alpha-diethylpropiolactone, ethylene oxalate, 3-methyl-1,4-dioxane-2,5-dione, 3,3-diethyl-1,4-dioxan-2,5-dione, gamma-butyrolactone, 1,4-dioxepan-2-one, 1,5-dioxepan-2-one, 1,4-dioxan-2-one, and combinations of two and more thereof, wherein the copolymer is comprised of about 10 weight percent to about 90 weight percent of poly(alkylene diglycolate), wherein the poly(alkylene diglycolate) additionally comprises pendant acrylate groups.
Claim 14
Dependent Claim
177 words
An absorbable device for use in medical applications, the medical device comprising a block, segmented, statistically random, or graft copolymer comprising the reaction product of: a) an absorbable, biocompatible poly(alkylene diglycolate) of comprising the reaction product of: 1. an acid or ester of diglycolic acid; and, 2. an alcohol selected group consisting of glycerol, pentaerythitol, trimethylolpropane, hydroxyl terminated poly(ethylene glycol)s, ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butylene glycol, dipropylene glycol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, and 1,8-octanediol, wherein the poly(alkylene diglycolate) comprises about 10 mole percent to about 90 mole percent of repeating units with tri-, tetra-alcohols, and hydroxyl terminated poly(ethylene glycol)s, and wherein the balance of the poly(alkylene diglycolate) comprises repeating units with diol alcohols, and, b) a polyester formed from lactone monomers selected from the group consisting of p-dioxanone, e-caprolactone, delta-valerolactone, beta-butyrolactone, epsilon-decalactone, 2,5-diketomorpholine, pivalolactone, alpha, alpha-diethylpropiolactone, ethylene oxalate, 3-methyl-1,4-dioxane-2,5-dione, 3,3-diethyl-1,4-dioxan-2,5-dione, gamma-butyrolactone, 1,4-dioxepan-2-one, 1,5-dioxepan-2-one, 1,4-dioxan-2-one, and combinations of two and more thereof, wherein the copolymer is comprised of about 10 weight percent to about 90 weight percent of poly(alkylene diglycolate), wherein the poly(alkylene diglycolate) additionally comprises pendant acrylate groups.
Claim 15
Dependent Claim
43 words
The absorbable device of claim 11 wherein the polyester formed from lactone monomers comprising a monomer selected from the group consisting of glycolide and lactide, wherein the copolymer is comprised of about 55 weight percent to about 95 weight percent of poly(alkylene diglycolate).
Claim 16
Dependent Claim
168 words
An absorbable device for use in medical applications, the medical device comprising a blend of: a) an absorbable, biocompatible poly(alkylene diglycolate) comprising the reaction product of: 1. an acid or ester of diglycolic acid; and, 2. an alcohol selected from the group consisting of glycerol, pentaerythitol, trimethylolpropane, hydroxyl terminated poly(ethylene glycol)s, ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butylene glycol, dipropylene glycol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, and 1,8-octanediol, wherein the poly(alkylene diglycolate) comprises about 10 mole percent to about 90 mole percent of repeating units with tri-, tetra-alcohols, and hydroxyl terminated poly(ethylene glycol)s, and wherein the balance of the poly(alkylene diglycolate) comprises repeating units with diol alcohols, and, b) a polyester formed from lactone monomers selected from the group consisting of p-dioxanone, e-caprolactone, delta-valerolactone, beta-butyrolactone, epsilon-decalactone, 2,5-diketomorpholine, pivalolactone, alpha, alpha-diethylpropiolactone, ethylene oxalate, 3-methyl-1,4-dioxane-2,5-dione, 3,3-diethyl-1,4-dioxan-2,5-dione, gamma-butyrolactone, 1,4-dioxepan-2-one, 1,5-dioxepan-2-one, 1,4-dioxan-2-one, and combinations of two and more thereof, wherein the blend is comprised of about 10 weight percent to about 90 weight percent of poly(alkylene diglycolate), wherein the poly(alkylene diglycolate) additionally comprises pendant acrylate groups.
Claim 17
Dependent Claim
168 words
An absorbable device for use in medical applications, the medical device comprising a blend of: a) an absorbable, biocompatible poly(alkylene diglycolate) comprising the reaction product of: 1. an acid or ester of diglycolic acid; and, 2. an alcohol selected from the group consisting of glycerol, pentaerythitol, trimethylolpropane, hydroxyl terminated poly(ethylene glycol)s, ethylene glycol, 1,2-propanediol, 1,3-propanediol, 1,4-butylene glycol, dipropylene glycol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, and 1,8-octanediol, wherein the poly(alkylene diglycolate) comprises about 10 mole percent to about 90 mole percent of repeating units with tri-, tetra-alcohols, and hydroxyl terminated poly(ethylene glycol)s, and wherein the balance of the poly(alkylene diglycolate) comprises repeating units with diol alcohols, and, b) a polyester formed from lactone monomers selected from the group consisting of p-dioxanone, e-caprolactone, delta-valerolactone, beta-butyrolactone, epsilon-decalactone, 2,5-diketomorpholine, pivalolactone, alpha, alpha-diethylpropiolactone, ethylene oxalate, 3-methyl-1,4-dioxane-2,5-dione, 3,3-diethyl-1,4-dioxan-2,5-dione, gamma-butyrolactone, 1,4-dioxepan-2-one, 1,5-dioxepan-2-one, 1,4-dioxan-2-one, and combinations of two and more thereof, wherein the blend is comprised of about 10 weight percent to about 90 weight percent of poly(alkylene diglycolate), wherein the poly(alkylene diglycolate) additionally comprises pendant acrylate groups.
Claim 18
Dependent Claim
44 words
The absorbable device of claim 13 wherein the polyester is formed from lactone monomers comprising a monomer selected from the group consisting of glycolide and lactide, wherein the blend is comprised of about 55 weight percent to about 95 weight percent of poly(alkylene diglycolate).
References Cited (Backward Citations)
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