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Phosphor, cathode-ray tube, fluorescent lamp and radiation intensifying screen

Assignee: Toshiba Corp
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Filing: 1994-12-16
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Granted: 1997-07-01
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Expires: 2014-12-16
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Abstract

Abstract Disclosed is a phosphor suitable for use in a cathode-ray tube, a fluorescent lamp, a radiation intensifying screen, which comprises transparent spherical particles having an average particle size of 0.5 to 20 μm and a ratio of the major diameter to the minor diameter of individual particles in the range of 1.0 to 1.5, and ultrafine particles having a diameter of 0.2 μm or less in an amount of 5 wt % or less.

Inventors

  • 👤 Naotoshi Matsuda
  • 👤 Masaaki Tamatani
  • 👤 Keiko Albessard
  • 👤 Miwa Okumura
  • 👤 Takeshi Takahara
  • 👤 Takeo Itou

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 10:20
CPC Classifications
H; H01; H01J; H01J29/00; H01J29/02; H01J29/10; H01J29/18; H01J29/20; C; C09; C09K; C09K11/00; C09K11/08; C09K11/67; C09K11/671; C09K11/77; C09K11/7766; C09K11/7767; C09K11/7769; C09K11/7771; C09K11/7783; C09K11/7784; C09K11/7787; C09K11/7789; G; G21; G21K; G21K4/00; H01J61/00; H01J61/02; H01J61/38; H01J61/42; H01J61/44; G21K2004/06; H01J61/70

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 57 words
A phosphor, comprising: transparent spherical particles having an average particle size of 0.5 to 20 μm and a ratio of the major diameter to the minor diameter of individual particles in the range of 1.0 to 1.5; and ultrafine particles having a diameter of 0.2 μm or less in an amount of 0.001-5 wt % or less.
Claim 2
Dependent Claim 57 words
A phosphor, comprising: transparent spherical particles having an average particle size of 0.5 to 20 μm and a ratio of the major diameter to the minor diameter of individual particles in the range of 1.0 to 1.5; and ultrafine particles having a diameter of 0.2 μm or less in an amount of 0.001-5 wt % or less.
Claim 3
Dependent Claim 101 words
The phosphor according to claim 1, represented by the formula: Ln 2 O 3 :R wherein Ln is at least one element selected from the group consisting of La, Gd, Lu and Y, and R is at least one element selected from the lanthanide group; and comprising, transparent spherical particles having an average particle size of 0.5 to 15 μm and a ratio of the major diameter to the minor diameter of individual particles in the range of 1.0 to 1.5, and ultrafine particles having a diameter of 0.2 μm or less in an amount of 0.001-2 wt % or less.
Claim 4
Dependent Claim 56 words
The phosphor according to claim 2, wherein said R is Eu and the molar ratio of Eu to Ln is 1 to 6%, said R is Tb and the molar ratio of Tb to Ln is 0.1 to 6%, or said R is Pr and the molar ratio of Pr to Ln is 0.01 to 5%.
Claim 5
Dependent Claim 38 words
The phosphor according to claim 2, represented by the formula: Gd 2 O 3 :R wherein R is at least one element selected from the lanthanide group; and at least part of crystalline system is a monoclinic system.
Claim 6
Dependent Claim 56 words
The phosphor according to claim 4, wherein said R is Eu and the molar ratio of Eu to Gd is 1 to 6%; said R is Tb and the molar ratio of Tb to Gd is 0.1 to 6%; or said R is Pr and the molar ratio of Pr to Gd is 0.01 to 5%.
Claim 7
Dependent Claim 36 words
The phosphor according to claim 4, represented by the formula: Gd 2 O 3 :Eu, wherein the content of the monoclinic system is 5 to 100% and the average particle size is 0.5 to 3 μm.
Claim 8
Dependent Claim 101 words
The phosphor according to claim 1, represented by the formula: Ln 2 O 2 S:R wherein Ln is at least one element selected from the group consisting of Y, La, Gd, and Lu, and R is at least one element selected from the lanthanide group; and comprising, transparent spherical particles having an average particle size of 0.5 to 15 μm and a ratio of the major diameter to the minor diameter of individual particles in the range of 1.0 to 1.5, and ultrafine particles having a diameter of 0.2 μm or less in an amount of 0.001-2 wt % or less.
Claim 9
Dependent Claim 56 words
The phosphor according to claim 7, wherein said R is Eu and the molar ratio of Eu to Ln is 2 to 7%; said R is Tb and the molar ratio of Tb to Ln is 0.1 to 6%; or said R is Pr and the molar ratio of Pr to Ln is 0.01 to 0.5%.
Claim 10
Dependent Claim 28 words
The phosphor according to claim 7, having reflectance for visual light of 85% or more when the phosphor is used in a layer having an optically indefinite thickness.
Claim 11
Dependent Claim 88 words
The phosphor according to claim 1, represented by the formula: MWO 4 wherein M is at least one component selected from the group consisting of Ca and Mg; or CaWO 4 :Pb, and comprising, transparent spherical particles having an average particle size of 0.5 to 20 μm and a ratio of the major diameter to the minor diameter of individual particles in the range of 1.0 to 1.5, and ultrafine particles having a diameter of 0.2 μm or less in an amount of 0.001-5 wt % or less.
Claim 12
Dependent Claim 27 words
The phosphor according to claim 10, wherein a content of said ultrafine particles having a diameter of 0.2 μm or less is 0.01 to 2 wt %.

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3.5 Years (Year 4) 2000-06-30 2000-12-30 2001-07-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-06-30 2004-12-30 2005-07-01 $3760.00 Window Closed / Lapsed
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