US5410093A
Expired / Lapsed
US
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Method for removing transesterification catalyst from polyether polyols
Assignee: Invista North America LLC
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Filing: 1994-02-17
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Granted: 1995-04-25
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Expires: 2014-02-17
Abstract
Abstract An improved method for recovering purified poly(tetramethylene ether) glycol or similar polyether polyol from an aqueous solution of polymer containing an alkaline metal catalyst residue involving the addition of a stoichiometric excess of magnesium sulfate or sulfite followed by evaporation of water and separation of molten polymer from precipitated solid phase (i.e., from magnesium hydroxide, alkaline metal sulfate/sulfite, and excess magnesium sulfate/sulfite). Such a process results in essentially complete removal of any basic transesterification catalyst and water without significant lost of poly(tetramethylene ether) glycol or the like.
Inventors
- 👤 Suriyanarayanan Dorai
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 06:46
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/02; C08G65/30
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
130 words
A method for purifying polyether polyol comprising the steps of: (a) contacting an aqueous solution of polyether polyol containing a residual of an alkaline transesterification catalysis with a stoichiometric excess of magnesium sulfate, magnesium sulfite or mixture thereof, wherein said stoichiometric excess is based on amount of said alkaline transesterification catalysis residual; (b) removing water from said aqueous solution of step (a) at a temperature above the melt temperature of said polyether polyol thus producing a molten polyether polyol phase and a precipitated second phase comprising sulfate and/or sulfite salts of the alkaline metal of said transesterification catalyst, magnesium hydroxide, and excess magnesium sulfate and/or sulfide; and (c) separating the molten polyether polyol phase from the precipitated second phase thus recovering polyether polyol substantially free of water and residual catalysis.
Claim 2
Independent Claim
130 words
A method for purifying polyether polyol comprising the steps of: (a) contacting an aqueous solution of polyether polyol containing a residual of an alkaline transesterification catalysis with a stoichiometric excess of magnesium sulfate, magnesium sulfite or mixture thereof, wherein said stoichiometric excess is based on amount of said alkaline transesterification catalysis residual; (b) removing water from said aqueous solution of step (a) at a temperature above the melt temperature of said polyether polyol thus producing a molten polyether polyol phase and a precipitated second phase comprising sulfate and/or sulfite salts of the alkaline metal of said transesterification catalyst, magnesium hydroxide, and excess magnesium sulfate and/or sulfide; and (c) separating the molten polyether polyol phase from the precipitated second phase thus recovering polyether polyol substantially free of water and residual catalysis.
Claim 3
Dependent Claim
18 words
A method according to claim 1 wherein said polyether polyol is poly(tetramethylene ether) glycol or a copolymer thereof.
Claim 4
Dependent Claim
59 words
A method according to claim 1 wherein said alkaline transesterification catalysis is selected from the group consisting of alkali metal hydroxide, alkali metal alkoxide, alkaline earth metal hydroxide, alkaline earth metal alkoxide, and mixtures thereof and said precipitated second phase comprises magnesium hydroxide, sulfate salts of said alkaline transesterification catalysis, and excess magnesium sulfate, magnesium sulfite or mixture thereof.
Claim 5
Dependent Claim
43 words
A method according to claim 2 wherein said contacting an aqueous solution of poly(tetramethylene ether) glycol is with a stoichiometric excess of magnesium sulfate and said precipitated second phase comprises magnesium hydroxide, sulfate salts of said alkaline transesterification catalysis, and excess magnesium sulfate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1998-04-24 | 1998-10-24 | 1999-04-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2002-04-24 | 2002-10-24 | 2003-04-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2006-04-24 | 2006-10-24 | 2007-04-25 | $7700.00 | Window Closed / Lapsed |