US4968524A
Expired / Lapsed
US
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Process for producing a polyacetylene
Assignee: Panasonic Holdings Corp
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Filing: 1988-10-12
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Granted: 1990-11-06
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Expires: 2008-10-12
Abstract
Abstract The present invention relates to an electric material, and particularly it relates to an organic substance having a polyacetylene linkage which exhibits electrical conductivity and nonlinear optical effect. More particularly, the present invention provides a process for producing an organic substance having a polyacetylene linkage which can be utilized, for example, as an electric material, said process comprising immersing a substrate having a hydrophilic surface in a solution of a substance containing an acetylene (--C.tbd.C--) group and a chlorosilane (--SiCl 3 ) group dissolved in a nonaqueous organic solvent, thereby subjecting the substance containing an acetylene group and a chlorosilane group to chemical adsorption on the surface of the substrate, subjecting said substance to polymerization reaction by the use of radiation such as X-rays, electron beams, γ-rays, or the like, and thereby producing a polyacetylene.
Inventors
- 👤 Kazufumi Ogawa
- 👤 Hideharu Tamura
- 👤 Norihisa Mino
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 11:55
CPC Classifications
H; H10; H10K; H10K85/00; H10K85/701; B; B05; B05D; B05D1/00; B05D1/18; B05D1/185; B82; B82Y; B82Y10/00; B82Y20/00; B82Y30/00; B82Y40/00; C; C08; C08F; C08F138/00; G; G02; G02F; G02F1/00; G02F1/35; G02F1/355; G02F1/361; G02F1/3615; G02F1/3618; H10K85/10; H10K85/141; H10K85/143; H10K85/40; H10P; H10P14/00; H10P14/40
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
75 words
A process for producing a polyacetylene which comprises a step of immersing a substrate having a hydrophilic surface in a solution of a substance having a chlorosilane group and a group(s) reactive to energy beams dissolved in a nonaqueous organic solvent, and thereby subjecting the substance having a hydrophilic group and the reactive group(s) to chemical adsorption on the surface of the substrate, and a step of polymerizing said substance by irradiation with energy beams.
Claim 2
Dependent Claim
75 words
A process for producing a polyacetylene which comprises a step of immersing a substrate having a hydrophilic surface in a solution of a substance having a chlorosilane group and a group(s) reactive to energy beams dissolved in a nonaqueous organic solvent, and thereby subjecting the substance having a hydrophilic group and the reactive group(s) to chemical adsorption on the surface of the substrate, and a step of polymerizing said substance by irradiation with energy beams.
Claim 3
Dependent Claim
32 words
A process for producing a polyacetylene according to claim 1, wherein said reactive groups(s) constituting the substance having a chlorosilane group and a group reactive to energy beams is an acetylene group.
Claim 4
Dependent Claim
26 words
A process for producing a polyacetylene according to claim 1, wherein said energy beams are ultraviolet rays, far ultraviolet rays, electron ion beams, X-rays, γ-rays, etc.
Claim 5
Dependent Claim
31 words
A process for producing a polyacetylene according to claim 1, wherein molecule of said substance having a chlorosilane group and a group(s) reactive to energy beams is a straight-chain hydrocarbon molecule.
Claim 6
Dependent Claim
25 words
A process for producing a polyacetylene according to claim 4, wherein the number of carbon atoms constituting said straight-chain hydrocarbon molecule is 10 or more.
Claim 7
Dependent Claim
23 words
A process for producing a polyacetylene according to claim 4, wherein said chlorosilane group is at the end of the straight-chain hydrocarbon molecule.
Claim 8
Dependent Claim
27 words
A process for producing a polyacetylene according to claim 4, wherein said group(s) reactive to energy beams is at an optional position in the straight-chain hydrocarbon molecule.
Claim 9
Dependent Claim
25 words
A process for producing a polyacetylene according to claim 4, wherein said straight-chain hydrocarbon molecule has one or more groups reactive to the energy beams.
Claim 10
Dependent Claim
29 words
A process for producing a polyacetylene according to claim 4, wherein the terminal group other than the terminal chlorosilane group of said straight-chain hydrocarbon molecule is an unsaturated group.
Claim 11
Dependent Claim
25 words
A process for producing a polyacetylene according to claim 9, wherein a multilayer film is formed using the straight-chain hydrocarbon molecules having the unsaturated group.
Claim 12
Dependent Claim
18 words
A process for producing a polyacetylene according to claim 9, wherein said unsaturated group is a vinyl group.
Claim 13
Dependent Claim
21 words
A process for producing a polyacetylene according to claim 4, wherein said straight-chain hydrocarbon molecule has one or more side chains.
Claim 14
Dependent Claim
30 words
A process for producing a polyacetylene according to claim 12, wherein the chlorosilane group is at the end of main chain of the straight-chain hydrocarbon molecule having a side chain(s).
Claim 15
Dependent Claim
36 words
A process for producing a polyacetylene according to claim 12, wherein the groups reactive to energy beams are present in the main chain and the side chain of the straight-chain hydrocarbon molecule having a side chain(s).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-11-05 | 1994-05-07 | 1994-11-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-11-05 | 1998-05-07 | 1998-11-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-11-05 | 2002-05-07 | 2002-11-06 | $7700.00 | Window Closed / Lapsed |