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US4925698A Expired / Lapsed US ⏱️ 0.0 years remaining

Surface modification of polymeric materials

Assignee: Tekmat Corp
•
Filing: 1989-03-08
•
Granted: 1990-05-15
•
Expires: 2009-03-08
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Abstract

Abstract A method of increasing the adsorption resistance of a polymer having surface carboxyl or hydroxyl groups by directly contacting the surface of the polymer with an acylating agent under conditions sufficient to chemically react the carboxyl or hydroxyl groups with the acylating agent.

Inventors

  • 👤 Mitchell Klausner
  • 👤 Michael P. Manning
  • 👤 Raymond F. Baddour

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:56
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/04; G02B1/041; G02B1/043; C; C08; C08J; C08J7/00; C08J7/12

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 54 words
A method of increasing the adsorption resistance of a polymer having surface carboxyl or hydroxyl groups comprising directly contacting the surface of said polymer with an acylating agent in the vapor phase under conditions sufficient to chemically react said carboxyl or said hydroxyl groups with said acylating agent without pretreating said surface with base.
Claim 2
Independent Claim 54 words
A method of increasing the adsorption resistance of a polymer having surface carboxyl or hydroxyl groups comprising directly contacting the surface of said polymer with an acylating agent in the vapor phase under conditions sufficient to chemically react said carboxyl or said hydroxyl groups with said acylating agent without pretreating said surface with base.
Claim 3
Dependent Claim 13 words
The method of claim 1 wherein said acylating agent comprises an acid halide.
Claim 4
Dependent Claim 17 words
The method of claim 2 wherein said acid halide has between 1 and 4 carbon atoms, inclusive.
Claim 5
Dependent Claim 12 words
The method of claim 2 wherein said acid halide is acryloyl chloride.
Claim 6
Dependent Claim 12 words
The method of claim 2 wherein said acid halide is acetyl chloride.
Claim 7
Dependent Claim 13 words
The method of claim 1 wherein said acylating agent comprises an acid anhydride.
Claim 8
Dependent Claim 12 words
The method of claim 1 wherein said acylating agent comprises an amide.
Claim 9
Dependent Claim 19 words
The method of claim 1 wherein said carboxyl or hydroxyl groups are present as side groups in said polymer.
Claim 10
Dependent Claim 19 words
The method of claim 1 wherein said carboxyl or hydroxyl groups are present as end groups in said polymer.
Claim 11
Dependent Claim 25 words
The method of claim 1 wherein said polymer is crosslinked and said carboxyl or hydroxyl groups are from the reagent used to crosslink said polymer.
Claim 12
Independent Claim 56 words
A method of increasing the soil resistance of a hydrophilic contact lens having surface carboxyl or hydroxyl groups comprising directly contacting the surface of said lens with an acylating agent in the vapor phase under conditions sufficient to chemically react said carboxyl or said hydroxyl groups with said acylating agent without pretreating said surface with base.
Claim 13
Independent Claim 56 words
A method of increasing the soil resistance of a hydrophilic contact lens having surface carboxyl or hydroxyl groups comprising directly contacting the surface of said lens with an acylating agent in the vapor phase under conditions sufficient to chemically react said carboxyl or said hydroxyl groups with said acylating agent without pretreating said surface with base.
Claim 14
Dependent Claim 13 words
The method of claim 11 wherein said acylating agent comprises an acid halide.
Claim 15
Dependent Claim 17 words
The method of claim 12 wherein said acid halide has between 1 and 4 carbon atoms, inclusive.
Claim 16
Dependent Claim 12 words
The method of claim 12 wherein said acid halide is acryloyl chloride.
Claim 17
Dependent Claim 12 words
The method of claim 12 wherein said acid halide is acetyl chloride.
Claim 18
Dependent Claim 13 words
The method of claim 11 wherein said acylating agent comprising an acid anhydride.
Claim 19
Dependent Claim 12 words
The method of claim 11 wherein said acylating agent comprises an amide.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-05-14 1993-11-13 1994-05-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-05-14 1997-11-13 1998-05-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-05-14 2001-11-13 2002-05-15 $7700.00 Window Closed / Lapsed

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