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US4569858A Expired / Lapsed US ⏱️ 0.0 years remaining

Surface modification of hydrophilic contact lenses

Assignee: PILINGTON BARNES HIND Inc
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Filing: 1985-01-28
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Granted: 1986-02-11
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Expires: 2005-01-28
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Abstract

Abstract The present invention relates to a method of modifying a surface of a soft contact lens to make the lens resistant to soiling. The method comprises initiating a reaction between the unhydrated lens surface containing carboxylic acid or alcohol moieties and agents capable of reacting with carboxylic acid or alcohol moieties in order to produce a surface which then either has a hydrophobic coating, a nonionic hydrophilic coating or is charged.

Inventors

  • 👤 Drahoslav Lim
  • 👤 Peter C. Morris

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 18:57
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/04; G02B1/041; G02B1/043

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 68 words
A method of modifying a surface of a soft contact lens which makes it resistant to soiling, said method comprising initiating a reaction between an unhydrated lens surface containing carboxylic acid of alcohol moieties and an agent capable of reacting with carboxylic acid or alcohol moieties wherein said agent is a diazoalkane, dimethyl formamide dialkyl acetal, alkylenediisocyanate or the reaction product of alkylenediisocyanate and polyethylene glycol monomethyl ether.
Claim 2
Independent Claim 68 words
A method of modifying a surface of a soft contact lens which makes it resistant to soiling, said method comprising initiating a reaction between an unhydrated lens surface containing carboxylic acid of alcohol moieties and an agent capable of reacting with carboxylic acid or alcohol moieties wherein said agent is a diazoalkane, dimethyl formamide dialkyl acetal, alkylenediisocyanate or the reaction product of alkylenediisocyanate and polyethylene glycol monomethyl ether.
Claim 3
Dependent Claim 27 words
The method of claim 1 wherein the agent is diazomethane, dimethylformamide dimethyl acetal, hexamethylene diisocyanate, or the reaction product of polyethylene glycol monomethyl ether and hexamethylene diisocyanate.
Claim 4
Dependent Claim 13 words
A contact lens made resistant to soiling by the method of claim 1.
Claim 5
Independent Claim 56 words
A method of modifying a surface of a soft contact lens which makes it resistant to soiling, said method comprising (a) treatment of the surface of an unhydrated lens with a strong base in a non-swelling solvent to produce anionic groups on the surface; and (b) initiating a reaction with an alkylating, acylating or sulfonating agent.
Claim 6
Independent Claim 56 words
A method of modifying a surface of a soft contact lens which makes it resistant to soiling, said method comprising (a) treatment of the surface of an unhydrated lens with a strong base in a non-swelling solvent to produce anionic groups on the surface; and (b) initiating a reaction with an alkylating, acylating or sulfonating agent.
Claim 7
Dependent Claim 17 words
The method of claim 4 wherein the strong base is potassium t-butoxide, sodium methoxide or butyl lithium.
Claim 8
Dependent Claim 19 words
The method of claim 4 wherein the reaction agent is neodecanoyl chloride, butane sultone, propane sultone or pivaloyl chloride.
Claim 9
Dependent Claim 24 words
The method of claim 4 wherein the time of the reaction is 1 to 245 hours and the temperature is ambient to 100° C.
Claim 10
Dependent Claim 13 words
A contact lens made resistant to soiling by the method of claim 4.

References Cited (Backward Citations)

US4411932A Cited
US4442141A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-02-10 1989-08-12 1990-02-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-02-10 1993-08-12 1994-02-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-02-10 1997-08-12 1998-02-11 $7700.00 Window Closed / Lapsed

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