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US4908272A
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Gas-barrier multilayered structure
Assignee: Mitsubishi Gas Chemical Co Inc
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Filing: 1988-04-25
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Granted: 1990-03-13
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Expires: 2008-04-25
Abstract
Abstract A gas-barrier multilayered structure comprising (A) at least one layer of a copolyamide composed of (a) a dicarboxylic acid component composed of 55 to 70 mole % of an aliphatic dicarboxylic acid component and 45 to 30 mole % of an aromatic dicarboxylic acid component consisting substantially of 20 to 30 mole % of isophthalic acid and 5 to 20 mole % of terephthalic acid, and (b) a diamine component composed substantially of a m-xylylenediamine component, and (B) at least one layer of a thermoplastic resin other than the copolyamide. Instead of the layer (A), there can be used (A') at least one layer of a mixture of 40 to 60 % by weight of a first copolyamide composed of (a) a dicarboxylic acid component composed of 55 to 70 mole % of an aliphatic dicarboxylic acid component and 45 to 30 mole % of an aromatic dicarboxylic acid component consisting substantially of 20 to 30 mole % of isophthalic acid and 5 to 20 mole % of terephthalic acid and (b) a diamine component composed substantially of m-xylylenediamine and 60 to 40 % by weight of a second polyamide composed of a dicarboxylic acid component consisting substantially of an aliphthalic dicarboxylic acid component and a diamine component consisting substantially of a m-xylylenediamine component.
Inventors
- 👤 Masahiro Harada
- 👤 Makoto Matsumura
- 👤 Toru Kino
- 👤 Akira Iwamoto
- 👤 Yoshiaki Momose
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 15:55
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/34; B32B27/06; B32B27/08; B32B27/32; B32B27/36; B32B27/365; B32B7/00; B32B7/04; B32B7/12; C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/265; C08L; C08L77/00; B32B2307/00; B32B2307/70; B32B2307/724; B32B2307/7242; B32B2369/00; B32B2377/00; B32B2439/00; B32B2439/70; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/31725; Y10T428/31728; Y10T428/31732; Y10T428/31736; Y10T428/31739; Y10T428/31743; Y10T428/31746; Y10T428/3175; Y10T428/31757
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
112 words
A gas-barrier multilayered structure comprising (A) at least one layer of a copolyamide which is substantially amorphous and has a glass transition temperature of 90° to 130° C. and is composed of (a) a dicarboxylic acid component composed of from more than 55 to less than 70 mole % of an aliphatic dicarboxylic acid component and 45 to 30 mole % of an aromatic dicarboxylic acid component consisting substantially of 20 to 30 mole % of isophthalic acid and 5 to 20 mole % of terephthalic acid, and (b) a diamine component composed substantially of a m-xylylenediamine component, and (B) at least one layer of a thermoplastic resin other than the copolyamide.
Claim 2
Dependent Claim
112 words
A gas-barrier multilayered structure comprising (A) at least one layer of a copolyamide which is substantially amorphous and has a glass transition temperature of 90° to 130° C. and is composed of (a) a dicarboxylic acid component composed of from more than 55 to less than 70 mole % of an aliphatic dicarboxylic acid component and 45 to 30 mole % of an aromatic dicarboxylic acid component consisting substantially of 20 to 30 mole % of isophthalic acid and 5 to 20 mole % of terephthalic acid, and (b) a diamine component composed substantially of a m-xylylenediamine component, and (B) at least one layer of a thermoplastic resin other than the copolyamide.
Claim 3
Dependent Claim
24 words
The multilayered structure of claim 1 wherein an adhesive layer (C) exists between the copolyamide layer (A) and the other thermoplasic resin layer (B).
Claim 4
Dependent Claim
18 words
The multilayered structure of claim 1 wherein the aliphatic dicarboxylic acid component of the copolyamide is adipic acid.
Claim 5
Dependent Claim
66 words
The multilayered structure of claim 1 which is of a five-layer structure and is composed of a central layer of a copolyamide containing adipic acid as the aliphatic dicarboxylic acid component, two outermost layers of polyethylene or polypropylene and adhesive layers of modified polypropylene or modified polyethylene between the central layer and one outermost layer and between the central layer and the other outermost layer, respectively.
Claim 6
Dependent Claim
53 words
The multilayered structure of claim 1 which is of a five-layer structure and is composed of two outermost layers of polyethylene terephthalate, a central layer of polyethylene terephthalate, and layers of the copolyamide existing between the central layer and one outermost layer and between the central layer and the other outermost layer, respectively.
Claim 7
Dependent Claim
55 words
The multilayered structure of claim 1 which is of a four-layer structure and is composed of one outside layer of a polyolefin resin, another outside layer of a copolymer of nylon 6 and nylon 66, a central layer of the copolyamide, and an adhesive layer between the central layer and the outside polyolefin resin layer.
Claim 8
Dependent Claim
32 words
The multilayered structure of claim 1 which is of a three-layer structure and is composed of two outside layers of a polycarbonate resin and a central layer of the copolyamide interposed therebetween.
Claim 9
Dependent Claim
158 words
A gas-barrier multilayered structure comprising (A') at least one layer of a mixture of 40 to 60% by weight of a first copolyamide which is substantially amorphous and has a glass transition temperature of 90° to 130° C. and is composed of (a) a dicarboxylic acid component composed of from more than 55 to less than 70 mole % of an aliphatic dicarboxylic acid component and 45 to 30 mole % of an aromatic dicarboxylic acid component consisting substantially of 20 to 30 mole % of isophthalic acid and 5 to 20 mole % of terephthalic acid and (b) a diamine component composed substantially of m-xylylenediamine and 60 to 40 % by weight of a second polyamide composed of a dicarboxylic acid component consisting substantially of an aliphatic dicarboxylic acid component and a diamine component consisting substantially of a m-xylylenediamine component, and (B') at least one layer of a thermoplastic resin other than the first and second polyamides.
Claim 10
Dependent Claim
158 words
A gas-barrier multilayered structure comprising (A') at least one layer of a mixture of 40 to 60% by weight of a first copolyamide which is substantially amorphous and has a glass transition temperature of 90° to 130° C. and is composed of (a) a dicarboxylic acid component composed of from more than 55 to less than 70 mole % of an aliphatic dicarboxylic acid component and 45 to 30 mole % of an aromatic dicarboxylic acid component consisting substantially of 20 to 30 mole % of isophthalic acid and 5 to 20 mole % of terephthalic acid and (b) a diamine component composed substantially of m-xylylenediamine and 60 to 40 % by weight of a second polyamide composed of a dicarboxylic acid component consisting substantially of an aliphatic dicarboxylic acid component and a diamine component consisting substantially of a m-xylylenediamine component, and (B') at least one layer of a thermoplastic resin other than the first and second polyamides.
Claim 11
Dependent Claim
25 words
The multilayered structure of claim 8 wherein an adhesive layer (C) exists between the polyamide mixture layer (A) and the other thermoplasic resin layer (B).
Claim 12
Dependent Claim
21 words
The multilayered structure of claim 8 wherein the aliphatic dicarboxylic acid component of the first and second polyamides is adipic acid.
Claim 13
Dependent Claim
72 words
The multilayered structure of claim 8 which is of a five-layer structure and is composed of a central layer of the mixture of the first and second polyamides containing adipic acid as the aliphatic dicarboxylic acid component, two outermost layers of polyethylene or polypropylene and adhesive layers of modified polypropylene or modified polyethylene between the central layer and one outermost layer and between the central layer and the other outermost layer, respectively.
Claim 14
Dependent Claim
59 words
The multilayered structure of claim 8 which is of a five-layer structure and is composed of two outermost layers of polyethylene terephthalate, a central layer of polyethylene terephthalate, and layers of the mixture of the first and second polyamides existing between the central layer and one outermost layer and between the central layer and the other outermost layer, respectively.
Claim 15
Dependent Claim
61 words
The multilayered structure of claim 8 which is of a four-layer structure and is composed of one outside layer of a polyolefin resin, another outside layer of a copolymer of nylon 6 and nylon 66, a central layer of the mixture of the first and second polyamides, and an adhesive layer between the central layer and the outside polyolefin resin layer.
Claim 16
Dependent Claim
38 words
The multilayered structure of claim 8 which is of a three-layer structure and is composed of two outside layers of a polycarbonate resin and a central layer of the mixture of the first and second polyamides interposed therebetween.
References Cited (Backward Citations)
US3843479A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-03-12 | 1993-09-11 | 1994-03-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-03-12 | 1997-09-11 | 1998-03-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-03-12 | 2001-09-11 | 2002-03-13 | $7700.00 | Window Closed / Lapsed |