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High strength, low modulus, ductile, biopcompatible titanium alloy

Assignee: Howmedica Osteonics Corp
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Filing: 1988-09-09
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Granted: 1989-08-15
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Expires: 2008-09-09
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Abstract

Abstract A high strength, low modulus, ductile, biocompatible titanium base alloy, characterized by a modules of elasticity not exceeding 100 GPa and consisting of up to 24% by weight of at least one isomorphous beta stabilizer selected from the group consisting of molybdenum, tantalum, niobium and zirconium, up to 3.0% by weight of at least one eutectoid beta stabilizer selected from the group consisting of iron, manganese, chromium, cobalt and nickel, wherein the combined amount of isomorphous beta stabilizer and eutectoid beta stabilizer is at least 10.2% by weight; optionally up to 3.0% by weight of at least one metallic alpha stabilizer selected from the group consisting of aluminum and lanthanum; and the balance titanium, apart from incidental impurities. A method for the preparation of said alloy, including a vacuum arc remelting step, is also disclosed.

Inventors

  • 👤 Kathy K. Wang
  • 👤 Larry J. Gustavson
  • 👤 John H. Dumbleton

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 15:20
CPC Classifications
A; A61; A61L; A61L27/00; A61L27/02; A61L27/04; A61L27/06; C; C22; C22C; C22C14/00; A61F; A61F2310/00; A61F2310/00005; A61F2310/00011; A61F2310/00023

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 215 words
A high strength, low modulus, ductile, biocompatible titanium base alloy consisting essentially of the following alloying components: an amount up to 24% by weight of at least one isomorphous beta stabilizer selected from the group consisting of molybdenum, tantalum, niobium and zirconium, provided that molybdenum, when present, is in an amount of at least 10% by weight, and when molybdenum is present with zirconium the molybdenum is in an amount of 10 to 13% by weight and the zirconium is in an amount of 5 to 7% by weight; an amount up to 3.0% by weight of at least one eutectoid beta stabilizer selected from the group consisting of iron, manganese, chromium, cobalt and nickel Wherein the combined amount of isomorphous beta stabilizer and eutectoid beta stabilizer is at lest 10.2 percent by weight; optionally an amount up to 3.0% by weight of at least one metallic alpha stabilizer selected from the group consisting of aluminum and lanthanum; and the balance titanium, apart from incidental impurities, but not exceeding by weight, among the non-metallic alpha stabilizers, 0.05% carbon, 0.30% oxygen and 0.02% nitrogen; and not exceeding 0.02% of the eutectoid former hydrogen; the proportion of each of the alloying components being balanced to provide an alloy having a modulus of elasticity not exceeding 100 GPa.
Claim 2
Dependent Claim 215 words
A high strength, low modulus, ductile, biocompatible titanium base alloy consisting essentially of the following alloying components: an amount up to 24% by weight of at least one isomorphous beta stabilizer selected from the group consisting of molybdenum, tantalum, niobium and zirconium, provided that molybdenum, when present, is in an amount of at least 10% by weight, and when molybdenum is present with zirconium the molybdenum is in an amount of 10 to 13% by weight and the zirconium is in an amount of 5 to 7% by weight; an amount up to 3.0% by weight of at least one eutectoid beta stabilizer selected from the group consisting of iron, manganese, chromium, cobalt and nickel Wherein the combined amount of isomorphous beta stabilizer and eutectoid beta stabilizer is at lest 10.2 percent by weight; optionally an amount up to 3.0% by weight of at least one metallic alpha stabilizer selected from the group consisting of aluminum and lanthanum; and the balance titanium, apart from incidental impurities, but not exceeding by weight, among the non-metallic alpha stabilizers, 0.05% carbon, 0.30% oxygen and 0.02% nitrogen; and not exceeding 0.02% of the eutectoid former hydrogen; the proportion of each of the alloying components being balanced to provide an alloy having a modulus of elasticity not exceeding 100 GPa.
Claim 3
Dependent Claim 63 words
An alloy according to claim 1, having a modulus of elasticity of 66.9 to GPa; a 0.2% offset yield strength of 925 to 1221 MPa; a rotating beam fatigue strength of 483 to 621 MPa at 10 7 cycles and of 345 to 380 MPa at a stress concentration factor, K t , of 1.6; and a tensile elongation of at least 10%.
Claim 4
Dependent Claim 45 words
An alloy according to claim 1, consisting essentially of 10 to 13% by weight of molybdenum; 5 to 7% by weight of zirconium; 0.2 to 3.0% by weight of iron; 0 to 3.0% by weight of aluminum; and the balance titanium, apart from incidental impurities.
Claim 5
Dependent Claim 40 words
An alloy according to claim 1, consisting essentially of 10.0 to 20.0% by weight niobium; 1.0 to 4.0% by weight zirconium; about 2.0% by weight iron; up to 1.0% by weight aluminum; and the balance titanium, apart from incidental impurities.
Claim 6
Dependent Claim 18 words
A prosthesis made from a high strength, low modulus, ductile, biocompatible titanium base alloy according to claim 1.
Claim 7
Dependent Claim 42 words
An alloy according to claim 3 consisting essentially of about 11.5% by weight molybdenum, about 6.0% by weight zirconium; about 0.4 to about 2.0% by weight iron, 0 to about 1.0% by weight aluminum; and the balance titanium, apart from incidental impurities.

References Cited (Backward Citations)

GB727085A Cited
US2821475A Cited
US4040129A Cited
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US4197643A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-08-14 1993-02-13 1993-08-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-08-14 1997-02-13 1997-08-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-08-14 2001-02-13 2001-08-15 $7700.00 Window Closed / Lapsed

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