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Prosthesis formed from dispersion strengthened cobalt-chromium-molybdenum alloy produced by gas atomization

Assignee: Howmedica Osteonics Corp
•
Filing: 1987-01-27
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Granted: 1987-12-22
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Expires: 2007-01-27
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Abstract

Abstract A dispersion strengthened cobalt-chromium-molybdenum alloy produced by gas atomization containing a fine oxide dispersion, and characterized, after fabrication by gas atomization, thermomechanical processing and further high temperature exposure, by excellent corrosion resistance, high fatigue strength, high ductility and high temperature stability; a process for producing said alloy and prostheses formed from said alloy.

Inventors

  • 👤 Kathy K. Wang
  • 👤 Larry J. Gustavson
  • 👤 John H. Dumbleton

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 06:58
CPC Classifications
C; C22; C22C; C22C19/00; C22C19/07; A; A61; A61L; A61L27/00; A61L27/02; A61L27/04; A61L27/045; A61F; A61F2310/00; A61F2310/00005; A61F2310/00011; A61F2310/00029

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 200 words
A prosthesis made by forging a high-strength, corrosion-resistant, high temperature stable, ductile alloy having homogeneously distributed dispersed oxides and fine, equiaxed grain structure after high temperature exposure, said alloy being produced by gas atomisation and consisting essentially of the following percentage composition by weight: ______________________________________ chromium 26 to 30 molybdenum 5 to 7 manganese 0 to 1 silicon 0 to 1 iron 0 to 0.75 nickel 0 to 1.0 carbon 0 to 0.35 nitrogen 0 to 0.25 oxygen 0.003 to 0.20 oxide-forming metal 0.003 to 2.0 ______________________________________ and the balance cobalt, apart from trace amounts of incidental impurities; in which the oxide-forming metal is a metal selected from the group consisting of magnesium, calcium, aluminum, yttrium, lanthanum, titanium and zirconium, which forms high temprature-stable, non-accretive, fine oxide particles which oxide has a free energy of formation greater than the oxide of the matrix metal and is homogeneously distributed in the dispersed phase; and said alloy after fabrication by gas atomization, thermomechanical processing and further high temperature exposure has an ultimate tensile strength of 160-200 k.s.i., a 0.2% offset yield strength of 75-100 k.s.i., an elongation of 37 to 60%, and a fatigue strength at 10 7 cycles of 70-95 k.s.i.
Claim 2
Dependent Claim 200 words
A prosthesis made by forging a high-strength, corrosion-resistant, high temperature stable, ductile alloy having homogeneously distributed dispersed oxides and fine, equiaxed grain structure after high temperature exposure, said alloy being produced by gas atomisation and consisting essentially of the following percentage composition by weight: ______________________________________ chromium 26 to 30 molybdenum 5 to 7 manganese 0 to 1 silicon 0 to 1 iron 0 to 0.75 nickel 0 to 1.0 carbon 0 to 0.35 nitrogen 0 to 0.25 oxygen 0.003 to 0.20 oxide-forming metal 0.003 to 2.0 ______________________________________ and the balance cobalt, apart from trace amounts of incidental impurities; in which the oxide-forming metal is a metal selected from the group consisting of magnesium, calcium, aluminum, yttrium, lanthanum, titanium and zirconium, which forms high temprature-stable, non-accretive, fine oxide particles which oxide has a free energy of formation greater than the oxide of the matrix metal and is homogeneously distributed in the dispersed phase; and said alloy after fabrication by gas atomization, thermomechanical processing and further high temperature exposure has an ultimate tensile strength of 160-200 k.s.i., a 0.2% offset yield strength of 75-100 k.s.i., an elongation of 37 to 60%, and a fatigue strength at 10 7 cycles of 70-95 k.s.i.
Claim 3
Dependent Claim 23 words
A prosthesis accordindg to claim 1, in which the oxide forming metal of the forged alloy is aluminum, lanthanum or a mixture thereof.
Claim 4
Dependent Claim 53 words
A prosthesis according to claim 2, in which the percentage composition by weight of the forged alloy is: ______________________________________ chromium 26.47-27.27 molybdenum 5.50-6.01 manganese 0.73-0.78 silicon 0.70-0.71 iron 0.066-0.359 nickel 0.002-0.187 carbon 0.09-0.11 nitrogen 0.10-[0.26]0.25 oxygen 0.0035-0.016 aluminum 0.40-0.81 lanthanum 0-0.15 ______________________________________ and the balance cobalt, apart from trace amount of incidental impurities.
Claim 5
Dependent Claim 73 words
A prosthesis according to claim 2, in which the percentage composition by weight of the forged alloy is: ______________________________________ chromium 27.24 molybdenum 5.97 manganese 0.74 silicon 0.71 iron 0.215 nickel 0.053 carbon 0.09 nitrogen 0.21 oxygen 0.0038 aluminum 0.45 lanthanum 0.022 ______________________________________ and the balance cobalt, apart from trace amount of incidental impurities, and said alloy after fabrication by gas atomisation, thermomechanical processing and further high temperature exposure has an elongation of 58.7%.
Claim 6
Dependent Claim 73 words
A prosthesis according to claim 2, in which the percentage composition by weight of the forged alloy is: ______________________________________ chromium 26.81 molybdenum 5.97 manganese 0.74 silicon 0.70 iron 0.52 nickel 0.094 carbon 0.09 nitrogen 0.22 oxygen 0.0142 aluminum 0.47 lanthanum 0.15 ______________________________________ and the balance cobalt, apart from trace amounts of incidental impurities, and said alloy after fabrication by gas atomisation, thermomechanical processing and further high temperature exposure has an elongation of 51.0%.
Claim 7
Dependent Claim 10 words
A prosthesis according to claim 1 having a porous coating.

References Cited (Backward Citations)

GB423562A Cited
GB974185A Cited
US3356542A Cited
US3591362A Cited
US3649256A Cited
SU368341A1 Cited
US3865585A Cited
DE2350546A1 Cited
US4012229A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-12-21 1991-06-22 1991-12-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-12-21 1995-06-22 1995-12-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-12-21 1999-06-22 1999-12-22 $7700.00 Window Closed / Lapsed

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