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US4499002A Expired / Lapsed US ⏱️ 0.0 years remaining

Scale inhibiting copolymer

Assignee: Noveon IP Holdings Corp
•
Filing: 1983-06-28
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Granted: 1985-02-12
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Expires: 2003-06-28
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Abstract

Abstract A random copolymer which consists essentially of a copolymer of (i) acrylic acid or methacrylic acid (together "(meth)acrylic"), (ii) acrylamide or methacrylamide (together "(meth)acrylamide"), and (iii) and alkoxyalkyl (meth)acrylate ester ("AAE") present in specified relative proportions, is soluble in water, and is surprisingly effective in the treatment of industrial process water used in recirculating water systems, particularly with respect to inhibiting the deposition of calcium phosphate on surfaces of equipment used in such systems.

Inventors

  • 👤 William F. Masler, III
  • 👤 Zahid Amjad

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 13:06
CPC Classifications
C; C02; C02F; C02F5/00; C02F5/08; C02F5/10; C02F5/12; A; A23; A23B; A23B70/00; A23B70/30; A23C; A23C9/00; A23C9/152

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 205 words
A composition for treating a predominantly aqueous stream to inhibit the deposition of precipitates selected from the group consisting of calcium phosphate, magnesium phosphate, zinc phosphate, calcium silicate, magnesium silicate, magnesium hydroxide, zinc hydroxide, iron oxide and mixtures thereof, said composition comprising an effective amount for the purpose, of a water-soluble essentially non-crosslinked random copolymer consisting essentially of a copolymer of acrylic acid or methacrylic acid, acrylamide or methacrylamide, and an alkoxylated primary alcohol ester of (meth)acrylic acid, the copolymer having the structural formula ##STR2## wherein X represents H, or NH 4 , or an alkali metal selected from the group consisting of sodium and potassium; R 1 represents H, or methyl; R 2 represents alkyl having from 2 to about 4 carbon atoms; R 3 represents alkyl having from 1 to about 10 carbon atoms; n is an integer in the range from 2 to about 6; m is an integer in the range from about 3 to about 70; and, for each y (that is, y=1) x is an integer in the range from about 1 to about 8, and z is a number in the range from 1 to about 0.075; and x, y and z are present in relative heterogeneous order.
Claim 2
Dependent Claim 205 words
A composition for treating a predominantly aqueous stream to inhibit the deposition of precipitates selected from the group consisting of calcium phosphate, magnesium phosphate, zinc phosphate, calcium silicate, magnesium silicate, magnesium hydroxide, zinc hydroxide, iron oxide and mixtures thereof, said composition comprising an effective amount for the purpose, of a water-soluble essentially non-crosslinked random copolymer consisting essentially of a copolymer of acrylic acid or methacrylic acid, acrylamide or methacrylamide, and an alkoxylated primary alcohol ester of (meth)acrylic acid, the copolymer having the structural formula ##STR2## wherein X represents H, or NH 4 , or an alkali metal selected from the group consisting of sodium and potassium; R 1 represents H, or methyl; R 2 represents alkyl having from 2 to about 4 carbon atoms; R 3 represents alkyl having from 1 to about 10 carbon atoms; n is an integer in the range from 2 to about 6; m is an integer in the range from about 3 to about 70; and, for each y (that is, y=1) x is an integer in the range from about 1 to about 8, and z is a number in the range from 1 to about 0.075; and x, y and z are present in relative heterogeneous order.
Claim 3
Dependent Claim 27 words
The composition of claim 1 wherein R 1 represents H; R 2 represents CH 2 --CH 2 (`ethyl`); and, R 3 represents CH 3 --CH 2 --(`ethyl`).
Claim 4
Dependent Claim 17 words
The composition of claim 2 wherein said aqueous stream is process water in a recirculating water system.
Claim 5
Dependent Claim 15 words
The composition of claim 2 wherein said aqueous stream is milk prior to being pasteurized.
Claim 6
Dependent Claim 21 words
The composition of claim 2 wherein the copolymer has a molecular weight in the range from about 2000 to about 50,000.
Claim 7
Dependent Claim 38 words
The composition of claim 5 in an aqueous solution having a pH in the range from about 5 to about 8, and a total solids content in the range from about 2 to about 60 percent by weight.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-02-12 1988-08-13 1989-02-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-02-12 1992-08-13 1993-02-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-02-12 1996-08-13 1997-02-12 $7700.00 Window Closed / Lapsed

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