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US4499002A
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Scale inhibiting copolymer
Assignee: Noveon IP Holdings Corp
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Filing: 1983-06-28
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Granted: 1985-02-12
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Expires: 2003-06-28
Abstract
Abstract A random copolymer which consists essentially of a copolymer of (i) acrylic acid or methacrylic acid (together "(meth)acrylic"), (ii) acrylamide or methacrylamide (together "(meth)acrylamide"), and (iii) and alkoxyalkyl (meth)acrylate ester ("AAE") present in specified relative proportions, is soluble in water, and is surprisingly effective in the treatment of industrial process water used in recirculating water systems, particularly with respect to inhibiting the deposition of calcium phosphate on surfaces of equipment used in such systems.
Inventors
- 👤 William F. Masler, III
- 👤 Zahid Amjad
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 13:06
CPC Classifications
C; C02; C02F; C02F5/00; C02F5/08; C02F5/10; C02F5/12; A; A23; A23B; A23B70/00; A23B70/30; A23C; A23C9/00; A23C9/152
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
205 words
A composition for treating a predominantly aqueous stream to inhibit the deposition of precipitates selected from the group consisting of calcium phosphate, magnesium phosphate, zinc phosphate, calcium silicate, magnesium silicate, magnesium hydroxide, zinc hydroxide, iron oxide and mixtures thereof, said composition comprising an effective amount for the purpose, of a water-soluble essentially non-crosslinked random copolymer consisting essentially of a copolymer of acrylic acid or methacrylic acid, acrylamide or methacrylamide, and an alkoxylated primary alcohol ester of (meth)acrylic acid, the copolymer having the structural formula ##STR2## wherein X represents H, or NH 4 , or an alkali metal selected from the group consisting of sodium and potassium; R 1 represents H, or methyl; R 2 represents alkyl having from 2 to about 4 carbon atoms; R 3 represents alkyl having from 1 to about 10 carbon atoms; n is an integer in the range from 2 to about 6; m is an integer in the range from about 3 to about 70; and, for each y (that is, y=1) x is an integer in the range from about 1 to about 8, and z is a number in the range from 1 to about 0.075; and x, y and z are present in relative heterogeneous order.
Claim 2
Dependent Claim
205 words
A composition for treating a predominantly aqueous stream to inhibit the deposition of precipitates selected from the group consisting of calcium phosphate, magnesium phosphate, zinc phosphate, calcium silicate, magnesium silicate, magnesium hydroxide, zinc hydroxide, iron oxide and mixtures thereof, said composition comprising an effective amount for the purpose, of a water-soluble essentially non-crosslinked random copolymer consisting essentially of a copolymer of acrylic acid or methacrylic acid, acrylamide or methacrylamide, and an alkoxylated primary alcohol ester of (meth)acrylic acid, the copolymer having the structural formula ##STR2## wherein X represents H, or NH 4 , or an alkali metal selected from the group consisting of sodium and potassium; R 1 represents H, or methyl; R 2 represents alkyl having from 2 to about 4 carbon atoms; R 3 represents alkyl having from 1 to about 10 carbon atoms; n is an integer in the range from 2 to about 6; m is an integer in the range from about 3 to about 70; and, for each y (that is, y=1) x is an integer in the range from about 1 to about 8, and z is a number in the range from 1 to about 0.075; and x, y and z are present in relative heterogeneous order.
Claim 3
Dependent Claim
27 words
The composition of claim 1 wherein R 1 represents H; R 2 represents CH 2 --CH 2 (`ethyl`); and, R 3 represents CH 3 --CH 2 --(`ethyl`).
Claim 4
Dependent Claim
17 words
The composition of claim 2 wherein said aqueous stream is process water in a recirculating water system.
Claim 5
Dependent Claim
15 words
The composition of claim 2 wherein said aqueous stream is milk prior to being pasteurized.
Claim 6
Dependent Claim
21 words
The composition of claim 2 wherein the copolymer has a molecular weight in the range from about 2000 to about 50,000.
Claim 7
Dependent Claim
38 words
The composition of claim 5 in an aqueous solution having a pH in the range from about 5 to about 8, and a total solids content in the range from about 2 to about 60 percent by weight.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-02-12 | 1988-08-13 | 1989-02-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-02-12 | 1992-08-13 | 1993-02-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-02-12 | 1996-08-13 | 1997-02-12 | $7700.00 | Window Closed / Lapsed |