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US4436769A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal organic vapor deposition procedure for preparing group III--V compounds on a heated substrate

Assignee: British Telecommunications PLC
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Filing: 1981-11-18
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Granted: 1984-03-13
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Expires: 2001-11-18
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Abstract

Abstract A method of depositing a group III element--group V element compound or alloy on a hot substrate using a metal organic chemical vapor deposition procedure. Attempts to apply an MOCVD procedure to the production of a group III element--group V element compound from alkyl derivatives of group III elements which are strong Lewis acids and group V element hydrides have met with limited success. This is because the reactants react in the cold gas phase to form an involatile polymer which does not give the required product on the hot substrate. The present invention proposes modifying the alkyl derivative of the group III element to be a weaker Lewis acid. This can be achieved by either substituting an electron donating group for one of the alkyl groups bonded to the group III element or by combining the group III element alkyl derivative with an alkyl derivative of a group V element thereby forming a volatile compound. Both the substituted alkyl derivative of the group III element and the volatile alkylated group III-V compound give the required product when used in admixture with a group V element hydride in an MOCVD process.

Inventors

  • 👤 Rodney H. Moss
  • 👤 Marc M. Faktor

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:13
CPC Classifications
C; C30; C30B; C30B25/00; C30B25/02; C23; C23C; C23C16/00; C23C16/06; C23C16/22; C23C16/30; C23C16/301; C30B29/00; C30B29/10; C30B29/40

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 99 words
In a method of forming a group III-group V compound on a heated substrate by causing vapor streams carrying respectively a group III alkyl derivative and a group V hydride to mix and impinge on the substrate, whereby the group III alkyl derivative and the group V hydride react to form the group III-group V compound, the improvement which comprises: modifying the group III alkyl derivative by the donation thereto of electron density to form a weaker Lewis acid; mixing the resulting modified group III alkyl derivative with the group V hydride; and impinging the mixture on the substrate.
Claim 2
Dependent Claim 99 words
In a method of forming a group III-group V compound on a heated substrate by causing vapor streams carrying respectively a group III alkyl derivative and a group V hydride to mix and impinge on the substrate, whereby the group III alkyl derivative and the group V hydride react to form the group III-group V compound, the improvement which comprises: modifying the group III alkyl derivative by the donation thereto of electron density to form a weaker Lewis acid; mixing the resulting modified group III alkyl derivative with the group V hydride; and impinging the mixture on the substrate.
Claim 3
Dependent Claim 47 words
The improved method of claim 1, wherein the modification of the group III alkyl derivative is accomplished by combining the alkyl derivative of the desired group III element with an alkyl derivative of a group V element, which is a Lewis Base, thereby forming a volatile adduct.
Claim 4
Dependent Claim 27 words
The improved method of claim 1, wherein the modification of the group III alkyl derivative is accomplished by replacing an alkyl group with an electron donating group.
Claim 5
Dependent Claim 19 words
The improved method of claim 1, wherein the modified derivative is prepared immediately before conveying it to the substrate.
Claim 6
Dependent Claim 28 words
The improved method of claim 3, wherein the modified derivative is prepared and isolated prior to the reaction with the group V hydride and deposition on the substrate.
Claim 7
Dependent Claim 13 words
The improved method of claim 1, wherein the group III element is indium.
Claim 8
Dependent Claim 30 words
The improved method of claim 1, wherein the vapor stream containing the group III alkyl derivative is maintained at a temperature above ambient to avoid condensing of the modified derivative.
Claim 9
Dependent Claim 15 words
The improved method of claim 1, wherein the vapor streams contain an excess of hydrogen.
Claim 10
Dependent Claim 22 words
The improved method of claim 1, wherein a mixture of group III alkyl derivatives is modified prior to conveying to the substrate.
Claim 11
Dependent Claim 18 words
The improved method of claim 1, wherein a mixture of group V hydrides is conveyed to the substrate.

References Cited (Backward Citations)

US3101280A Cited
US3556875A Cited
US3635771A Cited
US3663320A Cited
US3690915A Cited
US3664866A Cited
US3843398A Cited
US3867202A Cited
GB1593905A Cited
GB2007632B Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-03-13 1987-09-12 1988-03-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-03-13 1991-09-12 1992-03-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-03-13 1995-09-12 1996-03-13 $7700.00 Window Closed / Lapsed

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