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US4409308A Expired / Lapsed US ⏱️ 0.0 years remaining

Photoconductive member with two amorphous silicon layers

Assignee: Canon Inc
•
Filing: 1981-10-02
•
Granted: 1983-10-11
•
Expires: 2001-10-02
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Abstract

Abstract A photoconductive member comprises a support, a photoconductive layer constituted of an amorphous material containing silicon atoms as matrix and containing hydrogen atoms or halogen atoms, and an intermediate layer provided between them, said intermediate layer having a function to bar penetration of carriers from the side of the support into the photoconductive layer and to permit passage from the photoconductive layer to the support of photocarriers generated in the photoconductive layer by projection of electromagnetic waves and movement of the photocarriers toward the side of the support, and said intermediate layer being constituted of an amorphous material containing silicon atoms and oxygen atoms as constituents. A photoconductive member having a support, a photoconductive layer constituted of an amorphous material containing silicon atoms as matrix and containing hdyrogen atoms or halogen atoms as a constituent, and an intermediate layer provided between said support and said photoconductive layer, is characterized in that said intermediate layer is constituted of an amorphous material containing silicon atoms and oxygen atoms as constituent. A photoconductive member having a support a photoconductive layer constituted of an amorphous material containing silicon atoms as matrix and containing hydrogen atoms or halogen atoms as a constituent, and an intermediate layer provided between said support and said photoconductive layer, characterized in that said intermediate layer is constituted of an amorphous material containing silicon atoms and oxygen atoms as constituent.

Inventors

  • 👤 Isamu Shimizu
  • 👤 Shigeru Shirai
  • 👤 Eiichi Inoue

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:43
CPC Classifications
H; H10; H10F; H10F30/00; H10F30/10; H10F30/15; H10F71/00; H10F71/10; H10F71/103; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02P; Y02P70/00; Y02P70/50

Claims Analysis

Total Claims: 101
Claim 1
Independent Claim 106 words
A photoconductive member comprising: a support, a photoconductive layer constituted of an amorphous material containing silicon atoms as matrix and containing hydrogen atoms or halogen atoms, and an intermediate layer provided between them, side intermediate layer having a function to bar penetration of carriers from the said of the support into the photoconductive layer and to permit passage from the photoconductive layer to the support of photocarriers generated in the photoconductive layer by projection of electromagnetic waves and movement of the photocarriers toward the side of the support, and said intermediate layer being constituted of an amorphous material containing silicon atoms and oxygen atoms as constituents.
Claim 2
Dependent Claim 106 words
A photoconductive member comprising: a support, a photoconductive layer constituted of an amorphous material containing silicon atoms as matrix and containing hydrogen atoms or halogen atoms, and an intermediate layer provided between them, side intermediate layer having a function to bar penetration of carriers from the said of the support into the photoconductive layer and to permit passage from the photoconductive layer to the support of photocarriers generated in the photoconductive layer by projection of electromagnetic waves and movement of the photocarriers toward the side of the support, and said intermediate layer being constituted of an amorphous material containing silicon atoms and oxygen atoms as constituents.
Claim 3
Dependent Claim 25 words
A photoconductive member according to claim 1, wherein said amorphous material constituting the intermediate layer contains oxygen atoms in the range of 60-67 atomic percent.
Claim 4
Dependent Claim 22 words
A photoconductive member according to claim 1, wherein said amorphous material constituting the intermediate layer further contains hydrogen atoms as a constituent.
Claim 5
Dependent Claim 21 words
A photoconductive member according to claim 3, wherein said amorphous material contains hydrogen atoms in the range of 2-35 atomic percent.
Claim 6
Dependent Claim 35 words
A photoconductive member according to claim 1, wherein said amorphous material constituting the intermediate layer contains oxygen atoms in the range of 39-66 atomic percent and further hydrogen atoms 2-35 atomic percent as a constituent.
Claim 7
Dependent Claim 22 words
A photoconductive member according to claim 1, wherein said amorphous material constituting the intermediate layer further contains halogen atoms as a constituent.
Claim 8
Dependent Claim 21 words
A photoconductive member according to claim 6, wherein said amorphous material contains halogen atoms in the range of 1-20 atomic percent.
Claim 9
Dependent Claim 24 words
A photoconductive member according to claim 1, wherein said amorphous material constituting the intermediate layer further contains hydrogen atoms and halogen atoms as constituents.
Claim 10
Dependent Claim 29 words
A photoconductive member according to claim 8, wherein said amorphous material contains halogen atoms in the range of 1-20 atomic percent and hydrogen atoms up to 19 atomic percent.
Claim 11
Dependent Claim 14 words
A photoconductive member according to claim 1, wherein said intermediate layer is electrically insulative.
Claim 12
Dependent Claim 19 words
A photoconductive member according to claim 1, wherein said photoconductive layer has resistance of at least 5×10 9 Ωcm.
Claim 13
Dependent Claim 16 words
A photoconductive member according to claim 1, wherein said photoconductive layer is 1-100 microns in thickness.
Claim 14
Dependent Claim 21 words
A photoconductive member according to claim 1, wherein said photoconductive layer contains hydrogen atoms in the range of 1-40 atomic percent.
Claim 15
Dependent Claim 21 words
A photoconductive member according to claim 1, wherein said photoconductive layer contains halogen atoms in the range of 1-40 atomic percent.
Claim 16
Dependent Claim 26 words
A photoconductive member according to claim 1, wherein said photoconductive layer contains hydrogen atoms and halogen atoms in the range of 1-40 atomic percent in total.
Claim 17
Dependent Claim 14 words
A photoconductive member according to claim 1, wherein said photoconductive layer contains n-type impurity.
Claim 18
Dependent Claim 22 words
A photoconductive member according to claim 16, wherein said n-type impurity is an element in Group V A of the periodic table.
Claim 19
Dependent Claim 27 words
A photoconductive member according to claim 17, wherein said element in Group V A of the periodic table is selected from N, P, As, Sb and Bi.
Claim 20
Dependent Claim 28 words
A photoconductive member according to claim 16, wherein said photoconductive layer contains n-type impurity in the range of 10 -8 -10 -3 atomic ratio based on silicon atoms.
Claim 21
Dependent Claim 14 words
A photoconductive member according to claim 1, wherein said photoconductive layer contains p-type impurity.
Claim 22
Dependent Claim 22 words
A photoconductive member according to claim 20, wherein said p-type impurity is an element in Group III A of the periodic table.
Claim 23
Dependent Claim 23 words
A photoconductive member according to claim 21, wherein said element in Group III A is selected from B, Al, Ga, In and Tl.
Claim 24
Dependent Claim 28 words
A photoconductive member according to claim 20, wherein said photoconductive layer contains p-type impurity in the range of 10 -6 -10 -3 atomic ratio based on silicon atoms.
Claim 25
Dependent Claim 21 words
A photoconductive member according to claim 1, wherein an upper layer is provided on the upper surface of said photoconductive layer.
Claim 26
Dependent Claim 22 words
A photoconductive member according to claim 24, wherein said upper layer is composed of an amorphous material containing silicon atoms as matrix.
Claim 27
Dependent Claim 30 words
A photoconductive member according to claim 25, wherein said amorphous material further contains as constitution element at least one selected from the group consisting of carbon, oxygen and nitrogen atoms.
Claim 28
Dependent Claim 23 words
A photoconductive member according to claim 25 or 26, wherein said amorphous material further contains hydrogen atoms or halogen atoms as a constituent.
Claim 29
Dependent Claim 21 words
A photoconductive member according to claim 26, wherein said amorphous material contains carbon atoms in the range of 60-90 atomic percent.
Claim 30
Dependent Claim 31 words
A photoconductive member according to claim 25, wherein said upper layer contains oxygen atoms in the range of 39-66 atomic percent and hydrogen atoms in the range of 2-35 atomic percent.
Claim 31
Dependent Claim 38 words
A photoconductive member according to claim 25, wherein said upper layer contains oxygen atoms in the range of 48-66 atomic percent, halogen atoms in the range of 1-20 atomic percent and hydrogen atoms up to 19 atomic percent.
Claim 32
Dependent Claim 16 words
A photoconductive member according to claim 24, wherein said upper layer is 30-1000 A in thickness.
Claim 33
Dependent Claim 17 words
A photoconductive member according to claim 24, wherein said upper layer is composed of inorganic insulating materials.
Claim 34
Dependent Claim 17 words
A photoconductive member according to claim 24, wherein said upper layer is composed of organic insulating materials.
Claim 35
Dependent Claim 18 words
A photoconductive member according to claim 24, wherein said upper layer is non-photoconductive with respect to visible rays.
Claim 36
Dependent Claim 14 words
A photoconductive member according to claim 24, wherein said upper layer is electrically insulative.
Claim 37
Dependent Claim 24 words
A photoconductive member according to claim 1 or 24, wherein said photoconductive member further comprises a surface protecting layer of 0.5-70 microns in thickness.
Claim 38
Dependent Claim 40 words
A photoconductive member according to claim 1, wherein said intermediate layer contains oxygen atoms in the range of 48-66 atomic percent, and further halogen atoms in the range of 1-20 atomic percent and hydrogen atoms up to 19 atomic percent.
Claim 39
Dependent Claim 17 words
A photoconductive member according to claim 1, wherein halogen atom is selected from F, Cl and Br.
Claim 40
Dependent Claim 80 words
A photoconductive member having a support, a photoconductive layer constituted of an amorphous material containing silicon atoms as matrix and containing hydrogen atoms or halogen atoms as a constituent, and an intermediate layer provided between said support and said photoconductive layer, characterized in that said intermediate layer is constituted of an amorphous material containing silicon atoms and oxygen atoms as constitution elements wherein said intermediate layer is non-photoconductive in the visible light region and is from 30-1000 A° in thickness.
Claim 41
Dependent Claim 80 words
A photoconductive member having a support, a photoconductive layer constituted of an amorphous material containing silicon atoms as matrix and containing hydrogen atoms or halogen atoms as a constituent, and an intermediate layer provided between said support and said photoconductive layer, characterized in that said intermediate layer is constituted of an amorphous material containing silicon atoms and oxygen atoms as constitution elements wherein said intermediate layer is non-photoconductive in the visible light region and is from 30-1000 A° in thickness.
Claim 42
Dependent Claim 25 words
A photoconductive member according to claim 39, wherein said amorphous material constituting the intermediate layer contains oxygen atoms in the range of 60-67 atomic percent.
Claim 43
Dependent Claim 22 words
A photoconductive member according to claim 39, wherein said amorphous material constituting the intermediate layer further contains hydrogen atoms as a constituent.
Claim 44
Dependent Claim 21 words
A photoconductive member according to claim 41, wherein said amorphous material contains hydrogen atoms in the range of 2-35 atomic percent.
Claim 45
Dependent Claim 35 words
A photoconductive member according to claim 39, wherein said amorphous material constituting the intermediate layer contains oxygen atoms in the range of 39-66 atomic percent and further hydrogen atoms 2-35 atomic percent as a constituent.
Claim 46
Dependent Claim 22 words
A photoconductive member according to claim 39, wherein said amorphous material constituting the intermediate layer further contains halogen atoms as a constituent.
Claim 47
Dependent Claim 21 words
A photoconductive member according to claim 44, wherein said amorphous material contains halogen atoms in the range of 1-20 atomic percent.
Claim 48
Dependent Claim 24 words
A photoconductive member according to claim 39, wherein said amorphous material constituting the intermediate layer further contains hydrogen atoms and halogen atoms as constituents.
Claim 49
Dependent Claim 29 words
A photoconductive member according to claim 46, wherein said amorphous material contains halogen atoms in the range of 1-20 atomic percent and hydrogen atoms up to 19 atomic percent.
Claim 50
Dependent Claim 14 words
A photoconductive member according to claim 39, wherein said intermediate layer is electrically insulative.
Claim 51
Dependent Claim 19 words
A photoconductive member according to claim 39, wherein said photoconductive layer has resistance of at least 5×10 9 Ωcm.
Claim 52
Dependent Claim 16 words
A photoconductive member according to claim 39, wherein said photoconductive layer is 1-100 microns in thickness.
Claim 53
Dependent Claim 21 words
A photoconductive member according to claim 39, wherein said photoconductive layer contains hydrogen atoms in the range of 1-40 atomic percent.
Claim 54
Dependent Claim 21 words
A photoconductive member according to claim 39, wherein said photoconductive layer contains halogen atoms in the range of 1-40 atomic percent.
Claim 55
Dependent Claim 26 words
A photoconductive member according to claim 39, wherein said photoconductive layer contains hydrogen atoms and halogen atoms in the range of 1-40 atomic percent in total.
Claim 56
Dependent Claim 14 words
A photoconductive member according to claim 39, wherein said photoconductive layer contains n-type impurity.
Claim 57
Dependent Claim 22 words
A photoconductive member according to claim 54, wherein said n-type impurity is an element in Group V A of the periodic table.
Claim 58
Dependent Claim 27 words
A photoconductive member according to claim 55, wherein said element in Group V A of the periodic table is selected from N, P, As, Sb and Bi.
Claim 59
Dependent Claim 28 words
A photoconductive member according to claim 54, wherein said photoconductive layer contains n-type impurity in the range of 10 -8 -10 -3 atomic ratio based on silicon atoms.
Claim 60
Dependent Claim 14 words
A photoconductive member according to claim 39, wherein said photoconductive layer contains p-type impurity.
Claim 61
Dependent Claim 22 words
A photoconductive member according to claim 58, wherein said p-type impurity is an element in Group III A of the periodic table.
Claim 62
Dependent Claim 23 words
A photoconductive member according to claim 59, wherein said element in Group III A is selected from B, Al, Ga, In and Tl.
Claim 63
Dependent Claim 28 words
A photoconductive member according to claim 58, wherein said photoconductive layer contains p-type impurity in the range of 10 -6 -10 -3 atomic ratio based on silicon atoms.
Claim 64
Dependent Claim 21 words
A photoconductive member according to claim 39, wherein an upper layer is provided on the upper surface of said photoconductive layer.
Claim 65
Dependent Claim 22 words
A photoconductive member according to claim 62, wherein said upper layer is composed of an amorphous material containing silicon atoms as matrix.
Claim 66
Dependent Claim 30 words
A photoconductive member according to claim 63, wherein said amorphous material further contains as constitution element at least one selected from the group consisting of carbon, oxygen and nitrogen atoms.
Claim 67
Dependent Claim 23 words
A photoconductive member according to claim 63 or 64, wherein said amorphous material further contains hydrogen atoms or halogen atoms as a constituent.
Claim 68
Dependent Claim 21 words
A photoconductive member according to claim 64, wherein said amorphous material contains carbon atoms in the range of 60-90 atomic percent.
Claim 69
Dependent Claim 31 words
A photoconductive member according to claim 63, wherein said upper layer contains oxygen atoms in the range of 39-66 atomic percent and hydrogen atoms in the range of 2-35 atomic percent.
Claim 70
Dependent Claim 38 words
A photoconductive member according to claim 63, wherein said upper layer contains oxygen atoms in the range of 48-66 atomic percent, halogen atoms in the range of 1-20 atomic percent and hydrogen atoms up to 19 atomic percent.
Claim 71
Dependent Claim 16 words
A photoconductive member according to claim 62, wherein said upper layer is 30-1000 A in thickness.
Claim 72
Dependent Claim 17 words
A photoconductive member according to claim 62, wherein said upper layer is composed of inorganic insulating materials.
Claim 73
Dependent Claim 17 words
A photoconductive member according to claim 62, wherein said upper layer is composed of organic insulating materials.
Claim 74
Dependent Claim 18 words
A photoconductive member according to claim 62, wherein said upper layer is non-photoconductive with respect to visible rays.
Claim 75
Dependent Claim 14 words
A photoconductive member according to claim 62, wherein said upper layer is electrically insulative.
Claim 76
Dependent Claim 24 words
A photoconductive member according to claim 39 or 62, wherein said photoconductive member further comprises a surface protecting layer of 0.5-70 microns in thickness.
Claim 77
Dependent Claim 40 words
A photoconductive member according to claim 39, wherein said intermediate layer contains oxygen atoms in the range of 48-66 atomic percent, and further halogen atoms in the range of 1-20 atomic percent and hydrogen atoms up to 19 atomic percent.
Claim 78
Dependent Claim 68 words
A photoconductive member having a support, a photoconductive layer constituted of an amorphous material containing silicon atoms as matrix and containing hydrogen atoms or halogen atoms as a constituent, and a non-photoconductive layer in the visible light region consituted of an amorphous material containing silicon atoms and oxygen atoms as constitution elements in contact with said photoconductive layer wherein the non-photoconductive layer is from 30-1000 A° in thickness.
Claim 79
Dependent Claim 68 words
A photoconductive member having a support, a photoconductive layer constituted of an amorphous material containing silicon atoms as matrix and containing hydrogen atoms or halogen atoms as a constituent, and a non-photoconductive layer in the visible light region consituted of an amorphous material containing silicon atoms and oxygen atoms as constitution elements in contact with said photoconductive layer wherein the non-photoconductive layer is from 30-1000 A° in thickness.
Claim 80
Dependent Claim 25 words
A photoconductive member according to claim 76, wherein the amount of oxygen atoms in said amorphous material containing oxygen atoms ranges from 60-67 atomic percent.
Claim 81
Dependent Claim 21 words
A photoconductive member according to claim 76, wherein said amorphous material containing oxygen atoms further contains hydrogen atoms as a constituent.
Claim 82
Dependent Claim 21 words
A photoconductive member according to claim 78, wherein said amorphous material contains hydrogen atoms in the range of 2-35 atomic percent.
Claim 83
Dependent Claim 27 words
A photoconductive member according to claim 76, wherein said layer contains oxygen atoms in the range of 39-66 atomic percent and hydrogen atoms from 2-35 atomic percent.
Claim 84
Dependent Claim 21 words
A photoconductive member according to claim 76, wherein said amorphous material containing oxygen atoms further contains halogen atoms as a constituent.
Claim 85
Dependent Claim 21 words
A photoconductive member according to claim 81, wherein said amorphous material contains halogen atoms in the range of 1-20 atomic percent.
Claim 86
Dependent Claim 23 words
A photoconductive member according to claim 76, wherein said amorphous material containing oxygen atoms further contains hydrogen atoms and halogen atoms as constituents.
Claim 87
Dependent Claim 29 words
A photoconductive member according to claim 83, wherein said amorphous material contains halogen atoms in the range of 1-20 atomic percent and hydrogen atoms up to 19 atomic percent.
Claim 88
Dependent Claim 19 words
A photoconductive member according to claim 76, wherein said layer containing silicon atoms and oxygen atoms is electrically insulative.
Claim 89
Dependent Claim 19 words
A photoconductive member according to claim 76, wherein said photoconductive layer has resistance of at least 5×10 9 Ωcm.
Claim 90
Dependent Claim 16 words
A photoconductive member according to claim 76, wherein said photoconductive layer is 1-100 microns in thickness.
Claim 91
Dependent Claim 21 words
A photoconductive member according to claim 76, wherein said photoconductive layer contains hydrogen atoms in the range of 1-40 atomic percent.
Claim 92
Dependent Claim 21 words
A photoconductive member according to claim 76, wherein said photoconductive layer contains halogen atoms in the range of 1-40 atomic percent.
Claim 93
Dependent Claim 26 words
A photoconductive member according to claim 76, wherein said photoconductive layer contains hydrogen atoms and halogen atoms in the range of 1-40 atomic percent in total.
Claim 94
Dependent Claim 14 words
A photoconductive member according to claim 76, wherein said photoconductive layer contains n-type impurity.
Claim 95
Dependent Claim 22 words
A photoconductive member according to claim 91, wherein said n-type impurity is an element in Group V A of the periodic table.
Claim 96
Dependent Claim 27 words
A photoconductive member according to claim 92, wherein said element in Group V A of the periodic table is selected from N, P, As, Sb and Bi.
Claim 97
Dependent Claim 24 words
A photoconductive member according to claim 91, wherein said photoconductive layer contains n-type impurity in the atomic ratio of 10 -8 -10 -3 .
Claim 98
Dependent Claim 14 words
A photoconductive member according to claim 76, wherein said photoconductive layer contains p-type impurity.
Claim 99
Dependent Claim 22 words
A photoconductive member according to claim 95, wherein said p-type impurity is an element in Group III A of the periodic table.
Claim 100
Dependent Claim 23 words
A photoconductive member according to claim 96, wherein said element in Group III A is selected from B, Al, Ga, In, and Tl.
Claim 101
Dependent Claim 24 words
A photoconductive member according to claim 95, wherein said photoconductive layer contains p-type impurity in the atomic ratio of 10 -6 -10 -3 .

References Cited (Backward Citations)

US3041166A Cited
US4225222A Cited
US4265991A Cited
US4217374A Cited
US4226898A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-10 1987-04-11 1987-10-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-10 1991-04-11 1991-10-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-10 1995-04-11 1995-10-11 $7700.00 Window Closed / Lapsed

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