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US4377679A Expired / Lapsed US ⏱️ 0.0 years remaining

Photocurable compositions based on acrylate polyester urethanes

Assignee: Northrop Grumman Innovation Systems LLC
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Filing: 1982-01-28
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Granted: 1983-03-22
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Expires: 2002-01-28
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Abstract

Abstract Provided are processes for preparing compositions useful in photopolymerizable compositions, which processes comprise: A. reacting a polyether diol and an acrylic acid in about equal molar proportions; and B. 1. reacting a polyether diol and an acrylic acid in about equal molar proportions and 2. reacting the product of step B1, a hydroxyalkylacrylate and an organic diisocyanate in about equal molar proportions. Also provided are the products of these processes. These products are useful in photopolymerizable compositions which may typically contain, in addition to said products, N-vinyl-2-pyrrolidone and a photoinitiator.

Inventors

  • 👤 Claude J. Schmidle

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:53
CPC Classifications
C; C08; C08F; C08F290/00; C08F290/02; C08F290/06; C08F290/062; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/671; C08G18/672; Y; Y10; Y10S; Y10S525/00; Y10S525/92

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 45 words
A process for preparing compositions for use in photopolymerizable compositions comprising: A. reacting a polyether diol and an acrylic acid in about equal molar proportions, and B. reacting the product of step A, a hydroxyalkyl acrylate and an organic diisocyanate in about equal molar proportions.
Claim 2
Dependent Claim 45 words
A process for preparing compositions for use in photopolymerizable compositions comprising: A. reacting a polyether diol and an acrylic acid in about equal molar proportions, and B. reacting the product of step A, a hydroxyalkyl acrylate and an organic diisocyanate in about equal molar proportions.
Claim 3
Dependent Claim 14 words
The process of claim 1 wherein the polyether diol is a polypropylene glycol diol.
Claim 4
Dependent Claim 12 words
The process of claim 1 wherein the acrylic acid is acrylic acid.
Claim 5
Dependent Claim 17 words
The process of claim 1 wherein the polyether diol is a polypropylene glycol end-capped with ethylene oxide.
Claim 6
Dependent Claim 14 words
The process of claim 4 wherein the polypropylene glycol has the average formula: ##STR5##
Claim 7
Dependent Claim 17 words
The process of claim 1 wherein the hydroxyalkyl acrylate is selected from 2-hydroxyethyl acrylate and 2-hydroxypropyl acrylate.
Claim 8
Dependent Claim 13 words
The process of claim 1 wherein the organic diisocyanate is an aliphatic diisocyanate.
Claim 9
Dependent Claim 26 words
The process of claim 1 wherein the organic diisocyanate is selected from isophorone diisocyanate; 2,4-tolylene diisocyanate; 2,6-tolylene diisocyanate; hexamethylene diisocyanate; trimethyl hexamethylene diisocyanate and dicyclohexylmethane diisocyanate.
Claim 10
Dependent Claim 9 words
The product made by the process of claim 1.

References Cited (Backward Citations)

US3759809A Cited
US4064194A Cited
US4145511A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-03-21 1986-09-20 1987-03-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-03-21 1990-09-20 1991-03-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-03-21 1994-09-20 1995-03-22 $7700.00 Window Closed / Lapsed

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