US4309378A
Expired / Lapsed
US
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Process for the production of pneumatic tires having particularly high dynamic strength
Assignee: Bayer AG
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Filing: 1980-08-14
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Granted: 1982-01-05
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Expires: 2000-08-14
Abstract
Abstract The instant invention is directed to a process for the production of pneumatic tires having particularly high dynamic strength and low plastic deformability comprising casting or centrifugally casting the following liquid reaction system whose rapid hardening requires temperatures of at most 85° C.: (A) prepolymers or semiprepolymers of specified isocyanates and a polyol or polyol mixture having a hydroxyl functionality of 2.0 to 2.2 and an average molecular weight of from 1,000 to 3,000, wherein the molar ratio of polyol to diisocyanate is from 1:1.5 to 1:4.0, (B) specific aromatic diamine chain extenders, (C) catalysts, and (D) auxiliaries.
Inventors
- 👤 Otto Ganster
- 👤 Jurgen Schwindt
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 18:17
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; B; B29; B29C; B29C39/00; B29C39/02; B29C41/00; B29C41/02; B29C41/04; B29C41/042; B29C41/047; B29C45/00; B29C45/17; B29C45/26; B29C45/2616; B60; B60C; B60C1/00; C08G18/12; C08G2380/00
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
261 words
A process for the production of pneumatic tires having particularly high dynamic strength and low plastic deformability comprising casting, or centrifugally casting, the following liquid reaction system whose rapid hardening requires temperatures of at most 85° C.: (A) prepolymers or semiprepolymers of (i) an isocyanate selected from the group consisting of: (a) hexamethylene-1,6-diisocyanate, (b) 2,4- or 2,6-tolylene diisocyanate and mixtures thereof, (c) 4,4'- or 2,4'-diisocyanato-diphenylmethane and mixtures thereof, and (d) diisocyanato-diphenylmethane C 1 -C 4 alkylated from one to four times in the ortho position to the NCO-groups and (ii) a polyol or polyol mixture, having a hydroxyl functionality of 2.0 to 2.2 and an average molecular weight of 1,000 to 3,000 consisting of a single component or obtained by mixing several polyols having a molecular weight of 500 to 4,000, wherein the molar ratio of polyol to diisocyanate is from 1:1.5 to 1:4.0; (B) aromatic diamine chain extenders selected from the group consisting of: ##STR13## wherein R 1 and R 2 , which may be the same or different, represent C 2 H 5 --, C 3 H 7 -- and C 4 H 9 --; ##STR14## wherein R 1 , R 2 , R 3 and R 4 , which may be the same or different, represent C 2 H 5 -- and C 3 H 7 --; and ##STR15## wherein R 1 , R 2 and R 3 , which may be the same or different, represent C 2 H 5 --, C 3 H 7 -- and C 4 H 9 -- (C) catalyst; and (D) auxiliaries.
Claim 2
Dependent Claim
261 words
A process for the production of pneumatic tires having particularly high dynamic strength and low plastic deformability comprising casting, or centrifugally casting, the following liquid reaction system whose rapid hardening requires temperatures of at most 85° C.: (A) prepolymers or semiprepolymers of (i) an isocyanate selected from the group consisting of: (a) hexamethylene-1,6-diisocyanate, (b) 2,4- or 2,6-tolylene diisocyanate and mixtures thereof, (c) 4,4'- or 2,4'-diisocyanato-diphenylmethane and mixtures thereof, and (d) diisocyanato-diphenylmethane C 1 -C 4 alkylated from one to four times in the ortho position to the NCO-groups and (ii) a polyol or polyol mixture, having a hydroxyl functionality of 2.0 to 2.2 and an average molecular weight of 1,000 to 3,000 consisting of a single component or obtained by mixing several polyols having a molecular weight of 500 to 4,000, wherein the molar ratio of polyol to diisocyanate is from 1:1.5 to 1:4.0; (B) aromatic diamine chain extenders selected from the group consisting of: ##STR13## wherein R 1 and R 2 , which may be the same or different, represent C 2 H 5 --, C 3 H 7 -- and C 4 H 9 --; ##STR14## wherein R 1 , R 2 , R 3 and R 4 , which may be the same or different, represent C 2 H 5 -- and C 3 H 7 --; and ##STR15## wherein R 1 , R 2 and R 3 , which may be the same or different, represent C 2 H 5 --, C 3 H 7 -- and C 4 H 9 -- (C) catalyst; and (D) auxiliaries.
Claim 3
Dependent Claim
30 words
The process of claim 1, wherein said polyols have a molecular weight of 1,300 to 2,500 and wherein the molar ratio of polyol to isocyanate is from 1:1.5 to 1:3.0.
Claim 4
Dependent Claim
13 words
The process of claim 1, wherein said aromatic diamine chain extender is: ##STR16##
Claim 5
Dependent Claim
13 words
The process of claim 1, wherein said aromatic diamine chain extender is: ##STR17##
Claim 6
Dependent Claim
13 words
The process of claim 1, wherein said aromatic diamine chain extender is: ##STR18##
Claim 7
Dependent Claim
18 words
The process of claim 1, wherein hardening takes place at a temperature of from 50° to 85° C.
Claim 8
Dependent Claim
19 words
The process of claim 1, wherein said aromatic diamine chain extender is a mixture of the following diamines: ##STR19##
Claim 9
Dependent Claim
19 words
The process of claim 1, wherein said aromatic diamine chain extender is a mixture of the following diamines: ##STR20##
Claim 10
Dependent Claim
19 words
The process of claim 1, wherein said aromatic diamine chain extender is a mixture of the following diamines: ##STR21##
Claim 11
Dependent Claim
20 words
The process of claim 1, wherein said aromatic diamine chain extender is a mixture of the following diamines: ##STR22## ##STR23##
Claim 12
Dependent Claim
184 words
A process for the production of penumatic tires having particularly high dynamic strength and low plastic deformability comprising casting, or centrifugally casting, the following liquid reaction system whose rapid hardening requires temperatures of at most 85° C.: (A) prepolymers or semiprepolymers of (i) an isocyanate selected from the group consisting of: (a) hexamethylene-1,6-diisocyanate, (b) 2,4- or 2,6-tolylene diisocyanate and mixtures thereof, (c) 4,4'- or 2,4'-diisocyanato-diphenylmethane and mixtures thereof, and (d) diisocyanato-diphenylmethane C 1 -C 4 alkylated from one to four times in ortho position to the NCO-groups and (ii) a polyol or polyol mixture, having a hydroxyl functionality of 2.0 to 2.2 and an average molecular weight of 1,000 to 3,000 consisting of a single component or obtained by mixing several polyols having a molecular weight of 500 to 4,000, wherein the molar ratio of polyol to diisocyanate is from 1:1.5 to 1:4.0; (B) an aromatic diamine chain extender of the general formula: ##STR24## wherein R is C n H 2n+1 , n is an integer of from 4 to 10, and X is CH 3 -- or Cl; (C) catalyst; and (D) auxiliaries.
Claim 13
Dependent Claim
184 words
A process for the production of penumatic tires having particularly high dynamic strength and low plastic deformability comprising casting, or centrifugally casting, the following liquid reaction system whose rapid hardening requires temperatures of at most 85° C.: (A) prepolymers or semiprepolymers of (i) an isocyanate selected from the group consisting of: (a) hexamethylene-1,6-diisocyanate, (b) 2,4- or 2,6-tolylene diisocyanate and mixtures thereof, (c) 4,4'- or 2,4'-diisocyanato-diphenylmethane and mixtures thereof, and (d) diisocyanato-diphenylmethane C 1 -C 4 alkylated from one to four times in ortho position to the NCO-groups and (ii) a polyol or polyol mixture, having a hydroxyl functionality of 2.0 to 2.2 and an average molecular weight of 1,000 to 3,000 consisting of a single component or obtained by mixing several polyols having a molecular weight of 500 to 4,000, wherein the molar ratio of polyol to diisocyanate is from 1:1.5 to 1:4.0; (B) an aromatic diamine chain extender of the general formula: ##STR24## wherein R is C n H 2n+1 , n is an integer of from 4 to 10, and X is CH 3 -- or Cl; (C) catalyst; and (D) auxiliaries.
Claim 14
Dependent Claim
13 words
The process of claim 11, wherein said aromatic diamine chain extender is: ##STR25##
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1985-01-04 | 1985-07-06 | 1986-01-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1989-01-04 | 1989-07-06 | 1990-01-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1993-01-04 | 1993-07-06 | 1994-01-05 | $7700.00 | Window Closed / Lapsed |