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US4309378A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of pneumatic tires having particularly high dynamic strength

Assignee: Bayer AG
•
Filing: 1980-08-14
•
Granted: 1982-01-05
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Expires: 2000-08-14
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Abstract

Abstract The instant invention is directed to a process for the production of pneumatic tires having particularly high dynamic strength and low plastic deformability comprising casting or centrifugally casting the following liquid reaction system whose rapid hardening requires temperatures of at most 85° C.: (A) prepolymers or semiprepolymers of specified isocyanates and a polyol or polyol mixture having a hydroxyl functionality of 2.0 to 2.2 and an average molecular weight of from 1,000 to 3,000, wherein the molar ratio of polyol to diisocyanate is from 1:1.5 to 1:4.0, (B) specific aromatic diamine chain extenders, (C) catalysts, and (D) auxiliaries.

Inventors

  • 👤 Otto Ganster
  • 👤 Jurgen Schwindt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 18:17
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; B; B29; B29C; B29C39/00; B29C39/02; B29C41/00; B29C41/02; B29C41/04; B29C41/042; B29C41/047; B29C45/00; B29C45/17; B29C45/26; B29C45/2616; B60; B60C; B60C1/00; C08G18/12; C08G2380/00

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 261 words
A process for the production of pneumatic tires having particularly high dynamic strength and low plastic deformability comprising casting, or centrifugally casting, the following liquid reaction system whose rapid hardening requires temperatures of at most 85° C.: (A) prepolymers or semiprepolymers of (i) an isocyanate selected from the group consisting of: (a) hexamethylene-1,6-diisocyanate, (b) 2,4- or 2,6-tolylene diisocyanate and mixtures thereof, (c) 4,4'- or 2,4'-diisocyanato-diphenylmethane and mixtures thereof, and (d) diisocyanato-diphenylmethane C 1 -C 4 alkylated from one to four times in the ortho position to the NCO-groups and (ii) a polyol or polyol mixture, having a hydroxyl functionality of 2.0 to 2.2 and an average molecular weight of 1,000 to 3,000 consisting of a single component or obtained by mixing several polyols having a molecular weight of 500 to 4,000, wherein the molar ratio of polyol to diisocyanate is from 1:1.5 to 1:4.0; (B) aromatic diamine chain extenders selected from the group consisting of: ##STR13## wherein R 1 and R 2 , which may be the same or different, represent C 2 H 5 --, C 3 H 7 -- and C 4 H 9 --; ##STR14## wherein R 1 , R 2 , R 3 and R 4 , which may be the same or different, represent C 2 H 5 -- and C 3 H 7 --; and ##STR15## wherein R 1 , R 2 and R 3 , which may be the same or different, represent C 2 H 5 --, C 3 H 7 -- and C 4 H 9 -- (C) catalyst; and (D) auxiliaries.
Claim 2
Dependent Claim 261 words
A process for the production of pneumatic tires having particularly high dynamic strength and low plastic deformability comprising casting, or centrifugally casting, the following liquid reaction system whose rapid hardening requires temperatures of at most 85° C.: (A) prepolymers or semiprepolymers of (i) an isocyanate selected from the group consisting of: (a) hexamethylene-1,6-diisocyanate, (b) 2,4- or 2,6-tolylene diisocyanate and mixtures thereof, (c) 4,4'- or 2,4'-diisocyanato-diphenylmethane and mixtures thereof, and (d) diisocyanato-diphenylmethane C 1 -C 4 alkylated from one to four times in the ortho position to the NCO-groups and (ii) a polyol or polyol mixture, having a hydroxyl functionality of 2.0 to 2.2 and an average molecular weight of 1,000 to 3,000 consisting of a single component or obtained by mixing several polyols having a molecular weight of 500 to 4,000, wherein the molar ratio of polyol to diisocyanate is from 1:1.5 to 1:4.0; (B) aromatic diamine chain extenders selected from the group consisting of: ##STR13## wherein R 1 and R 2 , which may be the same or different, represent C 2 H 5 --, C 3 H 7 -- and C 4 H 9 --; ##STR14## wherein R 1 , R 2 , R 3 and R 4 , which may be the same or different, represent C 2 H 5 -- and C 3 H 7 --; and ##STR15## wherein R 1 , R 2 and R 3 , which may be the same or different, represent C 2 H 5 --, C 3 H 7 -- and C 4 H 9 -- (C) catalyst; and (D) auxiliaries.
Claim 3
Dependent Claim 30 words
The process of claim 1, wherein said polyols have a molecular weight of 1,300 to 2,500 and wherein the molar ratio of polyol to isocyanate is from 1:1.5 to 1:3.0.
Claim 4
Dependent Claim 13 words
The process of claim 1, wherein said aromatic diamine chain extender is: ##STR16##
Claim 5
Dependent Claim 13 words
The process of claim 1, wherein said aromatic diamine chain extender is: ##STR17##
Claim 6
Dependent Claim 13 words
The process of claim 1, wherein said aromatic diamine chain extender is: ##STR18##
Claim 7
Dependent Claim 18 words
The process of claim 1, wherein hardening takes place at a temperature of from 50° to 85° C.
Claim 8
Dependent Claim 19 words
The process of claim 1, wherein said aromatic diamine chain extender is a mixture of the following diamines: ##STR19##
Claim 9
Dependent Claim 19 words
The process of claim 1, wherein said aromatic diamine chain extender is a mixture of the following diamines: ##STR20##
Claim 10
Dependent Claim 19 words
The process of claim 1, wherein said aromatic diamine chain extender is a mixture of the following diamines: ##STR21##
Claim 11
Dependent Claim 20 words
The process of claim 1, wherein said aromatic diamine chain extender is a mixture of the following diamines: ##STR22## ##STR23##
Claim 12
Dependent Claim 184 words
A process for the production of penumatic tires having particularly high dynamic strength and low plastic deformability comprising casting, or centrifugally casting, the following liquid reaction system whose rapid hardening requires temperatures of at most 85° C.: (A) prepolymers or semiprepolymers of (i) an isocyanate selected from the group consisting of: (a) hexamethylene-1,6-diisocyanate, (b) 2,4- or 2,6-tolylene diisocyanate and mixtures thereof, (c) 4,4'- or 2,4'-diisocyanato-diphenylmethane and mixtures thereof, and (d) diisocyanato-diphenylmethane C 1 -C 4 alkylated from one to four times in ortho position to the NCO-groups and (ii) a polyol or polyol mixture, having a hydroxyl functionality of 2.0 to 2.2 and an average molecular weight of 1,000 to 3,000 consisting of a single component or obtained by mixing several polyols having a molecular weight of 500 to 4,000, wherein the molar ratio of polyol to diisocyanate is from 1:1.5 to 1:4.0; (B) an aromatic diamine chain extender of the general formula: ##STR24## wherein R is C n H 2n+1 , n is an integer of from 4 to 10, and X is CH 3 -- or Cl; (C) catalyst; and (D) auxiliaries.
Claim 13
Dependent Claim 184 words
A process for the production of penumatic tires having particularly high dynamic strength and low plastic deformability comprising casting, or centrifugally casting, the following liquid reaction system whose rapid hardening requires temperatures of at most 85° C.: (A) prepolymers or semiprepolymers of (i) an isocyanate selected from the group consisting of: (a) hexamethylene-1,6-diisocyanate, (b) 2,4- or 2,6-tolylene diisocyanate and mixtures thereof, (c) 4,4'- or 2,4'-diisocyanato-diphenylmethane and mixtures thereof, and (d) diisocyanato-diphenylmethane C 1 -C 4 alkylated from one to four times in ortho position to the NCO-groups and (ii) a polyol or polyol mixture, having a hydroxyl functionality of 2.0 to 2.2 and an average molecular weight of 1,000 to 3,000 consisting of a single component or obtained by mixing several polyols having a molecular weight of 500 to 4,000, wherein the molar ratio of polyol to diisocyanate is from 1:1.5 to 1:4.0; (B) an aromatic diamine chain extender of the general formula: ##STR24## wherein R is C n H 2n+1 , n is an integer of from 4 to 10, and X is CH 3 -- or Cl; (C) catalyst; and (D) auxiliaries.
Claim 14
Dependent Claim 13 words
The process of claim 11, wherein said aromatic diamine chain extender is: ##STR25##

References Cited (Backward Citations)

US3428610A Cited
US3794621A Cited
US3701374A Cited
US4029730A Cited
US3963681A Cited
GB1534258A Cited
US4096101A Cited
US4208507A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-01-04 1985-07-06 1986-01-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-01-04 1989-07-06 1990-01-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-01-04 1993-07-06 1994-01-05 $7700.00 Window Closed / Lapsed

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