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US4304713A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for preparing a foamed perfluorocarbon dielectric coaxial cable

Assignee: Commscope Technologies LLC
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Filing: 1980-02-29
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Granted: 1981-12-08
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Expires: 2000-02-29
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Abstract

Abstract An improved foamable dielectric composition comprising a melt extrudable perfluorocarbon resin containing therein (i) a polytetrafluoroethylene (PTFE) nucleating agent and (ii) a volatile blowing agent, preferably a lower fluorocarbon blowing agent having only one or two carbon atoms; a process for forming such a composition; and, products produced therewith. More specifically, a foamed melt extrudable fluorinated ethylene-propylene (FEP) polymer containing therein a PTFE nucleating agent and blown to a foamed structure by means of a volatile fluid--e.g., a lower fluorocarbon such as fluoromethane or, preferably, fluoroethane, a process for forming such a foamed compostion; and, products produced therewith such as jacketed electrical conductors and/or coaxial cables wherein at least one conductor is bonded to such a foamed melt extrudable resin. The foamed dielectric melt extrudable resin is characterized by its thermal stability, fire resistance, small closed cell structure, low density, and low insulating loss characteristics. In a preferred embodiment, the melt extrudable foamed resin comprises a perfluorocarbon polymer having a closed cellular structure with cells ranging from 10 to 40 mils., a density at least as low as 1.0 g./cc., and an insulation loss of less than 1.8 db/100 ft. at 1000 MHz.

Inventors

  • 👤 Robert D. Perelman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:43
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0061; C08J9/04; C08J9/12; C08J9/14; C08J9/143; C08J9/144; H; H01; H01B; H01B11/00; H01B11/18; H01B11/1834; H01B11/1839; H01B13/00; H01B13/06; H01B13/14; H01B13/142; C08J2327/00; C08J2327/02; C08J2327/12; C08J2427/00; Y; Y10; Y10S; Y10S264/00; Y10S264/05; Y10S264/13; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49117; Y10T29/49123; Y10T29/49826; Y10T29/49885

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 134 words
A process for preparing the core for a foam dielectric coaxial cable, said process comprising the steps of: (a) forming a mixture of a melt extrudable fluorinated ethylene-propylene polymer and a polytetrafluoroethylene nucleating agent; (b) heating the polymer and nucleating agent mixture to the molten state; (c) extruding the molten mixture through an extrusion die while feeding a continuous conductor axially through the extrusion die so as to form a layer of foam dielectric surrounding and in intimate contact with the continuous conductor along the entire length and about the entire periphery thereof; (d) dissolving or injecting a volatile liquid blowing agent in the melt extrudable polymer at a point in the process prior to exit of the moisture from the extrusion die; and, (e) recovering the foamed articles exiting from the extrusion die.
Claim 2
Dependent Claim 134 words
A process for preparing the core for a foam dielectric coaxial cable, said process comprising the steps of: (a) forming a mixture of a melt extrudable fluorinated ethylene-propylene polymer and a polytetrafluoroethylene nucleating agent; (b) heating the polymer and nucleating agent mixture to the molten state; (c) extruding the molten mixture through an extrusion die while feeding a continuous conductor axially through the extrusion die so as to form a layer of foam dielectric surrounding and in intimate contact with the continuous conductor along the entire length and about the entire periphery thereof; (d) dissolving or injecting a volatile liquid blowing agent in the melt extrudable polymer at a point in the process prior to exit of the moisture from the extrusion die; and, (e) recovering the foamed articles exiting from the extrusion die.
Claim 3
Dependent Claim 17 words
The process of claim 1 wherein the fluorinated ethylene-propylene polymer is a copolymer of tetrafluoroethylene and hexafluoropropylene.
Claim 4
Dependent Claim 14 words
The process of claim 1 wherein the volatile liquid blowing agent is a fluorocarbon.
Claim 5
Dependent Claim 21 words
The process of claim 1 wherein the fluorocarbon blowing agent is a lower fluorocarbon having from 1 to 2 carbon atoms.
Claim 6
Dependent Claim 17 words
The process of claim 4 wherein the lower fluorocarbon is a fluoroethane represented by the formula: ##STR5##
Claim 7
Dependent Claim 12 words
The process of claim 1 wherein the fluorocarbon blowing agent is 1,2-dichloro-1,1,2,2-tetrafluoroethane.
Claim 8
Dependent Claim 32 words
The process of claim 1 wherein on the order of 0.5 parts by weight of polytetrafluoroethylene are contained within on the order of 100 parts by weight of the fluorinated ethylene-propylene polymer.
Claim 9
Dependent Claim 18 words
The process of claim 1 wherein the average particle size of the polytetrafluoroethylene is less than 200 microns.

References Cited (Backward Citations)

US3072583A Cited
US3843757A Cited
US3575897A Cited
US3962153A Cited
US4107354A Cited
US4075265A Cited
US4048208A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-12-07 1985-06-08 1985-12-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-12-07 1989-06-08 1989-12-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-12-07 1993-06-08 1993-12-08 $7700.00 Window Closed / Lapsed

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