Patent US4297266A successfully refreshed from Google Patents.
US4297266A
Expired / Lapsed
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Microfilled dental composite and method using the same
Assignee: Den Mat Inc
•
Filing: 1980-02-08
•
Granted: 1981-10-27
•
Expires: 2000-02-08
Abstract
Abstract A filled-resin dental composite. The filler is a mixture of hydrophobic silica particles about 0.01 to 0.04 micron in diameter and glass particles about 2 to 30 microns in diameter. Preferably, the glass is x-ray opaque. An improved method for restoring carious lesions in a living tooth is presented, using the composite.
Inventors
- 👤 Robert L. Ibsen
- 👤 William R. Glace
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 15:39
CPC Classifications
A; A61; A61K; A61K6/00; A61K6/80; A61K6/884; A61K6/887
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
71 words
A filled-resin dental composite consisting essentially of ______________________________________
Component Parts by Weight
______________________________________
Ethoxylated bisphenol A dimethacrylate
53-17.5
Triethylene glycol dimethacrylate
4-13.5
Cure accelerator 0.25-1.0
Antioxidant 0.15-0.5
Curing agent 0.25-1.0
Ultra violet light absorbent
0.4-1.4
Sub-micron hydrophobic silica particles
10-30
Glass particles 20-67,
______________________________________ the silica particles ranging from about 0.1 micron to 0.04 micron in diameter and the glass particles ranging from about two to about thirty microns in diameter.
Claim 2
Dependent Claim
71 words
A filled-resin dental composite consisting essentially of ______________________________________
Component Parts by Weight
______________________________________
Ethoxylated bisphenol A dimethacrylate
53-17.5
Triethylene glycol dimethacrylate
4-13.5
Cure accelerator 0.25-1.0
Antioxidant 0.15-0.5
Curing agent 0.25-1.0
Ultra violet light absorbent
0.4-1.4
Sub-micron hydrophobic silica particles
10-30
Glass particles 20-67,
______________________________________ the silica particles ranging from about 0.1 micron to 0.04 micron in diameter and the glass particles ranging from about two to about thirty microns in diameter.
Claim 3
Dependent Claim
12 words
The dental composite of claim 1 wherein the glass is x-ray opaque.
Claim 4
Dependent Claim
70 words
A veneering dental paste for heat curing consisting essentially of ______________________________________
Component Parts by weight
______________________________________
Ethoxylated bisphenol A dimethacrylate
53-17.5
Triethylene glycol dimethacrylate
4-13.5
Antioxidant 0.15-0.5
Benzoyl peroxide 0.25-1.00
Ultra-violet light absorbent
0.25-1.00
Sub-micron hydrophobic silica particles
10-30
Glass particles 20-67,
______________________________________ the silica particles ranging from about 0.01 micron to 0.04 micron in diameter and the glass particles ranging from about two to about thirty microns in diameter.
Claim 5
Dependent Claim
70 words
A veneering dental paste for heat curing consisting essentially of ______________________________________
Component Parts by weight
______________________________________
Ethoxylated bisphenol A dimethacrylate
53-17.5
Triethylene glycol dimethacrylate
4-13.5
Antioxidant 0.15-0.5
Benzoyl peroxide 0.25-1.00
Ultra-violet light absorbent
0.25-1.00
Sub-micron hydrophobic silica particles
10-30
Glass particles 20-67,
______________________________________ the silica particles ranging from about 0.01 micron to 0.04 micron in diameter and the glass particles ranging from about two to about thirty microns in diameter.
Claim 6
Dependent Claim
12 words
The dental paste of claim 3 wherein the glass is x-ray opaque.
Claim 7
Dependent Claim
77 words
A filled-resin composite consisting essentially of ______________________________________
Component Parts by Weight
______________________________________
Ethoxylated bisphenol A dimethacrylate
53-17.5
Triethylene glycol dimethacrylate
4-13.5
2-hydroxy-4-methoxy benzophenone
0.4-1.5
Butyl hydroxy toluene 0.15-0.5
Benzoyl peroxide 0.25-1.0
2-hydroxyethyl-p-toluidine
0.25-1.0
Sub-micron hydrophobic silica particles
10-30
Barium-containing glass particles
20-67,
______________________________________ the particles size of the silica being in the range of about 0.01-0.04 micron and the particle size of the glass in the range of about two to thirty microns, averaging about seven microns.
Claim 8
Dependent Claim
77 words
A filled-resin composite consisting essentially of ______________________________________
Component Parts by Weight
______________________________________
Ethoxylated bisphenol A dimethacrylate
53-17.5
Triethylene glycol dimethacrylate
4-13.5
2-hydroxy-4-methoxy benzophenone
0.4-1.5
Butyl hydroxy toluene 0.15-0.5
Benzoyl peroxide 0.25-1.0
2-hydroxyethyl-p-toluidine
0.25-1.0
Sub-micron hydrophobic silica particles
10-30
Barium-containing glass particles
20-67,
______________________________________ the particles size of the silica being in the range of about 0.01-0.04 micron and the particle size of the glass in the range of about two to thirty microns, averaging about seven microns.
Claim 9
Dependent Claim
57 words
A microfilled dental composite consisting essentially of ______________________________________
Approximate
Ingredient Parts by Weight
______________________________________
Ethoxylated bisphenol A dimethacrylate
21
Triethylene glycol dimethacrylate
5
2-hydroxy-4-methoxybenzophenone
0.5
Butyl hydroxy toluene 0.2
Benzoyl peroxide 0.4
2-hydroxyethyl-p-toluidine
0.4
sub-micron hydrophobic silica particles
20
Glass particles 52,
______________________________________ the particle sizes of the fillers being approximately: silica 0.01-0.04 micron glass 2-30 microns.
Claim 10
Dependent Claim
57 words
A microfilled dental composite consisting essentially of ______________________________________
Approximate
Ingredient Parts by Weight
______________________________________
Ethoxylated bisphenol A dimethacrylate
21
Triethylene glycol dimethacrylate
5
2-hydroxy-4-methoxybenzophenone
0.5
Butyl hydroxy toluene 0.2
Benzoyl peroxide 0.4
2-hydroxyethyl-p-toluidine
0.4
sub-micron hydrophobic silica particles
20
Glass particles 52,
______________________________________ the particle sizes of the fillers being approximately: silica 0.01-0.04 micron glass 2-30 microns.
Claim 11
Dependent Claim
21 words
The dental composite of claim 6 wherein the glass contains a barium compound in an amount to render it x-ray opaque.
Claim 12
Dependent Claim
37 words
A microfilled dental composite consisting essentially of ______________________________________
Approximate
Ingredient Parts by Weight
______________________________________
Triethylene glycol dimethacrylate
11
Ethoxylated bisphenol A dimethacrylate
16.9
Sub-micron-hydrophobic silica particles
19.7
Glass particles 52.1,
______________________________________ silica 0.01-0.04 micron glass 2-30 microns.
Claim 13
Dependent Claim
37 words
A microfilled dental composite consisting essentially of ______________________________________
Approximate
Ingredient Parts by Weight
______________________________________
Triethylene glycol dimethacrylate
11
Ethoxylated bisphenol A dimethacrylate
16.9
Sub-micron-hydrophobic silica particles
19.7
Glass particles 52.1,
______________________________________ silica 0.01-0.04 micron glass 2-30 microns.
Claim 14
Dependent Claim
12 words
The dental composite of claim 8 wherein the glass is x-ray opaque.
Claim 15
Dependent Claim
40 words
A microfilled dental composite consisting essentially of ______________________________________
Approximate
Component Parts by Weight
______________________________________
Bis-GMA 36
Triethylene glycol dimethacrylate
24
Sub-micron hydrophobic silica particles
20
Glass particles 20,
______________________________________ the particle sizes being approximately: silica 0.01-0.04 micron glass 2-30 microns.
Claim 16
Dependent Claim
40 words
A microfilled dental composite consisting essentially of ______________________________________
Approximate
Component Parts by Weight
______________________________________
Bis-GMA 36
Triethylene glycol dimethacrylate
24
Sub-micron hydrophobic silica particles
20
Glass particles 20,
______________________________________ the particle sizes being approximately: silica 0.01-0.04 micron glass 2-30 microns.
Claim 17
Dependent Claim
12 words
The dental composite of claim 10 wherein the glass is x-ray opaque.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-10-26 | 1985-04-27 | 1985-10-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-10-26 | 1989-04-27 | 1989-10-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-10-26 | 1993-04-27 | 1993-10-27 | $7700.00 | Window Closed / Lapsed |