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US4297266A Expired / Lapsed US ⏱️ 0.0 years remaining

Microfilled dental composite and method using the same

Assignee: Den Mat Inc
•
Filing: 1980-02-08
•
Granted: 1981-10-27
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Expires: 2000-02-08
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Abstract

Abstract A filled-resin dental composite. The filler is a mixture of hydrophobic silica particles about 0.01 to 0.04 micron in diameter and glass particles about 2 to 30 microns in diameter. Preferably, the glass is x-ray opaque. An improved method for restoring carious lesions in a living tooth is presented, using the composite.

Inventors

  • 👤 Robert L. Ibsen
  • 👤 William R. Glace

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 13:42
CPC Classifications
A; A61; A61K; A61K6/00; A61K6/80; A61K6/884; A61K6/887

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 71 words
A filled-resin dental composite consisting essentially of ______________________________________ Component Parts by Weight ______________________________________ Ethoxylated bisphenol A dimethacrylate 53-17.5 Triethylene glycol dimethacrylate 4-13.5 Cure accelerator 0.25-1.0 Antioxidant 0.15-0.5 Curing agent 0.25-1.0 Ultra violet light absorbent 0.4-1.4 Sub-micron hydrophobic silica particles 10-30 Glass particles 20-67, ______________________________________ the silica particles ranging from about 0.1 micron to 0.04 micron in diameter and the glass particles ranging from about two to about thirty microns in diameter.
Claim 2
Dependent Claim 71 words
A filled-resin dental composite consisting essentially of ______________________________________ Component Parts by Weight ______________________________________ Ethoxylated bisphenol A dimethacrylate 53-17.5 Triethylene glycol dimethacrylate 4-13.5 Cure accelerator 0.25-1.0 Antioxidant 0.15-0.5 Curing agent 0.25-1.0 Ultra violet light absorbent 0.4-1.4 Sub-micron hydrophobic silica particles 10-30 Glass particles 20-67, ______________________________________ the silica particles ranging from about 0.1 micron to 0.04 micron in diameter and the glass particles ranging from about two to about thirty microns in diameter.
Claim 3
Dependent Claim 12 words
The dental composite of claim 1 wherein the glass is x-ray opaque.
Claim 4
Dependent Claim 70 words
A veneering dental paste for heat curing consisting essentially of ______________________________________ Component Parts by weight ______________________________________ Ethoxylated bisphenol A dimethacrylate 53-17.5 Triethylene glycol dimethacrylate 4-13.5 Antioxidant 0.15-0.5 Benzoyl peroxide 0.25-1.00 Ultra-violet light absorbent 0.25-1.00 Sub-micron hydrophobic silica particles 10-30 Glass particles 20-67, ______________________________________ the silica particles ranging from about 0.01 micron to 0.04 micron in diameter and the glass particles ranging from about two to about thirty microns in diameter.
Claim 5
Dependent Claim 70 words
A veneering dental paste for heat curing consisting essentially of ______________________________________ Component Parts by weight ______________________________________ Ethoxylated bisphenol A dimethacrylate 53-17.5 Triethylene glycol dimethacrylate 4-13.5 Antioxidant 0.15-0.5 Benzoyl peroxide 0.25-1.00 Ultra-violet light absorbent 0.25-1.00 Sub-micron hydrophobic silica particles 10-30 Glass particles 20-67, ______________________________________ the silica particles ranging from about 0.01 micron to 0.04 micron in diameter and the glass particles ranging from about two to about thirty microns in diameter.
Claim 6
Dependent Claim 12 words
The dental paste of claim 3 wherein the glass is x-ray opaque.
Claim 7
Dependent Claim 77 words
A filled-resin composite consisting essentially of ______________________________________ Component Parts by Weight ______________________________________ Ethoxylated bisphenol A dimethacrylate 53-17.5 Triethylene glycol dimethacrylate 4-13.5 2-hydroxy-4-methoxy benzophenone 0.4-1.5 Butyl hydroxy toluene 0.15-0.5 Benzoyl peroxide 0.25-1.0 2-hydroxyethyl-p-toluidine 0.25-1.0 Sub-micron hydrophobic silica particles 10-30 Barium-containing glass particles 20-67, ______________________________________ the particles size of the silica being in the range of about 0.01-0.04 micron and the particle size of the glass in the range of about two to thirty microns, averaging about seven microns.
Claim 8
Dependent Claim 77 words
A filled-resin composite consisting essentially of ______________________________________ Component Parts by Weight ______________________________________ Ethoxylated bisphenol A dimethacrylate 53-17.5 Triethylene glycol dimethacrylate 4-13.5 2-hydroxy-4-methoxy benzophenone 0.4-1.5 Butyl hydroxy toluene 0.15-0.5 Benzoyl peroxide 0.25-1.0 2-hydroxyethyl-p-toluidine 0.25-1.0 Sub-micron hydrophobic silica particles 10-30 Barium-containing glass particles 20-67, ______________________________________ the particles size of the silica being in the range of about 0.01-0.04 micron and the particle size of the glass in the range of about two to thirty microns, averaging about seven microns.
Claim 9
Dependent Claim 57 words
A microfilled dental composite consisting essentially of ______________________________________ Approximate Ingredient Parts by Weight ______________________________________ Ethoxylated bisphenol A dimethacrylate 21 Triethylene glycol dimethacrylate 5 2-hydroxy-4-methoxybenzophenone 0.5 Butyl hydroxy toluene 0.2 Benzoyl peroxide 0.4 2-hydroxyethyl-p-toluidine 0.4 sub-micron hydrophobic silica particles 20 Glass particles 52, ______________________________________ the particle sizes of the fillers being approximately: silica 0.01-0.04 micron glass 2-30 microns.
Claim 10
Dependent Claim 57 words
A microfilled dental composite consisting essentially of ______________________________________ Approximate Ingredient Parts by Weight ______________________________________ Ethoxylated bisphenol A dimethacrylate 21 Triethylene glycol dimethacrylate 5 2-hydroxy-4-methoxybenzophenone 0.5 Butyl hydroxy toluene 0.2 Benzoyl peroxide 0.4 2-hydroxyethyl-p-toluidine 0.4 sub-micron hydrophobic silica particles 20 Glass particles 52, ______________________________________ the particle sizes of the fillers being approximately: silica 0.01-0.04 micron glass 2-30 microns.
Claim 11
Dependent Claim 21 words
The dental composite of claim 6 wherein the glass contains a barium compound in an amount to render it x-ray opaque.
Claim 12
Dependent Claim 37 words
A microfilled dental composite consisting essentially of ______________________________________ Approximate Ingredient Parts by Weight ______________________________________ Triethylene glycol dimethacrylate 11 Ethoxylated bisphenol A dimethacrylate 16.9 Sub-micron-hydrophobic silica particles 19.7 Glass particles 52.1, ______________________________________ silica 0.01-0.04 micron glass 2-30 microns.
Claim 13
Dependent Claim 37 words
A microfilled dental composite consisting essentially of ______________________________________ Approximate Ingredient Parts by Weight ______________________________________ Triethylene glycol dimethacrylate 11 Ethoxylated bisphenol A dimethacrylate 16.9 Sub-micron-hydrophobic silica particles 19.7 Glass particles 52.1, ______________________________________ silica 0.01-0.04 micron glass 2-30 microns.
Claim 14
Dependent Claim 12 words
The dental composite of claim 8 wherein the glass is x-ray opaque.
Claim 15
Dependent Claim 40 words
A microfilled dental composite consisting essentially of ______________________________________ Approximate Component Parts by Weight ______________________________________ Bis-GMA 36 Triethylene glycol dimethacrylate 24 Sub-micron hydrophobic silica particles 20 Glass particles 20, ______________________________________ the particle sizes being approximately: silica 0.01-0.04 micron glass 2-30 microns.
Claim 16
Dependent Claim 40 words
A microfilled dental composite consisting essentially of ______________________________________ Approximate Component Parts by Weight ______________________________________ Bis-GMA 36 Triethylene glycol dimethacrylate 24 Sub-micron hydrophobic silica particles 20 Glass particles 20, ______________________________________ the particle sizes being approximately: silica 0.01-0.04 micron glass 2-30 microns.
Claim 17
Dependent Claim 12 words
The dental composite of claim 10 wherein the glass is x-ray opaque.

References Cited (Backward Citations)

US3926906A Cited
US3770811A Cited
US4032504A Cited
US4150012A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-10-26 1985-04-27 1985-10-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-10-26 1989-04-27 1989-10-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-10-26 1993-04-27 1993-10-27 $7700.00 Window Closed / Lapsed

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