← Back to Patent Explorer
US4239052A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of transporting viscous hydrocarbons

Assignee: ConocoPhillips Co
•
Filing: 1979-02-21
•
Granted: 1980-12-16
•
Expires: 1999-02-21
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract An improvement in the method of transporting viscous hydrocarbons through pipes is disclosed. Briefly, the improvement comprises adding water containing an effective amount of a combination of an ethoxylated alkyl phenol and a low molecular weight alkaryl sulfonate. The resulting emulsion has a lower viscosity and is more easily transported.

Inventors

  • 👤 Gifford G. McClaflin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:06
CPC Classifications
F; F17; F17D; F17D1/00; F17D1/08; F17D1/16; F17D1/17; Y; Y10; Y10T; Y10T137/00; Y10T137/0318; Y10T137/0391

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 201 words
In the method of pumping a viscous hydrocarbon through a pipe the improvement which comprises forming an oil-in-water emulsion by adding to said hydrocarbon from about 20 to about 80 volume percent of an aqueous solution containing, as the only essential materials, an effective amount, based on said hydrocarbon, of a combination of about 50 to about 10,000 parts per million of an ethoxylated alkyl phenol and about 50 to about 10,000 parts per million of a water-soluble alkaryl sulfonate, said ethoxylated alkyl phenol being selected from the group consisting of monoalkyl phenols and dialkyl phenols, wherein the alkyl group contains from about 6 to about 15 carbon atoms, and which contains from about 25 to about 75 ethoxy groups and said water-soluble alkaryl sulfonate has a molecular weight below about 410 and is represented by the formula R.sub.(n) Ar--SO.sub.3 M wherein Ar is an aromatic moiety which is phenyl, tolyl, xylyl, or ethylphenyl, R is a linear or branched alkyl group containing 4 to 16 carbon atoms, n is an integer of 1 or 2, M is sodium, potassium, or ammonium, and the total number of carbon atoms in the alkyl groups is in the range of 8 to 16.
Claim 2
Dependent Claim 201 words
In the method of pumping a viscous hydrocarbon through a pipe the improvement which comprises forming an oil-in-water emulsion by adding to said hydrocarbon from about 20 to about 80 volume percent of an aqueous solution containing, as the only essential materials, an effective amount, based on said hydrocarbon, of a combination of about 50 to about 10,000 parts per million of an ethoxylated alkyl phenol and about 50 to about 10,000 parts per million of a water-soluble alkaryl sulfonate, said ethoxylated alkyl phenol being selected from the group consisting of monoalkyl phenols and dialkyl phenols, wherein the alkyl group contains from about 6 to about 15 carbon atoms, and which contains from about 25 to about 75 ethoxy groups and said water-soluble alkaryl sulfonate has a molecular weight below about 410 and is represented by the formula R.sub.(n) Ar--SO.sub.3 M wherein Ar is an aromatic moiety which is phenyl, tolyl, xylyl, or ethylphenyl, R is a linear or branched alkyl group containing 4 to 16 carbon atoms, n is an integer of 1 or 2, M is sodium, potassium, or ammonium, and the total number of carbon atoms in the alkyl groups is in the range of 8 to 16.
Claim 3
Dependent Claim 13 words
The method of claim 1 wherein the ethoxylated phenol is a monoalkyl phenol.
Claim 4
Dependent Claim 38 words
The method of claim 2 wherein the alkaryl sulfonate has a molecular weight below about 375 and is represented by the formula ##STR2## wherein R is an alkyl group containing from about 9 to about 14 carbon atoms.
Claim 5
Dependent Claim 28 words
The method of claim 3 wherein the ethoxylated phenol is a monooctyl phenol containing about 30 to about 70 moles of ethylene oxide per mole of monooctyl phenol.
Claim 6
Dependent Claim 12 words
The method of claim 4 wherein said hydrocarbon is a crude oil.
Claim 7
Dependent Claim 31 words
The method of claim 1 wherein the amount of aqueous solution added to said hydrocarbon is in the range of about 30 to about 60 volume percent, base on said hydrocarbon.
Claim 8
Dependent Claim 44 words
The method of claim 6 wherein the aqueous solution contains, based on said hydrocarbon, a combination of about 100 to about 1,000 parts per million of an ethoxylated alkyl phenol and about 100 to about 1,000 parts per million of a water-soluble alkaryl sulfonate.
Claim 9
Dependent Claim 38 words
The method of claim 7 wherein the alkaryl sulfonate has a molecular weight below about 375 and is represented by the formula ##STR3## wherein R is an alkyl group containing from about 9 to about 14 carbon atoms.
Claim 10
Dependent Claim 28 words
The method of claim 8 wherein the ethoxylated phenol is a monooctyl phenol containing about 30 to about 70 moles of ethylene oxide per mole of monooctyl phenol.
Claim 11
Dependent Claim 21 words
The method of claim 9 wherein the alkyl group of said alkaryl sufonate contains about 10 to about 13 carbon atoms.
Claim 12
Dependent Claim 12 words
The method of claim 10 wherein said hydrocarbon is a crude oil.

References Cited (Backward Citations)

US2447475A Cited
US3380531A Cited
US3491835A Cited
US3467195A Cited
US3811505A Cited
US3943954A Cited
US4099537A Cited
US4108193A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-12-16 1984-06-16 1984-12-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-12-16 1988-06-16 1988-12-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-12-16 1992-06-16 1992-12-16 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag