Patent US4234972A successfully refreshed from Google Patents.
US4234972A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Bioglass coated metal substrate
Assignee: FLORIDA UNVERSITY OF
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Filing: 1978-06-21
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Granted: 1980-11-25
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Expires: 1998-06-21
Abstract
Abstract A prosthesis for cement-free bonding to bone comprising a metal substrate coated with a biologically active glass or glass-ceramic of uniform composition and thermal coefficient of expansion and free of flaws resulting from thermo-mechanical stresses, the glass coating being bonded to the metal substrate by ion diffusion of the interface wherein the thermal coefficients of expansion of the metal substrate and the glass or glass-ceramic coating are substantially different.
Inventors
- 👤 Larry L. Hench
- 👤 Paul J. Buscemi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 05:39
CPC Classifications
A; A61; A61L; A61L27/00; A61L27/28; A61L27/30; A61L27/306; A61C; A61C8/00; A61C8/0012; A61F; A61F2/00; A61F2/02; A61F2/30; A61F2/30767; C; C03; C03C; C03C4/00; C03C4/0007; C23; C23D; C23D5/00; C23D5/04; A61C8/0013; A61F2310/00; A61F2310/00389; A61F2310/00592; A61F2310/00928
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
159 words
A prosthesis or surgical implant suitable for cement-free bonding to bone consisting essentially of a metal substrate of sufficient strength for the intended use coated at least on the portions thereof to be bonded to the bone of the recipient with a coating of about 0.2 mm to about 2 mm thickness of a biologically active glass or glass-ceramic of uniform composition and thermal coefficient of expansion and substantially free of flaws resulting from the release of thermo-mechanical stresses, the surface of said substrate at its interface with said glass coating being roughened, to a degree sufficient to substantially increase the surface area of said substrate without permitting substantial mechanical interlocking between said metal surface and said glass coating, and oxidized, and said glass coating being bonded to said surface of said metal substrate by ion diffusion at said interface, wherein the thermal coefficients of expansion of said metal substrate and said glass or glass-ceramic coating are substantially different.
Claim 2
Dependent Claim
159 words
A prosthesis or surgical implant suitable for cement-free bonding to bone consisting essentially of a metal substrate of sufficient strength for the intended use coated at least on the portions thereof to be bonded to the bone of the recipient with a coating of about 0.2 mm to about 2 mm thickness of a biologically active glass or glass-ceramic of uniform composition and thermal coefficient of expansion and substantially free of flaws resulting from the release of thermo-mechanical stresses, the surface of said substrate at its interface with said glass coating being roughened, to a degree sufficient to substantially increase the surface area of said substrate without permitting substantial mechanical interlocking between said metal surface and said glass coating, and oxidized, and said glass coating being bonded to said surface of said metal substrate by ion diffusion at said interface, wherein the thermal coefficients of expansion of said metal substrate and said glass or glass-ceramic coating are substantially different.
Claim 3
Dependent Claim
15 words
A prosthesis or surgical implant of claim 1 wherein said metal is a cobalt-chrome alloy.
Claim 4
Dependent Claim
38 words
A prosthesis or surgical implant of claim 1 wherein said biologically active glass or glass-ceramic contains, by weight: SiO 2 --40-62% Na 2 O--10-32% CaO-10--32% P 2 O 5 --0-12% CaF 2 --0-18% B 2 O 3 --0-20%
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-11-25 | 1984-05-26 | 1984-11-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-11-25 | 1988-05-26 | 1988-11-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-11-25 | 1992-05-26 | 1992-11-25 | $7700.00 | Window Closed / Lapsed |