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US4233390A Expired / Lapsed US ⏱️ 0.0 years remaining

Lithographic printing plate having dual photosensitive layering

Assignee: Kodak Graphics Holding Inc
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Filing: 1979-07-20
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Granted: 1980-11-11
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Expires: 1999-07-20
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Abstract

Abstract A method for preparing aluminum based lithographic printing plates which comprises treating at least one surface of an aluminum base sheet with lithographically suitable, photosensitive, preferably water-soluble, diazo composition and then applying to said surface a lithographically suitable photopolymerizable composition to yield the desired photosensitive lithographic printing plate of improved characteristics.

Inventors

  • 👤 Paul Jargiello

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:03
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/09; G03F7/095; G03F7/0955

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 179 words
A lithographic printing plate capable of development with an aqueous alkali developer which comprises a sheet substrate having coated thereon a light-sensitive, lithograhically suitable, water-soluble diazo composition, said diazo composition having coated thereon a lithographically suitable photopolymerizable composition, which photopolymerizable composition comprises the admixture of, in percent by weight of the photopolymerizable composition: (a) an acrylonitrile butadiene styrene resin in an amount of from 2% to 25%; and (b) one or more resins selected from the group consisting of solid acrylic, polyurethane and polyamide resins in an amount of from 4% to 50%; and (c) cellulose acetate phthalate in an amount of from 4% to 50%; and (d) one or more ethylenically unsaturated monomeric or oligomeric compounds having on the average, more than one double bond, and being capable of forming a high polymer by free radical addition photopolymerization, in an amount of from 20% to 60%; and (e) a photoinitiator capable of generating free radicals in an amount of from 0.5% to 45%; and (f) p-phenol sulfonic acid sodium salt in an amount of from 0.4% to 5%.
Claim 2
Dependent Claim 179 words
A lithographic printing plate capable of development with an aqueous alkali developer which comprises a sheet substrate having coated thereon a light-sensitive, lithograhically suitable, water-soluble diazo composition, said diazo composition having coated thereon a lithographically suitable photopolymerizable composition, which photopolymerizable composition comprises the admixture of, in percent by weight of the photopolymerizable composition: (a) an acrylonitrile butadiene styrene resin in an amount of from 2% to 25%; and (b) one or more resins selected from the group consisting of solid acrylic, polyurethane and polyamide resins in an amount of from 4% to 50%; and (c) cellulose acetate phthalate in an amount of from 4% to 50%; and (d) one or more ethylenically unsaturated monomeric or oligomeric compounds having on the average, more than one double bond, and being capable of forming a high polymer by free radical addition photopolymerization, in an amount of from 20% to 60%; and (e) a photoinitiator capable of generating free radicals in an amount of from 0.5% to 45%; and (f) p-phenol sulfonic acid sodium salt in an amount of from 0.4% to 5%.
Claim 3
Dependent Claim 28 words
A lithographic printing plate of claim 1 wherein the photopolymerizable composition further comprises ingredients, in minor amounts, selected from the group consisting of colorants, polymerization inhibitors, and fillers.
Claim 4
Dependent Claim 19 words
A lithographic printing plate of claim 2 wherein the colorant is a dye, and the filler is fine silica.
Claim 5
Dependent Claim 28 words
The lithographic printing plate of claim 1 wherein the photoinitiator is comprised of an ingredient or ingredients selected from the group consisting of benzophenone, Michler's Ketone and O-chlorohexarylbiimidizole.
Claim 6
Dependent Claim 19 words
The lithographic printing plate of claim 1 wherein the photoinitiator comprises equal parts of benzophenone, Michler's Ketone and O-chlorohexarylbiimidizole.
Claim 7
Dependent Claim 36 words
The lithographic printing plate of claim 1 wherein the diazo coating weight is in the range of from 5 to 70 mg/sq.ft. and the coating weight of the photopolymerizable composition is from 100 to 600 mg./sq.ft.
Claim 8
Dependent Claim 27 words
The lithograhic printing plate of claim 1, 2, 4, or 5, wherein the diazo compound is the condensation product of paradiazo diphenyl amine with formaldehyde or paraformaldehyde.

References Cited (Backward Citations)

US3178283A Cited
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US3395014A Cited
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US3586507A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-11-11 1984-05-12 1984-11-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-11-11 1988-05-12 1988-11-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-11-11 1992-05-12 1992-11-11 $7700.00 Window Closed / Lapsed

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