Additives for contrast control in organic photoconductor compositions and elements

Claim 2

A film-forming composition having the characteristic of producing electrophotographic reproductions of reduced contrast, comprising, in solid solution: a p-type organic photoconductor, an n-type spectral sensitizing dye for the photoconductor, the sensitizing dye having an anion comprising a moiety selected from the group consisting of p-toluenesulfonate, fluorophosphate, tetrafluoroborate and chloro groups, and a hole trapping agent derived from a compound other than a spectral sensitizing dye whose oxidation potential in a neutral solution is at least 0.1 volts less than that of said organic photoconductor, said hole trapping agent being present in an amount sufficient to reduce the relative average contrast to at least 10% lower than the relative average contrast in the absence of the hole trapping agent.

Claim 3

The composition of claim 1 wherein the hole trapping agent is selected from the group consisting of tetraarylboron anions, bromide ions, and iodide ions.

Claim 4

The composition of claim 2 wherein the hole trapping agent is a tetraarylboron anion.

Claim 5

The composition of claim 3 wherein the hole trapping agent is a tetraphenylboron anion.

Claim 6

The composition of claim 2 wherein the hole trapping agent is a bromide ion.

Claim 7

The composition of claim 2 wherein the hole trapping agent is an iodide ion.

Claim 8

A film-forming composition having the characteristic of producing electrophotographic reproductions of reduced contrast, comprising, in solid solution: a p-type organic photoconductor, an n-type spectral sensitizing dye for the photoconductor, the sensitizing dye having an anion comprising a moiety selected from the group consisting of p-toluenesulfonate, fluorophosphate, tetrafluoroborate, and chloro groups, and a polyalkylammonium iodide hole trapping agent whose oxidation potential in a neutral solution is at least 0.1 volts less than that of said organic photoconductor, said hole trapping agent being present in an amount sufficient to reduce the relative average contrast at least 10% lower than the relative average contrast in the absence of the hole trapping agent.

Claim 9

A film-forming composition having the characteristic of producing electrophotographic reproductions of reduced contrast, comprising, in solid solution: a p-type organic photoconductor, an n-type spectral sensitizing dye for the photoconductor, the sensitizing dye having an anion comprising a moiety selected from the group consisting of p-toluenesulfonate, fluorophosphate, tetrafluoroborate, and chloro groups, and a polyalkylammonium iodide hole trapping agent whose oxidation potential in a neutral solution is at least 0.1 volts less than that of said organic photoconductor, said hole trapping agent being present in an amount sufficient to reduce the relative average contrast at least 10% lower than the relative average contrast in the absence of the hole trapping agent.

Claim 10

A photosensitive element capable of producing an electrophotographic reproduction of reduced contrast, comprising an electrically conducting support having coated thereon a photoconductive layer of an electrically insulating, film-forming binder having incorporated therein, in solid solution, a p-type organic photoconductor, an n-type spectral sensitizing dye for the photoconductor, the sensitizing dye having an anion comprising a moiety selected from the group consisting of p-toluenesulfonate, fluorophosphate, tetra-fluoroborate and chloro groups, and a hole trapping agent derived from a compound other than a spectral sensitizing dye whose oxidation potential in a neutral solution is at least 0.1 volts less than that of said organic photoconductor, said hole trapping agent being present in an amount sufficient to reduce the relative average contrast to at least 10% lower than the relative average contrast in the absence of the hole trapping agent.

Claim 11

A photosensitive element capable of producing an electrophotographic reproduction of reduced contrast, comprising an electrically conducting support having coated thereon a photoconductive layer of an electrically insulating, film-forming binder having incorporated therein, in solid solution, a p-type organic photoconductor, an n-type spectral sensitizing dye for the photoconductor, the sensitizing dye having an anion comprising a moiety selected from the group consisting of p-toluenesulfonate, fluorophosphate, tetra-fluoroborate and chloro groups, and a hole trapping agent derived from a compound other than a spectral sensitizing dye whose oxidation potential in a neutral solution is at least 0.1 volts less than that of said organic photoconductor, said hole trapping agent being present in an amount sufficient to reduce the relative average contrast to at least 10% lower than the relative average contrast in the absence of the hole trapping agent.

Claim 12

The photosensitive element of claim 8 wherein the p-type organic photoconductor is a p-type amine photoconductor.

Claim 13

The photosensitive element of claim 8 wherein the p-type organic photoconductor is phenylidibenzylamine.

Claim 14

The photosensitive element of claim 8 wherein the p-type organic photoconductor is triphenylamine.

Claim 15

The photosensitive element of claim 8 wherein the p-type organic photoconductor is 4,4-benzylidene-bis-(N,N-diethyl-m-toluidine).

Claim 16

The photosensitive element of claim 8 wherein the spectral sensitizing dye is selected from the group consisting of: 6-Chloro-1'-methyl-1,2',3'-triphenylimidazo [4,5-b] quinoxaline-3-indolocarbocyanine-p-toluenesulfonate 2,4,6-Triphenylpyrylium tetrafluoborate 2,6-Bis (4-ethylphenyl)-4-(4-n-amyloxyphenyl) thiapyrylium perchlorate 2-[3,5-Dimethyl-1-phenyl-4-pyrazolyl)vinyl]-1,3,3-trimethyl-3H-pyrrolo[2,3-b]pyridinium salt 2,6-Diphenyl-4-dimethylaminophenylthiapyrylium salt.

Claim 17

The photosensitive element of claim 8 wherein the hole trapping agent is selected from the group comprising tetraarylboron anions, bromide ions, and iodide ions.

Claim 18

The photosensitive element of claim 14 wherein the hole trapping agent is a tetraarylboron anion.

Claim 19

The photosensitive element of claim 15 wherein the hole trapping agent is a tetraphenylboron anion.

Claim 20

The photosensitive element of claim 14 wherein the hole trapping agent is a bromide ion.

Claim 21

The photosensitive element of claim 14 wherein the hole trapping agent is an iodide ion.

Claim 22

The photosensitive element of claim 8 wherein the photoconducting layer has a thickness ranging from 1 micrometer to 500 micrometers.

Claim 23

The photosensitive element of claim 8 wherein the photoconducting layer has a thickness ranging from 5 micrometers to 200 micrometers.

Claim 24

A photosensitive element capable of producing electrophotographic reproductions of reduced contrast, comprising an electrically conducting support having coated thereon a photoconductive layer of an electrically insulating, film-forming binder having incorporated therein, in solid solution, a p-type organic photoconductor, an n-type spectral sensitizing dye for the photoconductor, the sensitizing dye having an anion comprising a moiety selected from the group consisting of p-toluenesulphonate, fluorophosphate, tetrafluoroborate and chloro groups, and a polyalkylammonium iodide trapping agent whose oxidation potential in a neutral solution is at least 0.1 volts less than that of said organic photoconductor, said hole trapping agent being present in an amount sufficient to reduce the relative average contrast at least 10% lower than the relative average contrast in the absence of the hole trapping agent.

Claim 25

A photosensitive element capable of producing electrophotographic reproductions of reduced contrast, comprising an electrically conducting support having coated thereon a photoconductive layer of an electrically insulating, film-forming binder having incorporated therein, in solid solution, a p-type organic photoconductor, an n-type spectral sensitizing dye for the photoconductor, the sensitizing dye having an anion comprising a moiety selected from the group consisting of p-toluenesulphonate, fluorophosphate, tetrafluoroborate and chloro groups, and a polyalkylammonium iodide trapping agent whose oxidation potential in a neutral solution is at least 0.1 volts less than that of said organic photoconductor, said hole trapping agent being present in an amount sufficient to reduce the relative average contrast at least 10% lower than the relative average contrast in the absence of the hole trapping agent.

Claim 26

In an electrophotographic process comprising the steps of uniformly charging a photosensitive element in the dark, exposing said element to a pattern of activating radiation, and developing the resultant charge pattern with an electroscopic marking material to form an image pattern, the improvement of obtaining an image of reduced contrast which comprises utilizing as said photosensitive element, an element comprising an electrically conducting support having coated thereon a photoconductive layer of an electrically insulating, film-forming binder having incorporated therein, in solid solution, a p-type organic photoconductor, an n-type spectral sensitizing dye for the photoconductor, the sensitizing dye having an anion comprising a moiety selected from the group consisting of p-toluenesulfonate, fluorophosphate, tetrafluoroborate and chloro groups, and a hole trapping agent derived from a compound other than a spectral sensitizing dye whose oxidation potential in a neutral solution is at least 0.1 volts less than that of said organic photoconductor, said hole trapping agent being present in an amount sufficient to reduce the relative average contrast to at least 10% lower than the relative average contrast in the absence of the hole trapping agent.

Claim 27

In an electrophotographic process comprising the steps of uniformly charging a photosensitive element in the dark, exposing said element to a pattern of activating radiation, and developing the resultant charge pattern with an electroscopic marking material to form an image pattern, the improvement of obtaining an image of reduced contrast which comprises utilizing as said photosensitive element, an element comprising an electrically conducting support having coated thereon a photoconductive layer of an electrically insulating, film-forming binder having incorporated therein, in solid solution, a p-type organic photoconductor, an n-type spectral sensitizing dye for the photoconductor, the sensitizing dye having an anion comprising a moiety selected from the group consisting of p-toluenesulfonate, fluorophosphate, tetrafluoroborate and chloro groups, and a hole trapping agent derived from a compound other than a spectral sensitizing dye whose oxidation potential in a neutral solution is at least 0.1 volts less than that of said organic photoconductor, said hole trapping agent being present in an amount sufficient to reduce the relative average contrast to at least 10% lower than the relative average contrast in the absence of the hole trapping agent.