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Pressure-sensitive adhesives

Assignee: Artience Co Ltd
•
Filing: 1977-02-28
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Granted: 1978-08-29
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Expires: 1997-02-28
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Abstract

Abstract A pressure-sensitive adhesive comprising, by weight, (A) an aqueous dispersion of a copolymer of (1) at least one alkyl acrylate, (2) at least one alpha , beta -unsaturated carboxylic acid or hydroxyl group-containing acrylate or methacrylate or the like and (3) at least one vinylic or vinylidenic copolymerizable monomer, and (B) an aqueous dispersion of an ethylene-vinyl acetate copolymer.

Inventors

  • 👤 Masatoshi Mori
  • 👤 Ryoji Fukata

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:33
CPC Classifications
C; C09; C09J; C09J133/00; C09J133/04; C09J133/06; C09J133/08; C09J7/00; C09J7/30; C09J7/38; C09J7/381; C09J7/385; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L2666/00; C08L2666/02; C08L2666/04; C09J2301/00; C09J2301/30; C09J2301/302; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31928; Y10T428/31935

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 153 words
An aqueous dispersion of a pressure-sensitive adhesive of improved binding power towards polyolefins comprising, by weight, (A) 60 - 95 parts as solid matter of a 30-60% aqueous copolymer dispersion obtained by emulsion polymerization in water of a mixture of the following monomers (1), (2) and (3): (1) 60-99 parts of at least one monomeric acylate having a C 4 - C 12 alkyl group, (2) 1 - 7 parts of at least one monomer selected from the group consisting of α,β-unsaturated carboxylic acids, acrylate and methacrylate containing a hydroxyl group, acrylamide, N-methylolacrylamide and N-butoxymethylacrylamide, each monomer being copolymerizable with the monomer (1), and (3) 0 ∝ 39 parts of at least one monomer selected from the group consisting of vinylic copolymerizable monomers other than the monomers (1) and (2), and vinylidenic copolymerizable monomers and (B) 5 - 40 parts as solid matter of a 40-60% aqueous dispersin of an ethylene-vinyl acetate copolymer.
Claim 2
Dependent Claim 153 words
An aqueous dispersion of a pressure-sensitive adhesive of improved binding power towards polyolefins comprising, by weight, (A) 60 - 95 parts as solid matter of a 30-60% aqueous copolymer dispersion obtained by emulsion polymerization in water of a mixture of the following monomers (1), (2) and (3): (1) 60-99 parts of at least one monomeric acylate having a C 4 - C 12 alkyl group, (2) 1 - 7 parts of at least one monomer selected from the group consisting of α,β-unsaturated carboxylic acids, acrylate and methacrylate containing a hydroxyl group, acrylamide, N-methylolacrylamide and N-butoxymethylacrylamide, each monomer being copolymerizable with the monomer (1), and (3) 0 ∝ 39 parts of at least one monomer selected from the group consisting of vinylic copolymerizable monomers other than the monomers (1) and (2), and vinylidenic copolymerizable monomers and (B) 5 - 40 parts as solid matter of a 40-60% aqueous dispersin of an ethylene-vinyl acetate copolymer.
Claim 3
Dependent Claim 91 words
A pressure-sensitive adhesive according to claim 1, wherein the monomeric alkyl acrylate (a) is a member selected from the group consisting of butyl acrylate, hexyl acrylate, octyl acrylate and 2-ethylhexyl acrylate, the α, β-unsatured carboxylic acids are acrylic, methacrylic, crotonic, itaconic, maleic and fumaric acids; the hydroxyl group-containing acrylates and methacrylates are β-hydroxyethyl acrylate, β-hydroxypropyl acrylate, β-hydroxyethyl methacrylate and β-hydroxypropyl methacrylate; and the monomer (3) is a member selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, vinyl acetate, styrene and acrylonitrile.
Claim 4
Dependent Claim 59 words
The aqueous dispersion of the pressure sensitive adhesive according to claim 1 wherein an emulsifier which is polyoxyethylene alkyl phenol ether sulfate, polyoxyethylene alkyl phenol ether sulfonate, an alkyl benzene sulfonate or an α-olefin sulfonate or a mixture of one of said emulsifiers with polyoxyethylene alkyl phenol ether, polyoxyethylene stearate, polyoxyethylene or polyoxypropylene is added during said emulsion polymerization.
Claim 5
Dependent Claim 22 words
The pressure sensitive adhesive according to claim 1 which additionally contains a thickener to inrease the viscosity to 6,000 to 20,000 centipoises.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-08-28 1982-02-27 1982-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-08-28 1986-02-27 1986-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-08-28 1990-02-27 1990-08-29 $7700.00 Window Closed / Lapsed

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