Polyacrylates containing primary amino groups

Claim 1

A method of producing a polymeric material containing primary amino groups, which comprises copolymerizing (a) a monomer having the general formula: ##STR2## wherein R 1 is selected from the group consisting of H and CH 3 , Ar is a bifunctional aromatic residue, R 2 is an acyl group, and x is 1 to 20, and (b) an amount of a comonomer which is 2 to 30 times greater than the amount of said monomer by weight, said comonomer being selected from the group consisting of a hydroxyalkyl ester of acrylic acid, a hydroxyalkyl ester of methacrylic acid, an amide of acrylic acid, an amide of methacrylic acid, and styrene, the copolymerization being conducted at a temperature of 60° to 90° C; and treating the resulting copolymeric material at a temperature of 75° - 100° C. with a hydrolytic agent selected from the group consisting of a strong mineral acid and a strong mineral base to convert the acylamino groups into primary amino groups.

Claim 2

A method of producing a polymeric material containing primary amino groups, which comprises copolymerizing (a) a monomer having the general formula: ##STR2## wherein R 1 is selected from the group consisting of H and CH 3 , Ar is a bifunctional aromatic residue, R 2 is an acyl group, and x is 1 to 20, and (b) an amount of a comonomer which is 2 to 30 times greater than the amount of said monomer by weight, said comonomer being selected from the group consisting of a hydroxyalkyl ester of acrylic acid, a hydroxyalkyl ester of methacrylic acid, an amide of acrylic acid, an amide of methacrylic acid, and styrene, the copolymerization being conducted at a temperature of 60° to 90° C; and treating the resulting copolymeric material at a temperature of 75° - 100° C. with a hydrolytic agent selected from the group consisting of a strong mineral acid and a strong mineral base to convert the acylamino groups into primary amino groups.

Claim 8

A method of producing a polymeric material containing primary amino groups, which comprises copolymerizing (a) a monomer having the general formula: ##STR3## wherein R 1 is selected from the group consisting of H and CH 3 , Ar is a bifunctional aromatic residue, R 2 is an acyl group, and x is 1 to 20, (b) an amount of a comonomer which is 2 to 30 times greater than the amount of said monomer by weight, said comonomer being selected from the group consisting of a hydroxyalkyl ester of acrylic acid, a hydroxyalkyl ester of methacrylic acid, an amide of acrylic acid, an amide of methacrylic acid, and styrene, and (c) up to 70% by weight, based on the total weight of said monomer and said comonomer, of a crosslinking agent selected from the group consisting of an ester containing at least two acryloyl groups, an ester containing at least two methacryloyl groups, an amide containing at least two acryloyl groups, an amide containing at least two methacryloyl groups, and divinyl benzene, the copolymerization being conducted at a temperature of 60° to 90° C.; and treating the resulting copolymeric material at a temperature of 75° - 100° C. with a hydrolytic agent selected from the group consisting of a strong mineral acid and a strong mineral base to convert the acylamino groups into primary amino groups.

Claim 9

A method of producing a polymeric material containing primary amino groups, which comprises copolymerizing (a) a monomer having the general formula: ##STR3## wherein R 1 is selected from the group consisting of H and CH 3 , Ar is a bifunctional aromatic residue, R 2 is an acyl group, and x is 1 to 20, (b) an amount of a comonomer which is 2 to 30 times greater than the amount of said monomer by weight, said comonomer being selected from the group consisting of a hydroxyalkyl ester of acrylic acid, a hydroxyalkyl ester of methacrylic acid, an amide of acrylic acid, an amide of methacrylic acid, and styrene, and (c) up to 70% by weight, based on the total weight of said monomer and said comonomer, of a crosslinking agent selected from the group consisting of an ester containing at least two acryloyl groups, an ester containing at least two methacryloyl groups, an amide containing at least two acryloyl groups, an amide containing at least two methacryloyl groups, and divinyl benzene, the copolymerization being conducted at a temperature of 60° to 90° C.; and treating the resulting copolymeric material at a temperature of 75° - 100° C. with a hydrolytic agent selected from the group consisting of a strong mineral acid and a strong mineral base to convert the acylamino groups into primary amino groups.

Claim 18

A method of producing a polymeric material containing primary amino groups, which comprises copolymerizing at a temperature of 60° to 90° C. (a) an aminoacrylate selected from the group consisting of 2-(p-acetaminophenoxy)-ethyl methacrylate and 2-(p-acetaminophenoxy)-ethyl acrylate, (b) an amount of a hydroxy-acrylate which is 2 to 30 times greater than the amount of said aminoacrylate by weight, said hydroxy-acrylate being selected from the group consisting of 2-hydroxyethyl methacrylate and 2-hydroxyethyl acrylate, and (c) up to 70% by weight, based on the total weight of said aminoacrylate and said hydroxy-acrylate, of a crosslinking agent selected from the group consisting of ethylene dimethacrylate and ethylene diacrylate; and treating the resulting copolymeric material at a temperature of 75° - 100° C. with a hydrolytic agent selected from the group consisting of a strong mineral acid and a strong mineral base to convert the indicated acetamino groups into primary amino groups.

Claim 19

A method of producing a polymeric material containing primary amino groups, which comprises copolymerizing at a temperature of 60° to 90° C. (a) an aminoacrylate selected from the group consisting of 2-(p-acetaminophenoxy)-ethyl methacrylate and 2-(p-acetaminophenoxy)-ethyl acrylate, (b) an amount of a hydroxy-acrylate which is 2 to 30 times greater than the amount of said aminoacrylate by weight, said hydroxy-acrylate being selected from the group consisting of 2-hydroxyethyl methacrylate and 2-hydroxyethyl acrylate, and (c) up to 70% by weight, based on the total weight of said aminoacrylate and said hydroxy-acrylate, of a crosslinking agent selected from the group consisting of ethylene dimethacrylate and ethylene diacrylate; and treating the resulting copolymeric material at a temperature of 75° - 100° C. with a hydrolytic agent selected from the group consisting of a strong mineral acid and a strong mineral base to convert the indicated acetamino groups into primary amino groups.

Claim 20

A method of producing a polymeric material containing primary amino groups, which comprises copolymerizing at a temperature of 60° to 90° C. 2-(p-acetaminophenoxy)-ethyl methacrylate, an amount of 2-hydroxyethyl methacrylate which is 2 to 30 times greater than the amount of said aminomethacrylate by weight, and up to 70% by weight based on the total weight of said aminomethacrylate and said hydroxy-methacrylate, of ethylene dimethacrylate; and treating the resulting copolymeric material at a temperature of 75° - 100° C. with hydrochloric acid to convert the acetamino groups into primary amino groups.

Claim 21

A method of producing a polymeric material containing primary amino groups, which comprises copolymerizing at a temperature of 60° to 90° C. 2-(p-acetaminophenoxy)-ethyl methacrylate, an amount of 2-hydroxyethyl methacrylate which is 2 to 30 times greater than the amount of said aminomethacrylate by weight, and up to 70% by weight based on the total weight of said aminomethacrylate and said hydroxy-methacrylate, of ethylene dimethacrylate; and treating the resulting copolymeric material at a temperature of 75° - 100° C. with hydrochloric acid to convert the acetamino groups into primary amino groups.