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Thermoplastic resin composition

Assignee: Sumitomo Chemical Co Ltd
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Filing: 1975-01-30
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Granted: 1978-02-14
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Expires: 1995-01-30
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Abstract

Abstract A novel thermoplastic resin composition consisting essentially of polystyrene and a styrene-butadiene block copolymer. This resin composition is transparent, is excellent in mechanical properties, particularly in elongation, impact strength, and stiffness, is not liable to become cloudy on being bent, and is favorable in hinging endurance as well as in thermal resistance.

Inventors

  • 👤 Minoru Tabana
  • 👤 Tatsuyuki Mitsuno
  • 👤 Hiroshi Maki
  • 👤 Shizuo Narisawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 16:45
CPC Classifications
C; C08; C08L; C08L25/00; C08L25/02; C08L25/04; C08L25/06; B; B29; B29C; B29C51/00; B29C51/002; C08L53/00; C08L53/02

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 260 words
A resin composition consisting essentially of polystyrene having a molecular weight of 150,000 to 500,000 and a styrene-butadiene block copolymer represented by the formula A 1 --B 1 --C--B 2 --A 2 , wherein A 1 and A 2 represent non-elastomeric blocks composed of polymeric styrene chains, B 1 and B 2 represent elastomeric blocks composed of random-copolymer chains containing styrene and butadiene units uniformly distributed therein, C represents an elastomeric block composed of a polymeric butadiene chain or a styrene-butadiene copolymer chain, the total amount of A 1 and A 2 is 40 to 80% by weight, the total amount of B 1 and B 2 is 10 to 60% by weight, the amount of C is 0 to 25% by weight provided that the amount of C is smaller than the total amount of B 1 and B 2 , the weight ratio of A 1 to A 2 is 2:8 to 8:2, the weight ratio of B 1 to B 2 is 0:10 to 10:0, the weight ratio of styrene to butadiene in B 1 and B 2 is 10:90 to 75:25, and the weight ratio of styrene to butadiene in C is 0:100 to 10:90, the total styrene content to said styrene-butadiene block copolymer being 65 to 90% by weight, the total butadiene content of said block copolymer being 10 to 35% by weight, and said block copolymer having an intrinsic viscosity of 0.35 to 1.8 dl/g, as measure in toluene at 30° C, said resin composition obtained by mixing said polystyrene and said block copolymer.
Claim 2
Dependent Claim 260 words
A resin composition consisting essentially of polystyrene having a molecular weight of 150,000 to 500,000 and a styrene-butadiene block copolymer represented by the formula A 1 --B 1 --C--B 2 --A 2 , wherein A 1 and A 2 represent non-elastomeric blocks composed of polymeric styrene chains, B 1 and B 2 represent elastomeric blocks composed of random-copolymer chains containing styrene and butadiene units uniformly distributed therein, C represents an elastomeric block composed of a polymeric butadiene chain or a styrene-butadiene copolymer chain, the total amount of A 1 and A 2 is 40 to 80% by weight, the total amount of B 1 and B 2 is 10 to 60% by weight, the amount of C is 0 to 25% by weight provided that the amount of C is smaller than the total amount of B 1 and B 2 , the weight ratio of A 1 to A 2 is 2:8 to 8:2, the weight ratio of B 1 to B 2 is 0:10 to 10:0, the weight ratio of styrene to butadiene in B 1 and B 2 is 10:90 to 75:25, and the weight ratio of styrene to butadiene in C is 0:100 to 10:90, the total styrene content to said styrene-butadiene block copolymer being 65 to 90% by weight, the total butadiene content of said block copolymer being 10 to 35% by weight, and said block copolymer having an intrinsic viscosity of 0.35 to 1.8 dl/g, as measure in toluene at 30° C, said resin composition obtained by mixing said polystyrene and said block copolymer.
Claim 3
Dependent Claim 17 words
A resin composition according to claim 1, wherein molecular weight of the polystyrene is 200,000 to 400,000.
Claim 4
Dependent Claim 27 words
A resin composition according to claim 1, wherein weight ratio of the styrene-butadiene block copolymer to the polystyrene is from 2 : 98 to 20 : 80.
Claim 5
Dependent Claim 27 words
A resin composition according to claim 1, wherein weight ratio of the styrene-butadiene block copolymer to the polystyrene is from 20 : 80 to 70 : 30.
Claim 6
Dependent Claim 28 words
A resin composition according to claim 1, wherein the weight ratio of the styrene-butadiene block copolymer to the polystyrene is from 70 : 30 to 98 : 2.
Claim 7
Dependent Claim 20 words
A resin composition according to claim 1, wherein said composition is incorporated with a stabilizer, a colorant, and a lubricant.

References Cited (Backward Citations)

GB1145923A Cited
US3862251A Cited
US3872068A Cited
US3792127A Cited
US3873645A Cited
US3906058A Cited
US3907930A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-13 1981-08-15 1982-02-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-13 1985-08-15 1986-02-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-13 1989-08-15 1990-02-14 $7700.00 Window Closed / Lapsed

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