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US4066622A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyamide acids and polyesterimides from 1,3-adamantylene-bis-trimellitate dianhydrides

Assignee: BP Corp North America Inc
•
Filing: 1976-02-12
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Granted: 1978-01-03
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Expires: 1996-02-12
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Abstract

Abstract Novel dianhydrides derived from trimellitic anhydride and adamantane diacetates are polymerized with a diamine to produce the corresponding polyamide, which is subsequently converted to the polyesterimide by heat treatment at temperatures above 500° F.

Inventors

  • 👤 Allen Feinstein
  • 👤 Ellis K. Fields

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 11:35
CPC Classifications
C; C07; C07D; C07D307/00; C07D307/77; C07D307/87; C07D307/89; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/16

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 80 words
As a composition of matter, a polyamide acid formed by reacting about equimolar amounts of a dianhydride with a diamine at a temperature below 500° F., said dianhydride having the general formula ##STR4## wherein R 1 and R 2 are individually selected from the group consisting of hydrogen, an alkyl radical, and an aryl radical, and said diamine having the general formula H.sub.2 N --R.sub.3 --NH.sub.2 wherein R 3 is selected from the group consisting of alkylene and arylene groups.
Claim 2
Dependent Claim 80 words
As a composition of matter, a polyamide acid formed by reacting about equimolar amounts of a dianhydride with a diamine at a temperature below 500° F., said dianhydride having the general formula ##STR4## wherein R 1 and R 2 are individually selected from the group consisting of hydrogen, an alkyl radical, and an aryl radical, and said diamine having the general formula H.sub.2 N --R.sub.3 --NH.sub.2 wherein R 3 is selected from the group consisting of alkylene and arylene groups.
Claim 3
Dependent Claim 11 words
The polyamide acid of claim 1 wherein R 1 is hydrogen.
Claim 4
Dependent Claim 11 words
The polyamide acid of claim 2 wherein R 2 is hydrogen.
Claim 5
Dependent Claim 26 words
As a composition of matter, the polyamide acid produced by reacting about equimolar amount of 1,3-adamantylene-bistrimellitate dianhydride with 4,4'-diaminodiphenyl ether at a temperature below 500° F.
Claim 6
Dependent Claim 26 words
As a composition of matter, the polyamide acid produced by reacting about equimolar amount of 1,3-adamantylene-bistrimellitate dianhydride with 4,4'-diaminodiphenyl ether at a temperature below 500° F.
Claim 7
Dependent Claim 87 words
As a composition of matter, a polyestermide formed by reacting about equimolar amounts of a dianhydride with a diamine and heating the reaction product to a temperature of from 500° F. to 700° F., said dianhydride having the general formula ##STR5## wherein R 1 and R 2 are individually selected from the group consisting of hydrogen, an alkyl radical, and an aryl radical, and said diamine having the general formula H.sub.2 N--R.sub.3 --NH.sub.2 wherein R 3 is selected from the group consisting of alkalene and arylene groups.
Claim 8
Dependent Claim 87 words
As a composition of matter, a polyestermide formed by reacting about equimolar amounts of a dianhydride with a diamine and heating the reaction product to a temperature of from 500° F. to 700° F., said dianhydride having the general formula ##STR5## wherein R 1 and R 2 are individually selected from the group consisting of hydrogen, an alkyl radical, and an aryl radical, and said diamine having the general formula H.sub.2 N--R.sub.3 --NH.sub.2 wherein R 3 is selected from the group consisting of alkalene and arylene groups.
Claim 9
Dependent Claim 10 words
The polyesterimide of claim 5 wherein R 1 is hydrogen.
Claim 10
Dependent Claim 10 words
The polyesterimide of claim 6 wherein R 2 is hydrogen.
Claim 11
Dependent Claim 35 words
As a composition of matter, a polyesterimide formed by reacting about equimolar amounts of 1,3-adamantylene-bistrimellitate dianhydride with 4,4'-diaminodiphenyl ether and subsequently heating the reaction product to a temperature of from 500° F. to 700° F.
Claim 12
Dependent Claim 35 words
As a composition of matter, a polyesterimide formed by reacting about equimolar amounts of 1,3-adamantylene-bistrimellitate dianhydride with 4,4'-diaminodiphenyl ether and subsequently heating the reaction product to a temperature of from 500° F. to 700° F.

References Cited (Backward Citations)

US3814735A Cited
US3847872A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-01-02 1981-07-04 1982-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-01-02 1985-07-04 1986-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-01-02 1989-07-04 1990-01-03 $7700.00 Window Closed / Lapsed

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