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US4058401A Expired / Lapsed US ⏱️ 0.0 years remaining

Photocurable compositions containing group via aromatic onium salts

Assignee: General Electric Co
•
Filing: 1975-12-09
•
Granted: 1977-11-15
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Expires: 1995-12-09
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Abstract

Abstract Cationic polymerization of epoxy resin materials, such as epoxy monomers or prepolymers, can be achieved by use of certain radiation sensitive aromatic onium salts of Group VIa elements. Curable compositions are provided which can be used as sealants, coating compounds, encapsulants, etc.

Inventors

  • 👤 James V. Crivello

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 11:59
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029; C; C08; C08G; C08G59/00; C08G59/18; C08G59/68; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 232 words
Photocurable compositions consisting essentially of A. an epoxy resin polymerizable to a higher molecular weight state, B. from 0.1 to 15% by weight of a photodecomposable aromatic onium salt of a Group VIa element capable of effecting the cure of epoxy resin when exposed to radiant energy wherein said aromatic onium salt has the formula [(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sub.d .sup.+ [MQ.sub.e ].sup.-(e-f) where R is a monovalent aromatic organic radical, R 1 is a monovalent organic aliphatic radical selected from alkyl, cycloalkyl and substituted alkyl, R 2 is a polyvalent organic radical forming a heterocyclic or fused ring structure selected from aliphatic radicals and aromatic radicals, X is a Group VIa element selected from sulfur, selenium and tellurium, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 or 1, where the sum of a + b + c is a value equal to 3 or the valence of X, d = e - f f = valence of M and is an integer equal to from 2 to 7 inclusive e is >f and is an integer having a value up to 8 and C. from 0 to 100 parts by weight of filler, per 100 parts of epoxy resin.
Claim 2
Dependent Claim 232 words
Photocurable compositions consisting essentially of A. an epoxy resin polymerizable to a higher molecular weight state, B. from 0.1 to 15% by weight of a photodecomposable aromatic onium salt of a Group VIa element capable of effecting the cure of epoxy resin when exposed to radiant energy wherein said aromatic onium salt has the formula [(R).sub.a (R.sup.1).sub.b (R.sup.2).sub.c X].sub.d .sup.+ [MQ.sub.e ].sup.-(e-f) where R is a monovalent aromatic organic radical, R 1 is a monovalent organic aliphatic radical selected from alkyl, cycloalkyl and substituted alkyl, R 2 is a polyvalent organic radical forming a heterocyclic or fused ring structure selected from aliphatic radicals and aromatic radicals, X is a Group VIa element selected from sulfur, selenium and tellurium, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 to 3 inclusive, b is a whole number equal to 0 to 2 inclusive, c is a whole number equal to 0 or 1, where the sum of a + b + c is a value equal to 3 or the valence of X, d = e - f f = valence of M and is an integer equal to from 2 to 7 inclusive e is >f and is an integer having a value up to 8 and C. from 0 to 100 parts by weight of filler, per 100 parts of epoxy resin.
Claim 3
Dependent Claim 16 words
A photocurable composition in accordance with claim 1, where the onium salt is a sulfonium salt.
Claim 4
Dependent Claim 16 words
A photocurable composition in accordance with claim 1, where the onium salt is a selenium salt.
Claim 5
Dependent Claim 16 words
A photocurable composition in accordance with claim 1, where the onium salt is a tellurium salt.
Claim 6
Dependent Claim 18 words
A photocurable composition in accordance with claim 2, where the sulfonium salt is a dialkyl phenacyl sulfonium salt.
Claim 7
Dependent Claim 13 words
A photocurable composition in accordance with claim 1, having a sulfonium tetrafluoroborate salt.
Claim 8
Dependent Claim 18 words
A photocurable composition in accordance with claim 1, where the Group VIa onium salt is prepared in situ.
Claim 9
Dependent Claim 15 words
A composition in accordance with claim 1, where a mixture of onium salts are employed.
Claim 10
Dependent Claim 16 words
A composition in accordance with claim 1 in the form of a fluid at room temperature.
Claim 11
Dependent Claim 15 words
A photocurable composition in accordance with claim 1, in the form of a free-flowing powder.
Claim 12
Dependent Claim 17 words
A photocurable composition in accordance with claim 1, comprising a reaction product of 4,4'-isopropylidene diphenol and epichlorohydrin.
Claim 13
Dependent Claim 13 words
An article of manufacture comprising a substrate with a composition of claim 1.
Claim 14
Dependent Claim 16 words
A photocurable composition in accordance with claim 1, where the aromatic onium salt is triphenylsulfonium hexafluoroarsenate.
Claim 15
Dependent Claim 16 words
A photocurable composition in accordance with claim 1, where the aromatic onium salt is triphenylsulfonium hexafluoroantimonate.
Claim 16
Dependent Claim 16 words
A photocurable composition in accordance with claim 1, where the aromatic onium salt is triphenylsulfonium tetrafluoroborate.

References Cited (Backward Citations)

US3373221A Cited
US3412046A Cited
US3567453A Cited
US3826650A Cited
US3816280A Cited
US3729313A Cited
US3816281A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-11-14 1981-05-16 1981-11-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-11-14 1985-05-16 1985-11-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-11-14 1989-05-16 1989-11-15 $7700.00 Window Closed / Lapsed

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