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Patent US4052323A successfully refreshed from Google Patents.
US4052323A
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US
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High-temperature lubricant for the hot-working of metals
Assignee: Lonza AG
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Filing: 1974-11-13
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Granted: 1977-10-04
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Expires: 1994-11-13
Abstract
Abstract The high-temperature lubricant for the hot-working of metals which comprises (a) 10 to 90 percent by weight of graphite, (b) 2 to 45 percent by weight of an alkylene homopolymer or copolymer, and (c) 0.5 to 8 percent by weight of a dispersing agent. The lubricant is solid at room temperature. The high-temperature lubricant is applied in the form of an aqueous solution which includes 5 to 80 percent by weight of the solid high-temperature lubricant. The process of production and use of the high-temperature lubricant. The high-temperature lubricant for the hot-working of metals which comprises (a) 35 to 90 percent by weight of graphite, (b) 2 to 60 percent by weight of an alkylene homopolymer or copolymer, (c) 0.2 to 8 percent by weight of an auxiliary suspension agent, and (d) 2 to 40 percent by weight of a film stabilizer. The lubricant is applied in the form of an aqueous solution which includes 5 to 80 percent by weight of solid lubricant. The lubricant is used at temperatures of around 900° C. or higher.
Inventors
- 👤 Kurt Feneberger
- 👤 Rolf Gely
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 15:42
CPC Classifications
C; C10; C10M; C10M169/00; C10M169/04; C10M169/044; C10M103/00; C10M103/02; C10M107/00; C10M107/20; C10M107/22; C10M107/28; C10M125/00; C10M125/24; C10M125/26; C10M143/00; C10M143/06; C10M143/10; C10M145/00; C10M145/02; C10M145/10; C10M145/40; C10M2201/00; C10M2201/02; C10M2201/04; C10M2201/041; C10M2201/0413; C10M2201/042; C10M2201/0423; C10M2201/085; C10M2201/087; C10M2201/10; C10M2201/102; C10M2201/105; C10M2205/00; C10M2205/02; C10M2205/022; C10M2205/026; C10M2205/04; C10M2205/06; C10M2205/14; C10M2209/00; C10M2209/02; C10M2209/04; C10M2209/06; C10M2209/062; C10M2209/08; C10M2209/084; C10M2209/0845; C10M2209/086; C10M2209/0863; C10M2209/12; C10M2217/00; C10M2217/04; C10M2217/044; C10M2217/045; C10N; C10N2040/00; C10N2040/20; C10N2040/24; C10N2040/241; C10N2040/242; C10N2040/243; C10N2040/244; C10N2040/245; C10N2040/246; C10N2040/247
Claims Analysis
Total Claims: 33
Claim 1
Independent Claim
114 words
The high-temperature lubricant for the hot-working of metals which comprises (a) 10 to 90 percent by weight of graphite, (b) 2 to 45 percent by weight of an homopolymer or copolymer selected from the group consisting of polyethylene, poly(methyl methacrylate), polystyrene, poly(vinyl acetate), poly(vinyl laurate), poly(vinyl propionate), a copolymer of methyl methacrylate and styrene, a copolymer of methyl methacrylate and alpha-methyl-styrene, polyisobutylene, poly(dibutyl maleinate), poly(diallylphthalate), polypropylene, poly(methyl acrylate), a copolymer of vinyl acetate and ethylene, polyisobutylene and mixtures thereof, and (c) 0.5 to 8 percent by weight of a dispersing agent which is selected from the group consisting of a polysaccharide, an alkyl cellulose and an alginate, said lubricant being solid at room temperature.
Claim 2
Dependent Claim
114 words
The high-temperature lubricant for the hot-working of metals which comprises (a) 10 to 90 percent by weight of graphite, (b) 2 to 45 percent by weight of an homopolymer or copolymer selected from the group consisting of polyethylene, poly(methyl methacrylate), polystyrene, poly(vinyl acetate), poly(vinyl laurate), poly(vinyl propionate), a copolymer of methyl methacrylate and styrene, a copolymer of methyl methacrylate and alpha-methyl-styrene, polyisobutylene, poly(dibutyl maleinate), poly(diallylphthalate), polypropylene, poly(methyl acrylate), a copolymer of vinyl acetate and ethylene, polyisobutylene and mixtures thereof, and (c) 0.5 to 8 percent by weight of a dispersing agent which is selected from the group consisting of a polysaccharide, an alkyl cellulose and an alginate, said lubricant being solid at room temperature.
Claim 3
Dependent Claim
13 words
The high-temperature lubricant of claim 1 wherein said graphite is in particle form.
Claim 4
Dependent Claim
26 words
The high-temperature lubricant of claim 2 wherein said graphite has a particle size of up to 300 μm and a purity of at least 96 percent.
Claim 5
Dependent Claim
24 words
The high-temperature lubricant of claim 2 wherein said graphite has a particle size of about 100 μm and a purity of about 99.5 percent.
Claim 6
Dependent Claim
14 words
The high-temperature lubricant of claim 2 wherein component (b) is a vinyl acetate copolymer.
Claim 7
Dependent Claim
22 words
The high-temperature lubricant of claim 2 wherein component (b) is a mixture of a vinyl acetate homopolymer and a dibutyl maleinate homopolymer.
Claim 8
Dependent Claim
17 words
The high-temperature lubricant of claim 2 wherein component (b) is a copolymer of vinyl acetate and ethylene.
Claim 9
Dependent Claim
13 words
The high-temperature lubricant of claim 2 wherein said dispersing agent is a polysaccharide.
Claim 10
Dependent Claim
45 words
The high-temperature lubricant of claim 2 wherein said dispersing agent is selected from the group consisting of starch, cellulose, inulin, glycogen, agar, levan, lithenin, pectin, lignin, araban, methyl cellulose, ethyl cellulose, propyl cellulose, butyl cellulose, sodium alginate, potassium alginate, propylene glycol alginate and ammonium alginate.
Claim 11
Dependent Claim
29 words
The aqueous suspension comprising from 95 to 20 percent by weight of water and from 5 to 80 percent by weight of said solid high-temperature lubricant of claim 1.
Claim 12
Dependent Claim
37 words
The aqueous suspension of claim 10 which conains 20 percent by weight of said graphite, 9.5 percent by weight of vinyl acetate copolymer, 1 percent by weight of a polysaccharide and 69.5 percent by weight of water.
Claim 13
Dependent Claim
77 words
The aqueous suspension of claim 10 wherein up to 0.5 percent by weight of a wetting agent is present, said wetting agent is selected from the group consisting of an alkyl aryl sulfonate, a fatty acid amine, a fatty acid soap, a substituted amide of alkyl phosphate, a sulfonated ester of dicarboxylic acid, a sulfonated fatty amide, an alkylolamine, a sodium alkyl sulfate, an aliphatic ester amine, a polyether, a sulfonated high phenol and a naphthalene sulfonate.
Claim 14
Dependent Claim
41 words
The process of producing the aqueous suspension of the high-temperature lubricant of claim 10 comprising (a) preparing an aqueous suspension of said homopolymer or copolymer and said dispersing agent, and (b) inserting said graphite into the aqueous suspension of step (a).
Claim 15
Dependent Claim
28 words
The process of lubricating metals during hot-working of said metal which comprises contacting the metal workpiece or tool to be hot-worked with the aqueous suspension of claim 10.
Claim 16
Dependent Claim
25 words
The process of claim 14 wherein said aqueous suspension of said high-temperature lubricant is used for lubricating the mandrel during the production of seamless pipe.
Claim 17
Dependent Claim
154 words
The high-temperature lubricant for the hot-working of metals which comprises (a) 35 to 90 percent by weight of grahite, (b) 2 to 60 percent by weight of an homopolymer or copolymer selected from the group consisting of polyethylene, poly(methyl methacrylate), polystyrene, poly(vinyl acetate), poly(vinyl laurate), poly(vinyl propionate), copolymers of methyl methacrylate and styrene, a copolymer of methyl methacrylate and alpha-methyl-styrene, polyisobutylene, poly(dibutyl maleinate), poly(diallyl phthalate), polypropylene, poly(methyl acrylate), a copolymer of vinyl acetate and ethylene polyisobutylene, and mixtures thereof, (c) 0.2 to 8 percent by weight of an auxiliary suspension agent selected from the group consisting of a polysaccharide, an alkyl cellulose, an alginate and combinations thereof, and (d) 2 to 4 percent by weight of a film stabilizer selected from the group consisting of boron oxide, a sodium silicate, a silicic acid, a metal phosphate and a combination of one or more of said film stabilizers, said lubricant being solid at room temperature.
Claim 18
Dependent Claim
154 words
The high-temperature lubricant for the hot-working of metals which comprises (a) 35 to 90 percent by weight of grahite, (b) 2 to 60 percent by weight of an homopolymer or copolymer selected from the group consisting of polyethylene, poly(methyl methacrylate), polystyrene, poly(vinyl acetate), poly(vinyl laurate), poly(vinyl propionate), copolymers of methyl methacrylate and styrene, a copolymer of methyl methacrylate and alpha-methyl-styrene, polyisobutylene, poly(dibutyl maleinate), poly(diallyl phthalate), polypropylene, poly(methyl acrylate), a copolymer of vinyl acetate and ethylene polyisobutylene, and mixtures thereof, (c) 0.2 to 8 percent by weight of an auxiliary suspension agent selected from the group consisting of a polysaccharide, an alkyl cellulose, an alginate and combinations thereof, and (d) 2 to 4 percent by weight of a film stabilizer selected from the group consisting of boron oxide, a sodium silicate, a silicic acid, a metal phosphate and a combination of one or more of said film stabilizers, said lubricant being solid at room temperature.
Claim 19
Dependent Claim
13 words
The high-temperature lubricant of claim 16 wherein said graphite is in particle form.
Claim 20
Dependent Claim
13 words
The high-temperature lubricant of claim 17 wherein said film stabilizer is sodium silicate.
Claim 21
Dependent Claim
14 words
The high-temperature lubricant of claim 17 wherein said film stabilizer is colloidal silicic acid.
Claim 22
Dependent Claim
14 words
The high-temperature lubricant of claim 17 wherein said auxiliary suspension agent is a polysaccharide.
Claim 23
Dependent Claim
13 words
The high-temperature lubricant of claim 17 wherein said homopolymer or copolymer is polyisobutylene.
Claim 24
Dependent Claim
17 words
The high-temperature lubricant of claim 17 wherein component (b) is a copolymer of acrylic acid and styrene.
Claim 25
Dependent Claim
26 words
The high-temperature lubricant of claim 17 wherein said graphite has a particle size of up to 300 μm and a purity of at least 96 percent.
Claim 26
Dependent Claim
23 words
The high-temperature of claim 17 wherein said graphite has a particle size of about 100 μm and a purity of about 99.5 percent.
Claim 27
Dependent Claim
47 words
The high-temperature lubricant of claim 17 wherein said dispersing agent is selected from the group consisting of starch, cellulose, inulin, glycogen, agar, levan, lichenin, pectin, lignin, araban, methyl cellulose, ethyl cellulose, propyl cellulose, butyl cellulose, sodium alginate, potassium alginate, propylene glycol alginate, ammonium alginate and combinations thereof.
Claim 28
Dependent Claim
128 words
The high temperature lubricant of claim 17 wherein said film stabilizer is selected from the group consisting of sodium silicate, sodium disilicate, B 2 O 3 , sodium metasilicate, sodium orthosilicate, disilicic acid, metasilicic acid, lithium metaphosphate, potassium orthophosphate, sodium metaphosphate, potassium subphosphate, sodium pyrophosphate, barium pyrophosphate, barium orthophosphate, calcium pyrophosphate, calcium orthophosphate, calcium metaphosphate, calcium hypophosphate, berylium orthophosphate, magnesium orthophosphate, cobalt orthophosphate, zinc orthophosphate, aluminum orthophosphate, zinc pyrophosphate, cadmium orthophosphate, cadmium pyrophosphate, lead orthophosphate, cerium pyrophosphate, bismuth orthophosphate, chromium pyrophosphate, cerium orthophosphate, iron pyrophosphate, iron orthophosphate, manganese pyrophosphate, manganese orthophosphate, nickel pyrophosphate, thallium orthophosphate, platinum pyrophosphate, silver orthophosphate, silver pyrophosphate, nickel orthophosphate, lead pyrophosphate, chromium orthophosphate, manganese metaphosphate, copper orthophosphate, molybdenum metaphosphate, thorium orthophosphate, silver metaphosphate, tin orthophosphate, thallium pyrophosphate, tin pyrophosphate, tin metaphosphate and combinations thereof.
Claim 29
Dependent Claim
29 words
The aqueous suspension comprising from 95 to 20 percent by weight of water and from 5 to 80 percent by weight of said solid high-temperature lubricant of claim 16.
Claim 30
Dependent Claim
77 words
The aqueous solution of claim 27 wherein up to 0.5 percent by weight of a wetting agent is present, said wetting agent being selected from the group consisting of an alkyl aryl sulfonate, a fatty acid amine, a fatty acid soap, a substituted amide of alkyl phosphate, a sulfonated ester of dicarboxylic acid, a sulfonated fatty amide, an alkylolamine, a sodium alkyl sulfate, an aliphatic ester amine, a polyether, a sulfonated high phenol and a naphthalene sulfonate.
Claim 31
Dependent Claim
43 words
The process of producing the aqueous suspension of the high-temperature lubricant of claim 27 which comprises (a) preparing a dry admixture of said homopolymer or copolymer, said graphite, said film stabilizer and said dispersing agent, and (b) suspensing said dry admixture in water.
Claim 32
Dependent Claim
28 words
The process of lubricating metals during hot-working of said metal which comprises contacting the metal workpiece or tool to be hot-worked with the aqueous suspension of claim 27.
Claim 33
Dependent Claim
20 words
The process of claim 30 wherein said aqueous suspension of said high-temperature lubricant is used for lubricating pass rolling mills.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-10-03 | 1981-04-04 | 1981-10-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-10-03 | 1985-04-04 | 1985-10-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-10-03 | 1989-04-04 | 1989-10-04 | $7700.00 | Window Closed / Lapsed |