US4005024A
Expired / Lapsed
US
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Rinse aid composition containing an organosilane
Assignee: Procter and Gamble Co
•
Filing: 1975-04-22
•
Granted: 1977-01-25
•
Expires: 1995-04-22
Abstract
Abstract A rinse aid composition containing an organosilane and a low molecular weight monofunctional organic acid is capable of imparting soil release benefits to cooking utensils and tableware rinsed therewith. Food soils adhere to such surfaces less strongly, thereby making them easier to clean. The inclusion of the monofunctional organic acid insures that objectionable spotting or filming does not form on the rinsed objects.
Inventors
- 👤 Pedro A. Rodriguez
- 👤 David C. Heckert
- 👤 David M. Watt, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-22 16:22
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D3/162
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
244 words
A rinse aid composition capable of imparting soil release properties to cooking utensils and tableware washed therewith consisting essentially of: a. from 0.1% to 50% of an organosilane having the formula: ##STR21##or is a siloxane oligomer thereof wherein R 1 is an alkyl group containing 1 to 4 carbon atoms, (CH.sub.3).sub.3 Si or Z(OCH.sub.x H.sub.2x).sub.m where x is 2 to 4, m is 1 to 20, and Z is hydrogen, an alkyl group containing 1 to 18 carbons or an acyl group containing 1 to 4 carbon atoms; R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; R 3 is hydrogen or an alkyl group containing 1 to 18 carbon atoms; b is 1 to 3; c is 0 or 1; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x, m and Z are as defined above, or oxygen provided only one R 4 is oxygen and further provided that there is no X - when R 4 is oxygen; R 5 is an alkyl, aryl, or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus; b. from 5% to 98.9% of a water-soluble organic nonionic detergent; and c. from 1% to 40% of a monofunctional organic carboxylic acid containing 1 to 6 carbon atoms.
Claim 2
Dependent Claim
244 words
A rinse aid composition capable of imparting soil release properties to cooking utensils and tableware washed therewith consisting essentially of: a. from 0.1% to 50% of an organosilane having the formula: ##STR21##or is a siloxane oligomer thereof wherein R 1 is an alkyl group containing 1 to 4 carbon atoms, (CH.sub.3).sub.3 Si or Z(OCH.sub.x H.sub.2x).sub.m where x is 2 to 4, m is 1 to 20, and Z is hydrogen, an alkyl group containing 1 to 18 carbons or an acyl group containing 1 to 4 carbon atoms; R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; R 3 is hydrogen or an alkyl group containing 1 to 18 carbon atoms; b is 1 to 3; c is 0 or 1; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x, m and Z are as defined above, or oxygen provided only one R 4 is oxygen and further provided that there is no X - when R 4 is oxygen; R 5 is an alkyl, aryl, or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus; b. from 5% to 98.9% of a water-soluble organic nonionic detergent; and c. from 1% to 40% of a monofunctional organic carboxylic acid containing 1 to 6 carbon atoms.
Claim 3
Dependent Claim
159 words
The composition of claim 1 wherein the organosilane has the formula ##STR22##or is a siloxane oligomer thereof wherein Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, x is 2 to 4, and m is 1 to 20; R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; b is 1 to 3; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x, m and Z are as defined above, or oxygen provided only one R 4 is oxygen and further provided than when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus.
Claim 4
Dependent Claim
182 words
The composition of claim 1 wherein the organosilane has the formula ##STR23##or is a siloxane oligomer thereof wherein Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, x is 2 to 4, and m is 1 to 20; R 2 is an alkyl group containing 1 to 18 carbon atoms; R 1 is an alkyl group containing 1 to 4 carbon atoms, a is 0 or 1; d is 1 or 2 provided a+d does not exceed 2; b is 1 to 3; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x, m and Z are as defined above, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus.
Claim 5
Dependent Claim
166 words
The composition of claim 1 wherein the organosilane has the formula ##STR24##or is a siloxane oligomer thereof wherein Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, x is 2 to 4, and m is 1 to 20; R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; R 3 is an alkyl group containing 1 to 18 carbon atoms; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x, m and Z are as defined above, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus.
Claim 6
Dependent Claim
189 words
The compositions of claim 1 wherein the organosilane has the formula ##STR25##or is a siloxane oligomer thereof wherein Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, x is 2 to 4, and m is 1 to 20; R 2 is an alkyl group containing 1 to 18 carbon atoms; R 1 is an alkyl group containing 1 to 4 carbon atoms; a is 0 or 1; d is 1 or 2 provided a+d does not exceed 2; R 3 is an alkyl group containing 1 to 12 carbon atoms; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x, m and Z are as defined above, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus.
Claim 7
Dependent Claim
151 words
The composition of claim 1 wherein the organosilane has the formula ##STR26##or is a siloxane oligomer thereof wherein R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; b is 1 to 3; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x is 2 to 4, m is 1 to 20, and Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus.
Claim 8
Dependent Claim
158 words
The composition of claim 1 wherein the organosilane has the formula ##STR27##or is a siloxane oligomer thereof wherein R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; R 3 is an alkyl group containing 1 to 18 carbon atoms; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x is 2 to 4, m is 1 to 20, and Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus.
Claim 9
Dependent Claim
160 words
The composition of claim 1 wherein the organosilane has the formula ##STR28## or is a siloxane oligomer thereof wherein Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, x is 2 to 4, and m is 1 to 20; R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; b is 1 to 3; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x, m and Z are as defined above, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus.
Claim 10
Dependent Claim
183 words
The composition of claim 1 wherein the organosilane has the formula ##STR29## or is a siloxane oligomer thereof wherein Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, x is 2 to 4, and m is 1 to 20; R 2 is an alkyl group containing 1 to 18 carbon atoms; R 1 is an alkyl group containing 1 to 4 carbon atoms; a is 0 or 1; d is 1 or 2 provided a+d does not exceed 2; b is 1 to 3; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x, m and Z are as defined above, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus.
Claim 11
Dependent Claim
152 words
The composition of claim 1 wherein the organosilane has the formula ##STR30## or is a siloxane oligomer thereof wherein R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; b is 1 to 3; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x is 2 to 4, m is 1 to 20, and Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is halide; and Y is nitrogen, sulfur or phosphorus.
Claim 12
Dependent Claim
190 words
The composition of claim 1 in which said organosilane has the formula ##STR31##or is a siloxane oligomer thereof wherein R 1 is an alkyl group containing 1 to 4 carbon atoms, (CH.sub.3).sub.3 Si or Z(OC.sub.x H.sub.2x).sub.m where x is 2 to 4, m is 1 to 20, and Z is hydrogen, an alkyl group containing 1 to 18 carbons or an acyl group containing 1 to 4 carbon atoms; R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; R 3 is hydrogen or an alkyl group containing 1 to 18 carbon atoms; b is 1 to 3; c is 0 or 1; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x, m and Z are as defined above, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms; and X is halide.
Claim 13
Dependent Claim
146 words
The composition of claim 1 wherein the organosilane has the formula ##STR32##or is a siloxane oligomer thereof wherein R 1 is an alkyl group containing 1 to 4 carbon atoms; b 1 to 3; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x is 2 to 4, m is 1 to 20, and Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 4 to 22 carbon atoms; X is a halide; and Y is nitrogen, sulfur or phosphorus.
Claim 14
Dependent Claim
164 words
The composition of claim 1 wherein the organosilane has the formula ##STR33##or is a siloxane oligomer thereof wherein R 1 is an alkyl group containing 1 to 4 carbon atoms; R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 1 or 2; b is 1 to 3; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x is 2 to 4, m is 1 to 20, and Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is a halide; and Y is nitrogen, sulfur or phosphorus.
Claim 15
Dependent Claim
171 words
The composition of claim 1 wherein the organosilane has the formula ##STR34##or is a siloxane oligomer thereof wherein R 1 is an alkyl group containing 1 to 4 carbon atoms; R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; R 3 is an alkyl group containing 1 to 18 carbon atoms; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x is 2 to 4, m is 1 to 20, and Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is a halide; and Y is nitrogen, sulfur or phosphorus.
Claim 16
Dependent Claim
164 words
The composition of claim 1 wherein the organosilane has the formula ##STR35##or is a siloxane oligomer thereof wherein R 1 is an alkyl group containing 1 to 4 carbon atoms; R 2 is an alkyl group containing 1 to 18 carbon atoms; a is 0 to 2; b is 1 to 3; R 4 is an alkyl, aryl or arylalkyl group containing 1 to 12 carbon atoms, a carboxy-substituted alkyl group containing 1 to 4 carbon atoms, (C.sub.x H.sub.2x O).sub.m Z where x is 2 to 4, m is 1 to 20, and Z is hydrogen, an alkyl group containing 1 to 18 carbon atoms or an acyl group containing 1 to 4 carbon atoms, or oxygen provided only one R 4 is oxygen and further provided that when R 4 is oxygen there is no X -; R 5 is an alkyl, aryl or arylalkyl group containing 1 to 22 carbon atoms; X is a halide; and Y is nitrogen, sulfur or phosphorus.
Claim 17
Dependent Claim
14 words
The rinse aid composition of claim 1 wherein the organosilane has the formula ##STR36##
Claim 18
Dependent Claim
26 words
The composition of claim 1 wherein the monofunctional organic acid is acetic acid, formic acid, propionic acid, butenoic acid, pentanoic acid, caproic acid or mixture thereof.
Claim 19
Dependent Claim
12 words
The composition of claim 17 wherein the organic acid is acetic acid.
Claim 20
Dependent Claim
14 words
The composition of claim 17 additionally containing up to 30% of a sequestering agent.
Claim 21
Dependent Claim
37 words
The composition of claim 17 consisting essentially of a. from 1% to 10% of the organosilane; b. from 10% to 70% of the water-soluble nonionic detergent; and c. from 5% to 20% of the monofunctional organic acid.
Claim 22
Dependent Claim
18 words
The composition of claim 19 wherein the sequestering agent is present at a level of 5% to 10%.
Claim 23
Dependent Claim
12 words
The composition of claim 21 wherein the sequestering agent is citric acid.
Claim 24
Dependent Claim
12 words
The composition of claim 20 wherein the organic acid is acetic acid.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-01-25 | 1980-07-26 | 1981-01-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-01-25 | 1984-07-26 | 1985-01-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-01-25 | 1988-07-26 | 1989-01-25 | $7700.00 | Window Closed / Lapsed |