Patent US4001016A successfully refreshed from Google Patents.
US4001016A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymers which can be cross-linked by photopolymerization
Assignee: Agfa Gevaert AG
•
Filing: 1974-12-09
•
Granted: 1977-01-04
•
Expires: 1994-12-09
Abstract
Abstract Relief or resist images can be produced by means of a photosensitive material including a photosensitive layer with a polymer as defined hereinafter containing vinyl groups capable of being cross-linked upon exposure to actinic light to yield unsoluble cross-linked products at the exposed areas while the polymer in the unexposed areas remain soluble.
Inventors
- 👤 Hans-Jurgen Rosenkranz
- 👤 Hans Rudolph
- 👤 Erich Wolff
- 👤 Harald VON Rintelen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 20:07
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/038; G03F7/0388; C; C08; C08F; C08F20/00; C08F20/02; C08F20/52; C08F20/54; C08G; C08G63/00; C08G63/91; C08G63/914
Claims Analysis
Total Claims: 3
Claim 1
Independent Claim
193 words
A process for the production of photographic relief images or photoresists comprising the steps of imagewise exposing a supported light-sensitive material with a photocrosslinkable polymer in the layer, washing away the unexposed areas of the photosensitive layer to form a relief image of photocrosslinked polymeric material the improvement wherein the said photocrosslinkable polymer compound is a photopolymer of recurrent units of the general formula ##EQU6## wherein R stands for hydrogen or alkyl having up to 4 carbon atoms and R 1 represents hydrogen or alkyl having up to 4 carbon atoms, R 2 stands for hydrogen or alkyl having up to 8 carbon atoms, and A represents a divalent aliphatic bridging member having 2-4 carbon atoms or a bridging member of the formula --(CH.sub.2 --CH.sub.2 --O).sub.m --CH.sub.2 --CH.sub.2 -- wherein m represents an integer of 1 to 3, n is 2 or more, wherein the photopolymer is either a homopolymer or a copolymer with comonomers selected from the group consisting of vinyl monomers, vinyl esters, vinyl ethers, acrylic and methacrylic acid and their derivatives, maleic acid anhydride, and styrene and the light-sensitive polymer has an average molecular weight of between 10,000 and 100,000.
Claim 2
Dependent Claim
193 words
A process for the production of photographic relief images or photoresists comprising the steps of imagewise exposing a supported light-sensitive material with a photocrosslinkable polymer in the layer, washing away the unexposed areas of the photosensitive layer to form a relief image of photocrosslinked polymeric material the improvement wherein the said photocrosslinkable polymer compound is a photopolymer of recurrent units of the general formula ##EQU6## wherein R stands for hydrogen or alkyl having up to 4 carbon atoms and R 1 represents hydrogen or alkyl having up to 4 carbon atoms, R 2 stands for hydrogen or alkyl having up to 8 carbon atoms, and A represents a divalent aliphatic bridging member having 2-4 carbon atoms or a bridging member of the formula --(CH.sub.2 --CH.sub.2 --O).sub.m --CH.sub.2 --CH.sub.2 -- wherein m represents an integer of 1 to 3, n is 2 or more, wherein the photopolymer is either a homopolymer or a copolymer with comonomers selected from the group consisting of vinyl monomers, vinyl esters, vinyl ethers, acrylic and methacrylic acid and their derivatives, maleic acid anhydride, and styrene and the light-sensitive polymer has an average molecular weight of between 10,000 and 100,000.
Claim 3
Dependent Claim
25 words
The process of claim 1, in which the polymer comprises at least two of the said units of formula per 1000 units of molecular weight.
References Cited (Backward Citations)
US3081168A
Cited
US2972540A
Cited
US3043805A
Cited
US2976294A
Cited
US3533796A
Cited
US3427161A
Cited
US3486891A
Cited
US3620733A
Cited
US3764501A
Cited
US3858510A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-01-04 | 1980-07-05 | 1981-01-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-01-04 | 1984-07-05 | 1985-01-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-01-04 | 1988-07-05 | 1989-01-04 | $7700.00 | Window Closed / Lapsed |