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US4001016A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymers which can be cross-linked by photopolymerization

Assignee: Agfa Gevaert AG
•
Filing: 1974-12-09
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Granted: 1977-01-04
•
Expires: 1994-12-09
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Abstract

Abstract Relief or resist images can be produced by means of a photosensitive material including a photosensitive layer with a polymer as defined hereinafter containing vinyl groups capable of being cross-linked upon exposure to actinic light to yield unsoluble cross-linked products at the exposed areas while the polymer in the unexposed areas remain soluble.

Inventors

  • 👤 Hans-Jurgen Rosenkranz
  • 👤 Hans Rudolph
  • 👤 Erich Wolff
  • 👤 Harald VON Rintelen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:30
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/038; G03F7/0388; C; C08; C08F; C08F20/00; C08F20/02; C08F20/52; C08F20/54; C08G; C08G63/00; C08G63/91; C08G63/914

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 193 words
A process for the production of photographic relief images or photoresists comprising the steps of imagewise exposing a supported light-sensitive material with a photocrosslinkable polymer in the layer, washing away the unexposed areas of the photosensitive layer to form a relief image of photocrosslinked polymeric material the improvement wherein the said photocrosslinkable polymer compound is a photopolymer of recurrent units of the general formula ##EQU6## wherein R stands for hydrogen or alkyl having up to 4 carbon atoms and R 1 represents hydrogen or alkyl having up to 4 carbon atoms, R 2 stands for hydrogen or alkyl having up to 8 carbon atoms, and A represents a divalent aliphatic bridging member having 2-4 carbon atoms or a bridging member of the formula --(CH.sub.2 --CH.sub.2 --O).sub.m --CH.sub.2 --CH.sub.2 -- wherein m represents an integer of 1 to 3, n is 2 or more, wherein the photopolymer is either a homopolymer or a copolymer with comonomers selected from the group consisting of vinyl monomers, vinyl esters, vinyl ethers, acrylic and methacrylic acid and their derivatives, maleic acid anhydride, and styrene and the light-sensitive polymer has an average molecular weight of between 10,000 and 100,000.
Claim 2
Dependent Claim 193 words
A process for the production of photographic relief images or photoresists comprising the steps of imagewise exposing a supported light-sensitive material with a photocrosslinkable polymer in the layer, washing away the unexposed areas of the photosensitive layer to form a relief image of photocrosslinked polymeric material the improvement wherein the said photocrosslinkable polymer compound is a photopolymer of recurrent units of the general formula ##EQU6## wherein R stands for hydrogen or alkyl having up to 4 carbon atoms and R 1 represents hydrogen or alkyl having up to 4 carbon atoms, R 2 stands for hydrogen or alkyl having up to 8 carbon atoms, and A represents a divalent aliphatic bridging member having 2-4 carbon atoms or a bridging member of the formula --(CH.sub.2 --CH.sub.2 --O).sub.m --CH.sub.2 --CH.sub.2 -- wherein m represents an integer of 1 to 3, n is 2 or more, wherein the photopolymer is either a homopolymer or a copolymer with comonomers selected from the group consisting of vinyl monomers, vinyl esters, vinyl ethers, acrylic and methacrylic acid and their derivatives, maleic acid anhydride, and styrene and the light-sensitive polymer has an average molecular weight of between 10,000 and 100,000.
Claim 3
Dependent Claim 25 words
The process of claim 1, in which the polymer comprises at least two of the said units of formula per 1000 units of molecular weight.

References Cited (Backward Citations)

US3081168A Cited
US2972540A Cited
US3043805A Cited
US2976294A Cited
US3533796A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-01-04 1980-07-05 1981-01-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-01-04 1984-07-05 1985-01-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-01-04 1988-07-05 1989-01-04 $7700.00 Window Closed / Lapsed

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