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Unsaturated ester-amides of halogenated alkenes

Assignee: Individual
•
Filing: 1976-01-05
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Granted: 1976-12-28
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Expires: 1996-01-05
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Abstract

Abstract This invention deals with new unsaturated esteramides of α,β -unsaturated polycarboxylic acids derived from halogenated alcohols of the formula ##STR1## wherein R is a divalent hydrocarbon moiety having at least one and no more than 10 carbon atoms, X is a member selected from the class of bromine and chlorine, and R' is a member selected from the class of hydrogen, X and a monovalent hydrocarbon containing at least one and no more than 20 carbon atoms. Typical esteramides are the maleates, fumarates, itaconates and citraconates. These monomers possess fire-retardant properties and are useful for the synthesis of polymers and copolymers.

Inventors

  • 👤 Gaetano F. D'Alelio

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 10:19
CPC Classifications
D; D06; D06M; D06M14/00; C; C08; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/22; C08F20/40; C08L; C08L97/00; C08L97/02; B; B27; B27K; B27K2240/00; B27K2240/30; B27K3/00; B27K3/02; B27K3/15; C08K; C08K3/00; C08K3/16; C08K5/00; C08K5/04; C08K5/05; C08L77/00; C08L77/12; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/3188; Y10T428/31895; Y10T428/31906

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 198 words
A polymerization product of an ester-amide of an α,β-ethylenic unsaturated polycarboxylic acid selected from the class consisting of maleic, fumaric, methyl and dimethyl maleic and fumaric, mono and dichloromaleic and fumaric, dibromo maleic and fumaric, itaconic and aconitic acids, one of the acid groups therein being esterified by a halogenated alcohol having the formula ##STR88## wherein R is a divalent hydrocarbon radical having 1-10 carbon atoms therein, R' is selected from the class of H and monovalent hydrocarbon radicals of 1-20 carbon atoms, and X is bromine or chlorine, the second acid group being converted to an amide group of the formula --CONR" 2 wherein R" is a group selected from the class consisting of hydrogen and hydrocarbon groups of 1-20 carbon atoms and derivatives of said hydrocarbon groups in which derivative there is only one derivative group selected from the class consisting of --OH or --NH 2 , and when the polycarboxylic acid is aconitic acid, the third acid group is similarly amidified or unesterified or esterified with an alcohol selected from the class consisting of methyl, ethyl, propyl, amyl, hexyl, stearyl, benzyl, vinyl, allyl, methallyl, propargyl, butynyl, or crotyl, beta-N,N-dimethylaminoethyl, cyclohexyl, beta-hydroxyethyl, beta-bydroxypropyl, and ##STR89## alcohol.
Claim 2
Dependent Claim 198 words
A polymerization product of an ester-amide of an α,β-ethylenic unsaturated polycarboxylic acid selected from the class consisting of maleic, fumaric, methyl and dimethyl maleic and fumaric, mono and dichloromaleic and fumaric, dibromo maleic and fumaric, itaconic and aconitic acids, one of the acid groups therein being esterified by a halogenated alcohol having the formula ##STR88## wherein R is a divalent hydrocarbon radical having 1-10 carbon atoms therein, R' is selected from the class of H and monovalent hydrocarbon radicals of 1-20 carbon atoms, and X is bromine or chlorine, the second acid group being converted to an amide group of the formula --CONR" 2 wherein R" is a group selected from the class consisting of hydrogen and hydrocarbon groups of 1-20 carbon atoms and derivatives of said hydrocarbon groups in which derivative there is only one derivative group selected from the class consisting of --OH or --NH 2 , and when the polycarboxylic acid is aconitic acid, the third acid group is similarly amidified or unesterified or esterified with an alcohol selected from the class consisting of methyl, ethyl, propyl, amyl, hexyl, stearyl, benzyl, vinyl, allyl, methallyl, propargyl, butynyl, or crotyl, beta-N,N-dimethylaminoethyl, cyclohexyl, beta-hydroxyethyl, beta-bydroxypropyl, and ##STR89## alcohol.
Claim 3
Dependent Claim 12 words
A polymerization product of claim 1 having the repeating unit structure ##STR90##
Claim 4
Dependent Claim 12 words
A polymerization product of claim 1 having the repeating unit structure ##STR91##
Claim 5
Dependent Claim 12 words
A polymerization product of claim 1 having the repeating unit structure ##STR92##
Claim 6
Dependent Claim 12 words
A polymerization product of claim 1 having the repeating unit structure ##STR93##

References Cited (Backward Citations)

US2847455A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-12-28 1980-06-28 1980-12-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-12-28 1984-06-28 1984-12-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-12-28 1988-06-28 1988-12-28 $7700.00 Window Closed / Lapsed

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