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US3940430A Expired / Lapsed US ⏱️ 0.0 years remaining

Silanized antimicrobial compounds

Assignee: JE SIEBEL SONS' COMPANY Inc A CORP OF
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Filing: 1974-08-28
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Granted: 1976-02-24
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Expires: 1994-08-28
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Abstract

Abstract Silanized antimicrobial compounds are disclosed which are the reaction products of chlorinated phenols, bis-phenols, dihydric phenols, hydroxy diphenyl ethers and ortho or para hydroxybenzoic acids and their lower alkyl esters with an amino substituted silane having the general formula NH.sub.2 (CH.sub.2).sub.3 Si(R).sub.3 wherein R is methoxy, ethoxy or propoxy and n is 2, 3, or 4. The silane moiety is joined to the antimicrobial compound through the oxygen of a hydroxyl group of the starting compound.

Inventors

  • 👤 Mortimer Wilkes Brenner
  • 👤 Louis Laufer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-22 20:54
CPC Classifications
C; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 70 words
An antimicrobial silanized compound having the formula ##EQU2## wherein R is a radical taken from the group consisting of a chlorinated phenol, bis-phenol or diphenyl ether, a 6 to 9 carbon atom alkyl or chlorine substituted dihydric phenol, an ortho or para hydroxybenzoic acid or a 1 to 12 carbon atom alkyl ester thereof; R 1 and R 2 are methoxy, ethoxy or propoxy; and n is 2 to 4.
Claim 2
Dependent Claim 70 words
An antimicrobial silanized compound having the formula ##EQU2## wherein R is a radical taken from the group consisting of a chlorinated phenol, bis-phenol or diphenyl ether, a 6 to 9 carbon atom alkyl or chlorine substituted dihydric phenol, an ortho or para hydroxybenzoic acid or a 1 to 12 carbon atom alkyl ester thereof; R 1 and R 2 are methoxy, ethoxy or propoxy; and n is 2 to 4.
Claim 3
Dependent Claim 25 words
An antimicrobial silanized compound having the formula ##SPC16## wherein R 1 and R 2 are methoxy, ethoxy or propoxy, and n is 2 to 4.
Claim 4
Dependent Claim 25 words
An antimicrobial silanized compound having the formula ##SPC16## wherein R 1 and R 2 are methoxy, ethoxy or propoxy, and n is 2 to 4.
Claim 5
Dependent Claim 25 words
An antimicrobial silanized compound having the formula ##SPC17## wherein R 1 and R 2 are methoxy, ethoxy or propoxy and n is 2 to 4.
Claim 6
Dependent Claim 25 words
An antimicrobial silanized compound having the formula ##SPC17## wherein R 1 and R 2 are methoxy, ethoxy or propoxy and n is 2 to 4.
Claim 7
Dependent Claim 66 words
An antimicrobial silanized compound being the reaction product of NH.sub.2 (CH.sub.2).sub.n Si(R).sub.3 wherein R is methoxy, ethoxy or propoxy and n is 2 to 4, combined with a reacting compound taken from the group consisting of chlorinated phenols, bis-phenols and diphenyl ethers; 6 to 9 carbon atom alkyl or chlorine-substituted dihydric phenols; ortho or para hydroxybenzoic acids or 1 to 12 carbon atom alkyl esters thereof.
Claim 8
Dependent Claim 66 words
An antimicrobial silanized compound being the reaction product of NH.sub.2 (CH.sub.2).sub.n Si(R).sub.3 wherein R is methoxy, ethoxy or propoxy and n is 2 to 4, combined with a reacting compound taken from the group consisting of chlorinated phenols, bis-phenols and diphenyl ethers; 6 to 9 carbon atom alkyl or chlorine-substituted dihydric phenols; ortho or para hydroxybenzoic acids or 1 to 12 carbon atom alkyl esters thereof.
Claim 9
Dependent Claim 13 words
The antimicrobial silanized compound of claim 4 wherein said reacting compound is hexachlorophene.
Claim 10
Dependent Claim 13 words
The antimicrobial silanized compound of claim 4 wherein said reacting compound is dichlorophene.
Claim 11
Dependent Claim 14 words
The antimicrobial silanized compound of claim 4 wherein said reacting compound is o-benzyl p-chlorophenol.
Claim 12
Dependent Claim 13 words
The antimicrobial silanized compound of claim 4 wherein said reacting compound is pentachlorophenol.
Claim 13
Dependent Claim 23 words
The antimicrobial silanized compound of claim 4 wherein said reacting compound is taken from the group consisting of heptyl p-hydroxybenzoate and octyl p-hydroxybenzoate.
Claim 14
Dependent Claim 14 words
The antimicrobial silanized compound of claim 4 wherein said reacting compound is salicylic acid.
Claim 15
Dependent Claim 17 words
The antimicrobial silanized compound of claim 4 wherein said reacting compound is 2, 4, 4'-trichloro-2' hydroxyphenyl ether.
Claim 16
Dependent Claim 14 words
The antimicrobial silanized compound of claim 4 wherein said reacting compound is hexyl resorcinol.
Claim 17
Dependent Claim 25 words
An antimicrobial compound having the formula ##SPC18## wherein R 1 and R 2 are methoxy, ethoxy or propoxy and n is 2, 3, or 4.
Claim 18
Dependent Claim 25 words
An antimicrobial compound having the formula ##SPC18## wherein R 1 and R 2 are methoxy, ethoxy or propoxy and n is 2, 3, or 4.
Claim 19
Dependent Claim 57 words
An antimicrobial compound which is the reaction product of γ amino propyl triethoxy silane and a reactant compound taken from the group consisting of chlorinated phenols, bis-phenols and hydroxy diphenyl ethers; 6 to 9 carbon atom alkyl or chlorine substituted dihydric phenols; ortho or para hydroxybenzoic acids or the 1 to 12 carbon atom alkyl esters thereof.
Claim 20
Dependent Claim 57 words
An antimicrobial compound which is the reaction product of γ amino propyl triethoxy silane and a reactant compound taken from the group consisting of chlorinated phenols, bis-phenols and hydroxy diphenyl ethers; 6 to 9 carbon atom alkyl or chlorine substituted dihydric phenols; ortho or para hydroxybenzoic acids or the 1 to 12 carbon atom alkyl esters thereof.
Claim 21
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC19##
Claim 22
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC20##
Claim 23
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC21##
Claim 24
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC22##
Claim 25
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC23##
Claim 26
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC24##
Claim 27
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC25##
Claim 28
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC26##
Claim 29
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC27##
Claim 30
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC28##
Claim 31
Dependent Claim 11 words
The antimicrobial compound of claim 14 wherein the formula is ##SPC29##
Claim 32
Dependent Claim 91 words
An antimicrobial compound which is the product of X--NH(CH 2 ) n Si(R) 3 wherein X is hydrogen or an amino lower alkyl having from 1 to 4 carbon atoms, R is methoxy, ethoxy or propoxy and n is 2, 3, or 4; reacted with an antimicrobial starting compound taken from the group consisting of a chlorinated phenol, bis-phenol or hydroxy diphenyl ether, a 6 to 9 carbon atom alkyl or chlorine substituted dihydric phenol, an ortho or para hydroxybenzoic acid or a 1 to 12 carbon atom alkyl ester thereof.
Claim 33
Dependent Claim 91 words
An antimicrobial compound which is the product of X--NH(CH 2 ) n Si(R) 3 wherein X is hydrogen or an amino lower alkyl having from 1 to 4 carbon atoms, R is methoxy, ethoxy or propoxy and n is 2, 3, or 4; reacted with an antimicrobial starting compound taken from the group consisting of a chlorinated phenol, bis-phenol or hydroxy diphenyl ether, a 6 to 9 carbon atom alkyl or chlorine substituted dihydric phenol, an ortho or para hydroxybenzoic acid or a 1 to 12 carbon atom alkyl ester thereof.

References Cited (Backward Citations)

US3423445A Cited
US3546267A Cited
US3489783A Cited
US3636026A Cited
US3803194A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-02-23 1979-08-25 1980-02-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-02-23 1983-08-25 1984-02-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-02-23 1987-08-25 1988-02-24 $7700.00 Window Closed / Lapsed

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