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US3934587A Expired / Lapsed US ⏱️ 0.0 years remaining

Disposable articles having a water-permeable and water-repellent surface

Assignee: Individual
•
Filing: 1974-06-17
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Granted: 1976-01-27
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Expires: 1994-06-17
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Abstract

Abstract A novel material is disclosed and a process and apparatus for making the same, which process comprises reacting one side of a solid sheet or film of a polymeric compound containing reactable hydroxyl or amine groups with a vapor phase mixture of acid chloride and aldehyde. The resulting product is water-repellent along the treated side and water-permeable along the opposite, untreated side. Also disclosed are novel disposable articles such as sanitary clothing and containers for liquids fashioned from the material made by means of the process and apparatus of the present invention.

Inventors

  • 👤 Roy Gerald Gordon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 11:54
CPC Classifications
A; A61; A61L; A61L15/00; A61L15/16; A61L15/42; A61L15/62; A61F; A61F13/00; A61F13/15; A61F13/15203; A61F13/15211; A61L15/20; A61L15/22; A61L15/24; A61F2013/15008; A61F2013/15048; A61F13/15577; A61F2013/15821; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/25; Y10T428/254; Y10T428/31504; Y10T428/31942; Y10T428/31949; Y10T428/31953; Y10T428/31957; Y10T428/31964

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 137 words
An article of manufacture comprising a thin sheet, one side of said sheet being water-permeable and the other side being water-repellent, wherein said water-permeable side comprises a polymeric compound having a molecular weight in excess of about 1000 and having free hydrophilic groups selected from hydroxyl and amine groups and said water-repellent side comprises the reaction product of said polymeric compound with a vapor phase mixture comprising acid chloride having the general formula ##EQU4## and aldehyde having the general formula ##EQU5## wherein R 1 and R 2 are independently selected from straight or branched-chain aliphatic hydrocarbon radicals having from 1 to about 20 carbon atoms and cyclic hydrocarbon radicals having from 6 to about 20 carbon atoms, further wherein the molar proportion of acid chloride to aldehyde in the vapor phase mixture is greater than about 1:10.
Claim 2
Dependent Claim 137 words
An article of manufacture comprising a thin sheet, one side of said sheet being water-permeable and the other side being water-repellent, wherein said water-permeable side comprises a polymeric compound having a molecular weight in excess of about 1000 and having free hydrophilic groups selected from hydroxyl and amine groups and said water-repellent side comprises the reaction product of said polymeric compound with a vapor phase mixture comprising acid chloride having the general formula ##EQU4## and aldehyde having the general formula ##EQU5## wherein R 1 and R 2 are independently selected from straight or branched-chain aliphatic hydrocarbon radicals having from 1 to about 20 carbon atoms and cyclic hydrocarbon radicals having from 6 to about 20 carbon atoms, further wherein the molar proportion of acid chloride to aldehyde in the vapor phase mixture is greater than about 1:10.
Claim 3
Dependent Claim 58 words
An article of manufacture according to claim 1 wherein said reaction is carried out at atmospheric pressure and at a temperature which is both high enough to create a vapor pressure of acid chloride and aldehyde in the vapor phase of about one-half atmosphere and to heat the polymeric compound to the temperature required for reaction to occur.
Claim 4
Dependent Claim 25 words
An article of manufacture according to claim 1 wherein said solid phase polymeric compound is polyvinyl alcohol having a molecular weight greater than about 1000.
Claim 5
Dependent Claim 24 words
An article of manufacture according to claim 1 wherein said vapor phase mixture comprises about 30 mol-% octanoyl chloride and about 70 mol-% octanal.
Claim 6
Dependent Claim 23 words
An article of manufacture according to claim 1 wherein said vapor phase mixture comprises about 85 mol-% octanoyl chloride and 15 mol-% dodecanal.
Claim 7
Dependent Claim 29 words
An article of manufacture according to claim 1 wherein said polymeric compound is exposed to said vapor phase mixture for a period of about 10 seconds to 3 minutes.
Claim 8
Dependent Claim 101 words
A disposable paper container for containing aqueous liquids comprising cellulosic paper which has been exposed along the side normally coming into contact with aqueous liquids to a vapor phase mixture comprising acid chloride having the general formula ##EQU6## and aldehyde having the general formula ##EQU7## wherein R 1 and R 2 are independently selected from straight or branched-chain aliphatic hydrocarbon radicals having from 1 to about 20 carbon atoms and cyclic hydrocarbon radicals having from 6 to about 20 carbon atoms, further wherein the molar proportion of acid chloride to aldehyde in the vapor phase mixture is greater than about 1:10.
Claim 9
Dependent Claim 101 words
A disposable paper container for containing aqueous liquids comprising cellulosic paper which has been exposed along the side normally coming into contact with aqueous liquids to a vapor phase mixture comprising acid chloride having the general formula ##EQU6## and aldehyde having the general formula ##EQU7## wherein R 1 and R 2 are independently selected from straight or branched-chain aliphatic hydrocarbon radicals having from 1 to about 20 carbon atoms and cyclic hydrocarbon radicals having from 6 to about 20 carbon atoms, further wherein the molar proportion of acid chloride to aldehyde in the vapor phase mixture is greater than about 1:10.
Claim 10
Dependent Claim 106 words
A disposable paper container for containing aqueous liquids comprising paper having a film on one side formed by contact with polyvinyl alcohol and subsequently exposed along said polyvinyl alcohol side to a vapor phase mixture comprising acid chloride having the generaal formula ##EQU8## and aldehyde having the general formula ##EQU9## wherein R 1 and R 2 are independently selected from straight or branched-chain aliphatic hydrocarbon radicals having from 1 to about 20 carbon atoms and cyclic hydrocarbon radicals having from 6 to about 20 carbon atoms, further wherein the molar proportion of acid chloride to aldehyde in the vapor phase mixture is greater than about 1:10.
Claim 11
Dependent Claim 106 words
A disposable paper container for containing aqueous liquids comprising paper having a film on one side formed by contact with polyvinyl alcohol and subsequently exposed along said polyvinyl alcohol side to a vapor phase mixture comprising acid chloride having the generaal formula ##EQU8## and aldehyde having the general formula ##EQU9## wherein R 1 and R 2 are independently selected from straight or branched-chain aliphatic hydrocarbon radicals having from 1 to about 20 carbon atoms and cyclic hydrocarbon radicals having from 6 to about 20 carbon atoms, further wherein the molar proportion of acid chloride to aldehyde in the vapor phase mixture is greater than about 1:10.
Claim 12
Dependent Claim 112 words
A disposable article of sanitary clothing comprising a sheet of polyvinyl alcohol treated along the body-facing side by exposure to a vapor phase mixture comprising acid chloride having the general formula ##EQU10## and aldehyde having the general formula ##EQU11## wherein R 1 and R 2 are independently selected from straight or branched-chain aliphatic hydrocarbon radicals having from 1 to about 20 carbon atoms and cyclic hydrocarbon radicals having from 6 to about 20 carbon atoms, further wherein the molar porportion of acid chloride to aldehyde in the vapor phase mixture is greater than about 1:10, and bonded to said sheet along said treated side a soft, absorbent layer of a water-disposable material.
Claim 13
Dependent Claim 112 words
A disposable article of sanitary clothing comprising a sheet of polyvinyl alcohol treated along the body-facing side by exposure to a vapor phase mixture comprising acid chloride having the general formula ##EQU10## and aldehyde having the general formula ##EQU11## wherein R 1 and R 2 are independently selected from straight or branched-chain aliphatic hydrocarbon radicals having from 1 to about 20 carbon atoms and cyclic hydrocarbon radicals having from 6 to about 20 carbon atoms, further wherein the molar porportion of acid chloride to aldehyde in the vapor phase mixture is greater than about 1:10, and bonded to said sheet along said treated side a soft, absorbent layer of a water-disposable material.
Claim 14
Dependent Claim 20 words
A disposable article of sanitary clothing according to claim 9 wherein said article is suitable for use as a diaper.

References Cited (Backward Citations)

US2512195A Cited
US2471497A Cited
US3137540A Cited
US3089493A Cited
US3626943A Cited
US3661695A Cited
US3799167A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-01-26 1979-07-28 1980-01-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-01-26 1983-07-28 1984-01-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-01-26 1987-07-28 1988-01-27 $7700.00 Window Closed / Lapsed

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