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US3873660A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for forming multiaxially oriented containers

Assignee: Monsanto Co
•
Filing: 1973-02-26
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Granted: 1975-03-25
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Expires: 1993-02-26
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Abstract

Abstract Multiaxially oriented containers are formed from an extruded, molecularly orientable thermoplastic parison having a programmed wall thickness. The parison while at extrusion temperature is sealed at one end and expanded incrementally in a conditioning mold into the shape of a preform which is allowed to set therein for a brief time period in order to develop an outer skin at reduced temperature. The full wall of the variable thickness preform is then reduced in temperature to within the orientation temperature range and the preform then stretched longitudinally and expanded radially in a finishing mold to develop axial and radial orientation while forming the container. Since the thicker portion(s) of the programmed parison do not cool as much in the conditioning mold as do the thinner portion(s) they consequently subsequently stretch to a greater extent, and this phenomenom must be compensated for in the intitial programming step. The container finish is preferably formed in the conditioning mold while the thermoplastic is at elevated temperature. The molecularly orientable thermoplastic may be a high nitrile-groupcontaining polymer having excellent barrier properties of the type covered by the trademark LOPAC.

Inventors

  • 👤 Joseph R Reilly
  • 👤 Thomas F Sincock

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 10:18
CPC Classifications
B; B29; B29C; B29C49/00; B29C49/42; B29C49/58; B29C49/60; B29C49/02; B29C49/04; B29C49/04102; B29C49/0411; B29C49/04112; B29C49/04114; B29C49/08; B29C49/16; B29C49/18; B29C49/64; B29C49/6472; B29C2049/4294; B29C2049/6072; B29C2049/6091; B29C2793/00; B29C2793/0081; B29C2949/00; B29C2949/07; B29C2949/0715; B29C49/04116; B29C49/06; B29K; B29K2033/00; B29K2033/18; Y; Y10; Y10S; Y10S264/00; Y10S264/33

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 297 words
A method of forming a biaxially oriented container having a controlled distribution of wall thickness therein, said method comprising the steps of: a. continuously extruding an elongted, unconfined, hallow, thermoplastic parison at a temperature in excess of that at which substantial molecular orientation of the thermoplastic occurs; b. varying the thickness of the wall of the parison during extrusion in accordance with a predetermined program; c. closing separated sections of a conditioning mold on a portion of said variable wall thickness parison while pinching its end shut in the joint between said sections; d. introducing pressurized fluid into the conditioning mold-enclosed parison portion to expand it outwardly into contact with cooled surfaces of a cavity in the conditioning mold to form a self-supporting preform of varying wall thickness having an outer skin at reduced temperature; e. transferring said self-supporting preform from the conditioning mold to a temperature conditioning zone; f. reducing the temperature of inner wall sections of the variable wall thickness preform in said conditioning zone such that the entire wall thickness of such sections is within a temperature range at which substantial molecular orientation can occur, the thinner portions of such sections of said wall being at a lower temperature than the thicker portions; g. longitudinally stretching the temperature-conditioned preform to impart axial orientation thereto; and h. expanding the longitudinally stretched, variable wall thickness, temperature-conditioned preform radially outwardly against cooled surfaces of a cavity of a finishing mold to form the biaxially oriented container and reduce the temperature of the thermoplastic sufficiently to lock in the orientation stresses produced during the longitudinal and radial stretching, the thin, cooler portion of such sections of said preform stretching less than the thicker hotter portions thereof during said expansion, thereby producing said wall thickness distribution in said container.
Claim 2
Independent Claim 297 words
A method of forming a biaxially oriented container having a controlled distribution of wall thickness therein, said method comprising the steps of: a. continuously extruding an elongted, unconfined, hallow, thermoplastic parison at a temperature in excess of that at which substantial molecular orientation of the thermoplastic occurs; b. varying the thickness of the wall of the parison during extrusion in accordance with a predetermined program; c. closing separated sections of a conditioning mold on a portion of said variable wall thickness parison while pinching its end shut in the joint between said sections; d. introducing pressurized fluid into the conditioning mold-enclosed parison portion to expand it outwardly into contact with cooled surfaces of a cavity in the conditioning mold to form a self-supporting preform of varying wall thickness having an outer skin at reduced temperature; e. transferring said self-supporting preform from the conditioning mold to a temperature conditioning zone; f. reducing the temperature of inner wall sections of the variable wall thickness preform in said conditioning zone such that the entire wall thickness of such sections is within a temperature range at which substantial molecular orientation can occur, the thinner portions of such sections of said wall being at a lower temperature than the thicker portions; g. longitudinally stretching the temperature-conditioned preform to impart axial orientation thereto; and h. expanding the longitudinally stretched, variable wall thickness, temperature-conditioned preform radially outwardly against cooled surfaces of a cavity of a finishing mold to form the biaxially oriented container and reduce the temperature of the thermoplastic sufficiently to lock in the orientation stresses produced during the longitudinal and radial stretching, the thin, cooler portion of such sections of said preform stretching less than the thicker hotter portions thereof during said expansion, thereby producing said wall thickness distribution in said container.
Claim 3
Dependent Claim 41 words
The process of claim 1 wherein the thickness of that portion of the wall of the parison which will constitute the upper portion of the preform and subsequently the area adjacent the neck of the finished container is increased during extrusion.
Claim 4
Dependent Claim 32 words
The process of claim 1 wherein the extent of expansion of the parison portion in the conditioning mold is between 150 to 300% of the inside diameter of the parison during extrusion.
Claim 5
Dependent Claim 34 words
The process of claim 1 wherein a molded neck finish is formed on the preform in the conditioning mold while the thermoplastic is at said temperature above that at which substantial molecular orientation occurs.
Claim 6
Dependent Claim 32 words
The process of claim 4 wherein said neck finish is formed by expanding a section of the parison portion outwardly against molding surfaces of the conditioning mold corresponding to said neck finish.
Claim 7
Dependent Claim 15 words
The process of claim 5 wherein said container is a bottle having a narrow neck.
Claim 8
Dependent Claim 40 words
The process of claim 1 wherein at least 60 weight percent of the thermoplastic has been polymerized from methacrylonitrile monomer, the remainder thereof including at least one polymerized comonomer having at least one ethylenically unsaturated bond in its molecular structure.
Claim 9
Dependent Claim 128 words
In the method of forming a blow molded biaxially oriented container from an extruded thermoplastic parison which includes exposing the parison to temperature conditioning means to bring its temperature to witHin the range at which substantial molecular orientation can occur and then longitudinally stretching the temperature-conditioned parison prior to blow molding to develop uniaxial orientation, the improvement which comprises closing separated sections of a conditioning mold on said parison while pinching its end shut in the joint between said sections and the introducing pressurized fluid into the enclosed parison to incrementally expand it outwardly into contact with cooled surfaces of a cavity in the conditioning mold to form a self-supporting closed end preform having an outer skin at reduced temperature suitable for transfer to said temperature conditioning means.
Claim 10
Dependent Claim 128 words
In the method of forming a blow molded biaxially oriented container from an extruded thermoplastic parison which includes exposing the parison to temperature conditioning means to bring its temperature to witHin the range at which substantial molecular orientation can occur and then longitudinally stretching the temperature-conditioned parison prior to blow molding to develop uniaxial orientation, the improvement which comprises closing separated sections of a conditioning mold on said parison while pinching its end shut in the joint between said sections and the introducing pressurized fluid into the enclosed parison to incrementally expand it outwardly into contact with cooled surfaces of a cavity in the conditioning mold to form a self-supporting closed end preform having an outer skin at reduced temperature suitable for transfer to said temperature conditioning means.
Claim 11
Independent Claim 248 words
A method of making a biaxially oriented, narrow necked container having controlled wall thickness distribution from a high nitrile polymer, said method comprising: a. extruding a thermoplastic parison of said high nitrile polymer at a temperature within the range of between 400* to 500*F.; b. increasing the thickness of one portion of said parison with respect to another portion during said extrusion; c. enclosing said variable wall thickness parison in a conditioning mold; d. expanding said variable wall thickness parison incrementally outwardly against cooled walls of a cavity in said conditioning mold to form a preform having a molded neck finish and an elongated body containing said variable thickness portions; e. reducing the temperature of the body of said preform such that it is within the range of between 250* to 325* F., the average temperature of the wall of the thickened portion corresponding to the thickened portion of the parison being within said temperature range but incrementally greater than the average wall temperature of said another portion of said body; f. increasing the length of said temperature-conditioned preform such that the thickened portion at said incrementally greater average wall temperature stretches more than said another portion and is consequently reduced in thickness, said length increase creating uniaxial molecular orientation in the preform; and g. expanding the thus increased-length preform radially outwardly against the wall of a cavity corresponding to the configuration of the container to create radial orientation in the thermoplastic and form said biaxially oriented container.
Claim 12
Independent Claim 248 words
A method of making a biaxially oriented, narrow necked container having controlled wall thickness distribution from a high nitrile polymer, said method comprising: a. extruding a thermoplastic parison of said high nitrile polymer at a temperature within the range of between 400* to 500*F.; b. increasing the thickness of one portion of said parison with respect to another portion during said extrusion; c. enclosing said variable wall thickness parison in a conditioning mold; d. expanding said variable wall thickness parison incrementally outwardly against cooled walls of a cavity in said conditioning mold to form a preform having a molded neck finish and an elongated body containing said variable thickness portions; e. reducing the temperature of the body of said preform such that it is within the range of between 250* to 325* F., the average temperature of the wall of the thickened portion corresponding to the thickened portion of the parison being within said temperature range but incrementally greater than the average wall temperature of said another portion of said body; f. increasing the length of said temperature-conditioned preform such that the thickened portion at said incrementally greater average wall temperature stretches more than said another portion and is consequently reduced in thickness, said length increase creating uniaxial molecular orientation in the preform; and g. expanding the thus increased-length preform radially outwardly against the wall of a cavity corresponding to the configuration of the container to create radial orientation in the thermoplastic and form said biaxially oriented container.
Claim 13
Independent Claim 216 words
A METHOD OF FORMING A MOLECULARLY ORIENTED CONTAINER WHICH COMPRISES: A. EXTRUDING AN UNCONFINED, HOLLOW THERMOPLASTIC PARISON AT A TEMPERATURE IN EXCESS OF THAT AT WHICH SUBSTANTIAL MOLECULAR ORIENTATION OF THE THERMOPLASTIC OCCURS ON STRETCHING; B. CLOSING SECTIONS OF A PARISON CONDITIONING AND SHAPING MOLD ON SAID PARISON TO ENCLOSE SAID PARISON THEREIN WHILE PINCHING ITS END SHUT BETWEEN THE SECTIONS; C. SUBJECTING THE ENCLOSED PARISON TO A DEFORMING PRESSURE WHILE AT SAID TEMPERATURE TO EXPAND IT OUTWARDLY AGAINST COOLED MOLDING SURFACES OF SAID CONDITIONING AND SHAPING MOLD TO FORM A PREFORM HAVING A BODY PORTION AND A MOLDED FINISH; D. TRANSFERRING SAID PREFORM WHILE STILL IN A PRESSURE SENSITIVE BUT DIMENSIONALLY STABLE STATE FROM THE CONDITIONING AND SHAPING MOLD TO A TEMPERATURE CONDITIONING ZONE; E. BRINGING THE TEMPERATURE OF THE THERMOPLASTIC OF AT LEAST THE BODY PORTION OF THE PREFORM IN THE CONDITIONING ZONE TO WITHIN THE RANGE AT WHICH SUBSTANTIAL MOLECULAR ORIENTATION OF THE THERMOPLASTIC OCCURS ON STRETCHING; F. TRANSFERRING THE PREFORM FROM THE CONDITIONING ZONE TO A FINISHING MOLD AFTER THE TEMPERATURE OF THE BODY PORTION THEREOF HAS REACHED SUCH RANGE; AND G. LONGITUDINALLY STRETCHING AND RADIALLY EXPANDING THE BODY PORTION ONLY OF SAID PREFORM WHILE WITHIN SAID TEMPERATURE RANGE AGAINST MOLDING SURFACES OF THE FINISHING MOLD TO FORM SAID MOLECULARLY ORIENTED CONTAINER.
Claim 14
Independent Claim 216 words
A METHOD OF FORMING A MOLECULARLY ORIENTED CONTAINER WHICH COMPRISES: A. EXTRUDING AN UNCONFINED, HOLLOW THERMOPLASTIC PARISON AT A TEMPERATURE IN EXCESS OF THAT AT WHICH SUBSTANTIAL MOLECULAR ORIENTATION OF THE THERMOPLASTIC OCCURS ON STRETCHING; B. CLOSING SECTIONS OF A PARISON CONDITIONING AND SHAPING MOLD ON SAID PARISON TO ENCLOSE SAID PARISON THEREIN WHILE PINCHING ITS END SHUT BETWEEN THE SECTIONS; C. SUBJECTING THE ENCLOSED PARISON TO A DEFORMING PRESSURE WHILE AT SAID TEMPERATURE TO EXPAND IT OUTWARDLY AGAINST COOLED MOLDING SURFACES OF SAID CONDITIONING AND SHAPING MOLD TO FORM A PREFORM HAVING A BODY PORTION AND A MOLDED FINISH; D. TRANSFERRING SAID PREFORM WHILE STILL IN A PRESSURE SENSITIVE BUT DIMENSIONALLY STABLE STATE FROM THE CONDITIONING AND SHAPING MOLD TO A TEMPERATURE CONDITIONING ZONE; E. BRINGING THE TEMPERATURE OF THE THERMOPLASTIC OF AT LEAST THE BODY PORTION OF THE PREFORM IN THE CONDITIONING ZONE TO WITHIN THE RANGE AT WHICH SUBSTANTIAL MOLECULAR ORIENTATION OF THE THERMOPLASTIC OCCURS ON STRETCHING; F. TRANSFERRING THE PREFORM FROM THE CONDITIONING ZONE TO A FINISHING MOLD AFTER THE TEMPERATURE OF THE BODY PORTION THEREOF HAS REACHED SUCH RANGE; AND G. LONGITUDINALLY STRETCHING AND RADIALLY EXPANDING THE BODY PORTION ONLY OF SAID PREFORM WHILE WITHIN SAID TEMPERATURE RANGE AGAINST MOLDING SURFACES OF THE FINISHING MOLD TO FORM SAID MOLECULARLY ORIENTED CONTAINER.
Claim 15
Dependent Claim 14 words
The method of claim 10 wherein the thermoplastic parison has a variable wall thickness.
Claim 16
Dependent Claim 27 words
The method of claim 10 wherein the thermoplastic material comprisEs a major portion of a polymerized monomer containing at least one nitrile group in its molecular structure.

References Cited (Backward Citations)

US2331687A Cited
US2331702A Cited
US2750625A Cited
US3311684A Cited
US3781395A Cited
US3776991A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-03-24 1978-09-23 1979-03-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-03-24 1982-09-23 1983-03-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-03-24 1986-09-23 1987-03-25 $7700.00 Window Closed / Lapsed

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