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US3868408A Expired / Lapsed US ⏱️ 0.0 years remaining

Ethylenically unsaturated dicarboxylic acid esters of {60 , {60 -dihydroperfluoro alcohols

Assignee: Air Products and Chemicals Inc
•
Filing: 1971-09-27
•
Granted: 1975-02-25
•
Expires: 1991-09-27
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Abstract

Abstract The alpha, beta-ethylenically unsaturated dicarboxylic acid ester of an alpha, alpha-dihydroperfluoroalcohol is prepared by sulfation of the fluorinated alcohol with oleum, sulfur trioxide or chlorosulfonic acid and subsequent esterification of the resulting sulfate with maleic, fumaric, mesaconic, citraconic or itaconic acid. The resulting alpha, beta-ethylenically unsaturated esters of the alpha, alpha-dihydroperfluoroalcohols can be polymerized and applied to materials as coating compositions with high glass transition temperatures, high utility temperatures and resistance to soiling.

Inventors

  • 👤 Dewey George Holland
  • 👤 Burton David Beitchman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:33
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/263; D06M15/277; C; C08; C08F; C08F22/00; C08F22/10; C08F22/12; C08F22/18; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31692; Y10T428/31699

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 33 words
A DIESTER HAVING THE FORMULA: (RFCH2)2R WHERE RF IS CNF2N+1(C6F10); C6F10 IS A PERFLUOROCYCLOPHEXANE RING WHERE N IS AN INTEGER OF FROM 0 TO 4; AND WHERE R IS (-02CCH:CHC02-), (-02CCH:C(CH3)C02-) OR (-02CC8CH2)CH2CO2-).
Claim 2
Dependent Claim 33 words
A DIESTER HAVING THE FORMULA: (RFCH2)2R WHERE RF IS CNF2N+1(C6F10); C6F10 IS A PERFLUOROCYCLOPHEXANE RING WHERE N IS AN INTEGER OF FROM 0 TO 4; AND WHERE R IS (-02CCH:CHC02-), (-02CCH:C(CH3)C02-) OR (-02CC8CH2)CH2CO2-).
Claim 3
Dependent Claim 9 words
The diester of claim 1 wherein R is (-O2CCH:CHCO2-).
Claim 4
Dependent Claim 9 words
The diester of claim 1 wherein R is (-O2CC(CH2)CH2CO2-).
Claim 5
Dependent Claim 9 words
The diester of claim 1 wherein R is (-O2CCH:C(CH3)CO2-).
Claim 6
Dependent Claim 21 words
The diester of a dibasic acid and alpha, alpha-dihydroperfluorocyclohexanecarbinol wherein the dibasic acid is maleic, fumaric, mesaconic, citraconic or itaconic acid.
Claim 7
Dependent Claim 21 words
The diester of a dibasic acid and alpha, alpha-dihydroperfluorocyclohexanecarbinol wherein the dibasic acid is maleic, fumaric, mesaconic, citraconic or itaconic acid.
Claim 8
Dependent Claim 3 words
Di-(alpha, alpha-dihydroperfluorocyclohexanecarbinol) fumarate.
Claim 9
Dependent Claim 3 words
Di-(alpha, alpha-dihydroperfluorocyclohexanecarbinol) fumarate.
Claim 10
Dependent Claim 3 words
Di-(alpha, alpha-dihydroperfluorocyclohexanecarbinol) itaconate.
Claim 11
Dependent Claim 3 words
Di-(alpha, alpha-dihydroperfluorocyclohexanecarbinol) itaconate.
Claim 12
Dependent Claim 3 words
Di-(alpha, alpha-dihydroperfluorocyclohexanecarbinol) mesaconate.
Claim 13
Dependent Claim 3 words
Di-(alpha, alpha-dihydroperfluorocyclohexanecarbinol) mesaconate.
Claim 14
Dependent Claim 3 words
Di-(alpha, alpha-dihydroperfluorocyclohexanecarbinol) maleate.
Claim 15
Dependent Claim 3 words
Di-(alpha, alpha-dihydroperfluorocyclohexanecarbinol) maleate.
Claim 16
Dependent Claim 3 words
Di-(alpha, alpha-dihydroperfluorocyclohexanecarbinol) citraconate.
Claim 17
Dependent Claim 3 words
Di-(alpha, alpha-dihydroperfluorocyclohexanecarbinol) citraconate.

References Cited (Backward Citations)

US2778850A Cited
US3223725A Cited
US3239557A Cited
US3385882A Cited
US3671574A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-02-24 1978-08-26 1979-02-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-02-24 1982-08-26 1983-02-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-02-24 1986-08-26 1987-02-25 $7700.00 Window Closed / Lapsed

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