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US3728594A Expired / Lapsed US ⏱️ 0.0 years remaining

Electroluminescent device comprising a transition metal oxide doped with a trivalent rare earth element

Assignee: RCA Corp
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Filing: 1971-11-17
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Granted: 1973-04-17
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Expires: 1991-11-17
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Abstract

Abstract An electroluminescent device includes a layer including a transition metal oxide doped with a trivalent rare earth metal. The transition metal oxide has the general formula, Mxi(MiiOy)z where Mi is a Group IIA element or a group IIIB element, Mii is a transition metal, O is oxygen and the subscripts x, y and z denote the number of each of the elements depending on the valences of the particular elements used. The layer may be in the form of a single crystalline body of the doped transition metal oxide or particles of the transition metal oxide in a dielectric medium. A pair of spaced contacts are provided on the layer. For the single crystalline body one of the contacts is a blocking contact and the other is an ohmic contact. For the layer which includes the particles in a dielectric medium, both contacts are blocking contacts. Light is emitted from the layer when a current is applied through the layer between the contacts; DC current being used for the single crystalline body and AC current for the particles in a dielectric medium.

Inventors

  • 👤 W Yim
  • 👤 P Yocom

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 12:56
CPC Classifications
H; H10; H10H; H10H20/00; H10H20/80; H10H20/81; H10H20/822

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 120 words
An electroluminescent device comprising: a. a single crystalline layer of a transition metal oxide having the formula: Mix(MiiOy)z wherein Mi is an element selected from the group consisting of Group IIA elements and Group IIIB elements; Mii is a transition metal; O is oxygen; x denotes the number of Mi atoms, z denotes the number of Mii atoms, y times z denotes the number of O atoms, with x, y, and z being chosen depending on the valences of the particular elements used, said layer having an N type conductivity with a donor concentration of from 1014 to 1017 per cm3; B. a dopant of a trivalent rare earth metal; and c. a pair of spaced contacts on said layer.
Claim 2
Dependent Claim 120 words
An electroluminescent device comprising: a. a single crystalline layer of a transition metal oxide having the formula: Mix(MiiOy)z wherein Mi is an element selected from the group consisting of Group IIA elements and Group IIIB elements; Mii is a transition metal; O is oxygen; x denotes the number of Mi atoms, z denotes the number of Mii atoms, y times z denotes the number of O atoms, with x, y, and z being chosen depending on the valences of the particular elements used, said layer having an N type conductivity with a donor concentration of from 1014 to 1017 per cm3; B. a dopant of a trivalent rare earth metal; and c. a pair of spaced contacts on said layer.
Claim 3
Dependent Claim 18 words
An electroluminescent device in accordance with claim 1 in which one of said contacts is a blocking contact.
Claim 4
Dependent Claim 27 words
An electroluminescent device in accordance with claim 1 in which Mi is a metal selected from the group consisting of calcium, strontium, magnesium, barium, yttrium and lanthanum.
Claim 5
Dependent Claim 30 words
An electroluminescent device in accordance with claim 3 in which Mii is a transition metal selected from the group consisting of titanium, vanadium, niobium, tungsten, zirconium, molybdenum, hafnium and tantalum.
Claim 6
Dependent Claim 31 words
An electroluminescent device in accordance with claim 4 in which the rare earth metal is selected from the group consisting of praseodymium, neodymium, samarium, europium, terbium, dysprosium, holmium, erbium and thulium.
Claim 7
Dependent Claim 28 words
An electroluminescent device in accordance with claim 5 in which the amount of the rare earth metal in the body is between 0.01 and 0.5 percent by weight.

References Cited (Backward Citations)

US3254267A Cited
US3523045A Cited
US3441517A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1976-04-16 1976-10-16 1977-04-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1980-04-16 1980-10-16 1981-04-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1984-04-16 1984-10-16 1985-04-17 $7700.00 Window Closed / Lapsed

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