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US5646217A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymer composition containing polyhydroxyalkanoate and metal compound

Assignee: Yield10 Bioscience Inc
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Filing: 1993-11-04
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Granted: 1997-07-08
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Expires: 2013-11-04
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Abstract

Abstract Polymer compositions are provided which comprise a first polyhydroxyalkanoate component and optionally a second polymer component, the composition have enhanced properties by using an inorganic oxygen containing compound in the composition. The inorganic oxygen containing compound may be acting as a transesterification catalyst.

Inventors

  • 👤 Timothy Hammond

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 00:39
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/04; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08K5/00; C08K5/0091; C08K5/04; C08K5/09; C08K5/098

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 200 words
A polymer composition comprising a first component which is a polyhydroxyalkanoate (PHA), a second component which is a different PHA or a synthetic polyester which is a polypropiolactone, polybutyrolactone, polyvalerolactone, polycaprolactone or copolymer thereof, a polyactide, a polyester containing a combination of a dicarboxylic acid component and diol, the dicarboxylic acid component being selected from the group consisting of malonic, succinic, glutaric, adipic, pimelic, azelaic, sebacic, fumaric, 2,2-dimethylglutaric, suberic, 1,3-cyclopentane dicarboxylic, 1,4-dicyclohexane-dicarboxylic, 1,3-cyclohexane dicarboxylic, diglycolic, iraconic, maleic, 2,5-norbornane dicarboxylic, ester forming derivatives thereof and combinations thereof and the diol being selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, 1,3-propanediol, 2,2-dimethyl-1,3-propanediol, 1,3 butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 2,2,-trimethyl-1,6-hexanediol, thiodiethanol, 1,3-cyclobutanediol, triethyleneglycol, tetraethyleneglycol, di-, tri-, tetra-propyleneglycol, combinations thereof, a cellulose, cellulose acetate, cellulose butyrate, and the copolymer of succinic acid and butylene glycol, in which 5% to 90% of each of said first and second components are present by weight and 0.1 to 5 phr of at least one transesterification catalyst which is an oxy compound of a metal from Group 11A or 111A or IVA of the Periodic Table, or of a metalloid having a valency of at least 3 from a B Group of the Periodic Table.
Claim 2
Dependent Claim 200 words
A polymer composition comprising a first component which is a polyhydroxyalkanoate (PHA), a second component which is a different PHA or a synthetic polyester which is a polypropiolactone, polybutyrolactone, polyvalerolactone, polycaprolactone or copolymer thereof, a polyactide, a polyester containing a combination of a dicarboxylic acid component and diol, the dicarboxylic acid component being selected from the group consisting of malonic, succinic, glutaric, adipic, pimelic, azelaic, sebacic, fumaric, 2,2-dimethylglutaric, suberic, 1,3-cyclopentane dicarboxylic, 1,4-dicyclohexane-dicarboxylic, 1,3-cyclohexane dicarboxylic, diglycolic, iraconic, maleic, 2,5-norbornane dicarboxylic, ester forming derivatives thereof and combinations thereof and the diol being selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, 1,3-propanediol, 2,2-dimethyl-1,3-propanediol, 1,3 butanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 2,2,-trimethyl-1,6-hexanediol, thiodiethanol, 1,3-cyclobutanediol, triethyleneglycol, tetraethyleneglycol, di-, tri-, tetra-propyleneglycol, combinations thereof, a cellulose, cellulose acetate, cellulose butyrate, and the copolymer of succinic acid and butylene glycol, in which 5% to 90% of each of said first and second components are present by weight and 0.1 to 5 phr of at least one transesterification catalyst which is an oxy compound of a metal from Group 11A or 111A or IVA of the Periodic Table, or of a metalloid having a valency of at least 3 from a B Group of the Periodic Table.
Claim 3
Dependent Claim 22 words
A polymer composition according to claim 1 in which the second component is selected from group consisting of polyhydroxyalkanoate, polycaprolactone and potylactide.
Claim 4
Dependent Claim 22 words
A polymer composition according to claim 1 in which the first component is capable of over 30% crystallinity in absence of plasticiser.
Claim 5
Dependent Claim 95 words
A polymer composition according to claim 1 in which (a) the first and second polymer components are different PHA having repeating units of formula: --O--CmHn--CO-- where n=2 m; (b) the first component contains 70-95 mol percent of m=3 units with m being 4 in the balance of the units therein; (c) the second component contains at least 99 mol percent of units where m=3with m being 4 in the balance of the units therein; and (d) the components have been reacted sufficiently to increase the crystallization velocity, and/or to decrease the rate of thermal degradation.
Claim 6
Dependent Claim 46 words
A polymer composition according to claim 1 in which the second component is a polylactic acid, the oxycompound is antimony trioxide and the components have been reacted sufficiently to produce a phase having a glass transition at a temperature different from that of either starting component.
Claim 7
Dependent Claim 39 words
A polymer composition according to claim 1 in which the second component is polycaprolactone and the components have been reacted sufficiently to increase the elongation-to-break as compared with the value for the corresponding composition not containing the oxy compound.
Claim 8
Dependent Claim 17 words
A composition according to claim 1 in which the oxy compound is introduced as a titanium alkoxide.
Claim 9
Dependent Claim 31 words
A process for preparing a composition according to claim 1 by mixing the components and the oxy compound and heat treating the mixture in a molten state to react said components.
Claim 10
Dependent Claim 22 words
A process of making shaped articles which comprises shaping a composition according to claim 1 and subjecting it to a crystallization temperature.

References Cited (Backward Citations)

JPS63172762A Cited
CA2029747A1 Cited
US5124371A Cited
US5252701A Cited
US5191016A Cited
JPH04146952A Cited
US5281691A Cited
US5439985A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-07-07 2001-01-06 2001-07-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-07-07 2005-01-06 2005-07-08 $3760.00 Window Closed / Lapsed
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