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US5550173A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester composition

Assignee: Yield10 Bioscience Inc
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Filing: 1993-11-04
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Granted: 1996-08-27
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Expires: 2013-11-04
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Abstract

Abstract PCT No. PCT/GB93/02279 Sec. 371 Date May 5, 1995 Sec. 102(e) Date May 5, 1995 PCT Filed Nov. 4, 1993 PCT Pub. No. WO94/11445 PCT Pub. Date May 26, 1994A polymer composition comprising at least one structural polymer and at least one oligomer of at least one polymer selected from the group; polyhydroxyalkanoates, polylactide, polycaprolactone and co-polymers thereof.

Inventors

  • 👤 Timothy Hammond
  • 👤 Jasbinder S. Bal

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 04:07
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/04; C08L101/00

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 80 words
A polymer composition comprising at least one biodegradable microbiologically produced polyhydroxyalkanoate (PHA) having a of molecular weight Mw of at least 50000, having repeating units of formula I: --O--C.sub.m H.sub.n --CO-- I where m is 3 in all said units or m is 3 in some of said units and m is 4 in the remainder of said units; and n is 2m and at least one oligomer selected from the group consisting of hydroxyalkanoate, lactide, caprolactone and co-oligomers thereof.
Claim 2
Dependent Claim 80 words
A polymer composition comprising at least one biodegradable microbiologically produced polyhydroxyalkanoate (PHA) having a of molecular weight Mw of at least 50000, having repeating units of formula I: --O--C.sub.m H.sub.n --CO-- I where m is 3 in all said units or m is 3 in some of said units and m is 4 in the remainder of said units; and n is 2m and at least one oligomer selected from the group consisting of hydroxyalkanoate, lactide, caprolactone and co-oligomers thereof.
Claim 3
Dependent Claim 20 words
A polymer composition according to claim 1 in which the oligomer has an average molecular weight of 2000 or less.
Claim 4
Dependent Claim 52 words
A polymer composition according to claim 2 in which the content of the oligomer is in the range 1 to 40 parts by weight per hundred parts of PHA and the PHA is plasticised thereby to the extent of a decrease of 5° to 30° C. in its glass transition temperature Tg.
Claim 5
Dependent Claim 38 words
A polymer composition according to claim 1 in which the oligomer has an average molecular weight in the range 4000 to 20000 and has a glass transition temperature Tg within 10° C. of the Tg of the PHA.
Claim 6
Dependent Claim 20 words
A polymer composition according to claim 1 in which the oligomer is an oligohydroxyalkanoate derived from a microbiologically produced PHA.
Claim 7
Dependent Claim 52 words
A polymer composition according to claim 1 in which the oligomer has repeating units of formula I: --O--C.sub.m H.sub.n --CO-- I where m is 3 in all said units or m is 3 in some of said units and m is 4 in the remainder of said units; and n is 2m.
Claim 8
Dependent Claim 25 words
A polymer composition according to claim 6 in which m is 3 in at least 70 mol % of the repeating units of said oligomer.
Claim 9
Dependent Claim 24 words
A process of making a composition according to claim 1 which comprises mixing the PHA and the oligomer in the dissolved or molten state.
Claim 10
Dependent Claim 16 words
A method of making shaped articles characterised by using a polymer composition according to claim 1.
Claim 11
Dependent Claim 80 words
An oligohydroxyalkanoate having an average molecular weight Mw in the range 4000 to 25000, which is the product of de-polymerising a microbiologically produced PHA having units of formula I: --O--C.sub.m H.sub.n --CO-- I in which m is 3 in all said units or m is 3 in some of said units and 4 in the remainder of said units, and n is 2m, said PHA being crystallisable to the extent of over 30% and having carboxyalkyl and hydroxy end groups.
Claim 12
Dependent Claim 80 words
An oligohydroxyalkanoate having an average molecular weight Mw in the range 4000 to 25000, which is the product of de-polymerising a microbiologically produced PHA having units of formula I: --O--C.sub.m H.sub.n --CO-- I in which m is 3 in all said units or m is 3 in some of said units and 4 in the remainder of said units, and n is 2m, said PHA being crystallisable to the extent of over 30% and having carboxyalkyl and hydroxy end groups.
Claim 13
Dependent Claim 25 words
A polymer composition according to claim 1 in which m is 3 in at least 70 mol % of the repeating units of said PHA.

References Cited (Backward Citations)

US5126255A Cited
EP0443270A2 Cited
EP0450777A2 Cited
WO1992001548A1 Cited
WO1992004413A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-08-27 2000-02-26 2000-08-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-08-27 2004-02-26 2004-08-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-08-27 2008-02-26 2008-08-27 $7700.00 Window Closed / Lapsed

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